Nitroalkane is acidic only towards:
3. NaOH
Na2CO3
alcohol
liquid NH3
Primary, secondary, and tertiary amines may be separated by using:
Ethanoyl chloride
Diethyl oxalate
Thionyl chloride
None of the above
The name urea was given by:
Wohler
Berzelius
Roulle
Lemery
Urea when heated a white residue is formed. Its alkaline solution when treated with few drops of CuSO4 solution gives:
Red colour
Violet colour
Green colour
Yellow colour
The diamide of carbonic acid is:
acetamide
formamide
benzamide
urea
The basic character of methylamines in vapour phase is:
3°>2°>1°>NH3
2°>3°>1°>NH3
1°>2°>3°>NH3
None of these
Gabriel's phthalimide reaction is used to prepare:
Primary amine
Secondary amine
Tertiary amine
All of the above
Grignard reagent and acetyl chloride does not react with:
RNH2
R2NH
R3N
General formula of an amine is:
CnH2n+1N
CnH2n+2N
CnH2n+3N
CnH2nN
The amine may contain:
-NH2 gp.
N||H gp.
-N|| gp.
all of these
Primary amine and secondary amine are distinguished by:
Br2/KOH
HClO
HNO2
NH3
Which of the following is carbamide?
CH3CONH2
NH2CONH2
CH2(NH2)CONH2
CO(OH)NH2
Reaction of primary amine with aldehydes gives:
amide
aldimine
nitrile
none of these
An amine reacts with C6H5SO2Cl and the product is soluble in alkali, amine is:
1°
2°
3°
Which of the following will give a primary amine on hydrolysis?
Nitroparaffin
Alkyl cyanide
Oxime
Alkyl isocyanate
Mark the correct statement:
Methyl amine is slightly acidic.
Methyl amine is less basic than ammonia.
Methyl amine is a stronger base than ammonia.
Methyl amine forms salts with alkali.
Which one of the following amines will not react with HNO2 acid to give nitrogen?
CH3NH2
CH3CH2NH2
CH3-C|CH3H-NH2
What is decreasing order of basicity of p-, s-, t-ethyl amines and NH3 in aqueous medium ?
NH3>C2H5NH2>(C2H5)2NH>(C2H5)3N
(C2H5)3N>(C2H5)2NH>C2H5NH2>NH3
(C2H5)2NH>C2H5NH2>NH3>(C2H5)3N
(C2H5)2NH>(C2H5)3N>C2H5NH2>NH3
Urea on heating with ethanol gives:
Urethane
Urea alcohol
Ureides
Alkyl nitrite on reduction with Sn/HCl gives:
Alcohol
Hydroxylamine
Both (a) and (b)
Hydrazine
Which of the following compounds is expected to be the most basic?
Aniline
Ethylamine
Methylamine
The action of nitrous acid on a primary amine gives:
nitroalkane
alkyl nitrite
secondary amine
The reaction,
CH3CN+4H→Na/C2H5OHCH3CH2NH2 is called:
Sabatier reaction
Hofmann's bromamide reaction
Mendius reaction
A colourless organic compound gave brisk effervescence with a mixture of NaNO2 and dil. HCl. It could be:
glucose
oxalic acid
benzoic acid
Identify X in the sequence,
X →HNO2 C3H8O →H2SO4K2Cr2O7 C3H6O2
CH3-NH-CH2-CH3
CH3-CH2-CH2-NH2
(CH3)3N
none of the above
Aliphatic amines are ......basic than NH3 but aromatic amines are .....basic than NH3
more, less
less, more
both (a) and (b)
Aliphatic amines are soluble in water because:
they are basic.
they are amino compounds.
they are lighter than water.
of formation of hydrogen bonds with water.
The general formula of quaternary ammonium compound is:
R-NH2
[R4N]+X-
NH4X
Amines have:
garlic odour
fishy odour
jasmine odour
bitter almonds odour
Aqueous solution of urea is:
Acidic
Alkaline
Almost neutral
Amphoteric
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