What will be the product when aniline reacts with benzoyl chloride ?
N-phenybenzamide
N-methylbenzamide
Benzamide
N-ethylbenzamide
The correct increasing order of basic strength for the following compounds is .
II<III<I
III<I<II
III<II<I
II<I<III
In the nitration of benzene using a mixture of conc. H2SO4 and conc. HNO3,
the species that initiates the reaction is -
1. NO22. NO+3. NO2+4. NO2-
Match the compounds given in Column I with the items given in Column II.
Column I
Column II
Codes
A B C D
2 1 4 3
3 1 5 2
5 4 3 2
4 3 2 1
Assertion(A): N-ethylbenzene sulphonamide is soluble in alkali.
Reason(R): Hydrogen attached to nitrogen in sulphonamide is strongly acidic.
Both assertion and reason are true and the reason is the correct explanation of assertion.
Both assertion and reason are true and the reason is not the correct explanation of assertion.
Assertion is true but the reason is false.
Assertion is false but the reason is true.
Assertion(A): Only a small amount of HCI is required in the reduction of nitro compounds with iron scrap and HCI in the presence of steam.
Reason(R): FeCl2 formed gets hydrolyzed to release HCI during the reaction.
(i) Aromatic amine + Nitrous acid →A(ii) Aliphatic amine + Nitrous acid → B
The A and B in the above reactions are -
Alcohol, Diazonium salt
Aldehyde, Diazonium salt
Diazonium salt, Alcohol
Diazonium salt, Aldehyde
Amines are less acidic than alcohols of comparable molecular masses because
N is more electronegative than O.
O is more electronegative than N.
N can accomodate negative charge easily than O
Amides are more stable than alcohols
In the conversion of Nitromethane to methylamine, the reagent used is -
1. SOCl22. NaNH23. PCl54. Sn/HCl
An aromatic compound ‘A’ on treatment with ammonia and heating forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular formula C6H7N. The Substrate A is -
Benzamine
Aniline
Benzoic acid
Reaction of propanamide with ethanolic sodium hydroxide and bromine will give -
Ethylamine
Methylamine
Propylamine
A compound A when reacted with PCl5 and then with ammonia gave B. B when treated with bromine and caustic potash produced C. C on treatment with NaNO2 and HCl at 0°C and then boiling produced ortho-cresol. Compound A is:
o-Toluic acid
o-Chlorotoluene
o-Bromotoluene
m-Toluic acid
An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. The structure of (A) is
CH3CH2-NH-CH3
CH3-N|CH3-CH3
CH3CH2CH2-NH2
Which of the following compounds is most basic ?
D
If D is N-methyl aniline than A is:
Aniline reacts with Br2 water, and NaNO2/HCl gives respectively :
Aniline when diazotized in cold and then treated with dimethyl aniline gives a coloured product. Its structure would be :-
The reaction which gives isocyanide is :
The final product C, obtained in this reaction, would be :
A method for the identification of primary, secondary and tertiary amines is -
Azo-dye test
Carbylamine test
Hinsberg’s test
None of these
Aromatic primary amines cannot be prepared by Gabriel phthalimide synthesis because -
Alkyl halides do not undergo electrophilic substitution with the anion formed by the phthalimide
Alkyl halides do not undergo nucleophilic substitution with the anion formed by the phthalimide
Aryl halides do not undergo nucleophilic substitution with the anion formed by the phthalimide
Aryl halides do not undergo electrophilic substitution with the anion formed by the phthalimide
The primary amine is -
(CH3)2CHNH2
CH3(CH2)2NH-CH3
CH3(CH2)2N(CH3)2
None of the above
Which of the following is a secondary amine is -
1. CH3(CH2)2NH2 2. (CH3CH2)2NCH3 3. C6H5NHCH34. (CH3)3NH2
The tertiary amine is-
1. (CH3CH2)2NCH3 2. (CH3)3NH2 3. m-BrC6H4NH24. None of these
The chemical test used to distinguish between aniline and benzylamine is-
Nitrous acid.
Reduction Reaction
Hinsberg reagent
None of above
The chemical test used to distinguish between aniline and N-methyl aniline is-
Hoffmann bromamide reaction
Acetylation
The chemical test used to distinguish between methylamine and dimethylamine is-
Hinsberg's reagent
Both 2 and 3
X, Y, and Z in the above sequence are -
X= Fe/HCl, Y= Br2/FeCl3, and Z = H2O/ warm
X= Br2/FeCl3, Y= Fe/HCl, and Z = H2O/ warm
X= HBr/ hv, Y= Fe/HCl, and Z = H3PO2
X = HBr/ hv Y = Br2/FeCl3, and Z = H3PO2
X, and Y in the following sequence are
X = Br2/CS2, and Y =
X = Br2/H2O and Y =
X = Br2/CS2 and Y =
Benzyl chloride →KCN X →LiAlH4 Y
The product X and Y are -
2-Phenylethanenitrile and Benzoic acid
Benzonitrile and Benzoic acid
2-Phenylethanenitrile and 2-Phenylethanamine
Benzonitrile and 2-Phenylethanamine
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