What will be the product when aniline reacts with benzoyl chloride ?

  • N-phenybenzamide 

  • N-methylbenzamide

  • Benzamide

  • N-ethylbenzamide

The correct increasing order of basic strength for the following compounds is .

  • II<III<I

  • III<I<II

  • III<II<I

  • II<I<III

In the nitration of benzene using a mixture of conc. H2SO4 and conc. HNO3,

the species that initiates the reaction is -

1. NO22.  NO+3.  NO2+4.NO2-

  • 1
  • 2
  • 3
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Match the compounds given in Column I with the items given in Column II.

Column I

Column II

A. Benzene sulphonyl chloride
B. Sulphanilic acid
C. Alkyl diazonium salts
D. Aryl diazonium salts
1. Zwitter ion
2. Hinsberg reagent
3. Dyes
4. Conversion to alcohols

Codes

          A         B          C           D

  •        2          1           4           3

  •        3          1           5           2

  •        5          4           3           2

  •        4          3           2           1

Assertion(A): N-ethylbenzene sulphonamide is soluble in alkali.

Reason(R): Hydrogen attached to nitrogen in sulphonamide is strongly acidic.

  •   Both assertion and reason are true and the reason is the correct explanation of assertion.

  •   Both assertion and reason are true and the reason is not the correct explanation of assertion.

  •   Assertion is true but the reason is false.

  •   Assertion is false but the reason is true.

Assertion(A): Only a small amount of HCI is required in the reduction of nitro compounds with iron scrap and HCI in the presence of steam.

Reason(R): FeCl2 formed gets hydrolyzed to release HCI during the reaction.

  • Both assertion and reason are true and the reason is the correct explanation of assertion.

  • Both assertion and reason are true and the reason is not the correct explanation of assertion.

  • Assertion is true but the reason is false.

  • Assertion is false but the reason is true.

(i) Aromatic amine + Nitrous acid A(ii) Aliphatic amine  + Nitrous acid  B

The A and B in the above reactions are -

  • Alcohol, Diazonium salt

  • Aldehyde, Diazonium salt

  • Diazonium salt, Alcohol

  • Diazonium salt, Aldehyde

Amines are less acidic than alcohols of comparable molecular masses because

  • N is more electronegative than O.

  • O is more electronegative than N.

  • N can accomodate negative charge easily than O

  • Amides are more stable than alcohols

In the conversion of  Nitromethane to methylamine, the reagent used is -

1. SOCl22. NaNH23. PCl54. Sn/HCl

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  • 2
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An aromatic compound ‘A’ on treatment with ammonia and heating forms compound ‘B’ which on heating with Br2 and KOH forms a compound ‘C’ of molecular formula C6H7N. The Substrate A is -

  • Benzamide

  • Benzamine

  • Aniline

  • Benzoic acid 

Reaction of propanamide with ethanolic sodium hydroxide and bromine will give -

  • Ethylamine

  • Methylamine

  • Propylamine

  • Aniline

A compound A when reacted with PCl5 and then with ammonia gave B. B when treated with bromine and caustic potash produced C. C on treatment with NaNO2 and HCl at 0°C and then boiling produced ortho-cresol. Compound A is:

  •  o-Toluic acid

  •  o-Chlorotoluene

  •  o-Bromotoluene

  •  m-Toluic acid

An organic compound (C3H9N) (A), when treated with nitrous acid, gave an alcohol and N2 gas was evolved. (A) on warming with CHCl3 and caustic potash gave (C) which on reduction gave isopropylmethylamine. The structure of (A) is

  •   CH3CH2-NH-CH3

  •   CH3-N|CH3-CH3

  •  CH3CH2CH2-NH2

  •  

Which of the following compounds is most basic ?

  •  

  •  

  •  

  •  

D

If D is N-methyl aniline than A is:




  •  

  •  

  • CH3NH2

  •  

Aniline reacts with Br2 water, and NaNO2/HCl gives respectively :

  •   p-Bromoaniline; p-Chloroaniline
  •   2,4,6-Tribromoaniline; p-Chloroaniline
  •   2,4,6-Tribromoaniline; Benzenediazoniumchloride
  •   p-Bromoaniline; Benzenediazoniumchloride

Aniline when diazotized in cold and then treated with dimethyl aniline gives a coloured product. Its structure would be :- 

  •  

The reaction which gives isocyanide is :

  • Reimer Tiemann reaction.
  •   Carbylamine reaction.
  •   Hoffmann bromamide reaction.
  •   None of the above.

The final product C, obtained in this reaction, would be :

  •  

  •  

  •  

  •  

A method for the identification of primary, secondary and tertiary amines is -

  • Azo-dye test

  • Carbylamine test

  •  Hinsberg’s test

  • None of these

Aromatic primary amines cannot be prepared by Gabriel phthalimide synthesis because -

  • Alkyl halides do not undergo electrophilic substitution with the anion formed by the phthalimide

  • Alkyl halides do not undergo nucleophilic substitution with the anion formed by the phthalimide

  • Aryl halides do not undergo nucleophilic substitution with the anion formed by the phthalimide

  • Aryl halides do not undergo electrophilic substitution with the anion formed by the phthalimide

The primary amine is -

  •  (CH3)2CHNH2

  •  CH3(CH2)2NH-CH3

  •  CH3(CH2)2N(CH3)2

  • None of the above

Which of the following is a secondary amine is -

1. CH3(CH2)2NH2 2. (CH3CH2)2NCH3 3. C6H5NHCH34. (CH3)3NH2

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The tertiary amine is-

1. (CH3CH2)2NCH3 2. (CH3)3NH2 3. m-BrC6H4NH24. None of these

  • 1
  • 2
  • 3
  • 4

The chemical test used to distinguish between aniline and benzylamine is-

  • Nitrous acid.

  • Reduction Reaction

  • Hinsberg reagent

  • None of above

The chemical test used to distinguish between aniline and N-methyl aniline is-

 

 

  • Carbylamine test 

  • Hoffmann bromamide reaction

  • Acetylation

  • None of above

The chemical test used to distinguish between methylamine and dimethylamine is-

 

 

  • Hoffmann bromamide reaction

  • Hinsberg's reagent 

  • Carbylamine test

  • Both 2 and 3

 

X, Y, and Z in the above sequence are -

 

  • X= Fe/HCl, Y= Br2/FeCl3, and Z = H2O/ warm

  •  X= Br2/FeCl3, Y= Fe/HCl, and Z = H2O/ warm

  •   X= HBr/ hv, Y= Fe/HCl, and Z = H3PO2

  • X = HBr/ hv Y = Br2/FeCl3, and Z = H3PO2

X, and Y in the following sequence are

  • X = Br2/CS2, and Y = 

  • X = Br2/H2O and Y = 

  • X = Br2/CS2 and  Y = 

  • X = Br2/H2O and  Y = 

Benzyl chloride KCN X LiAlH4 Y

The product X and Y are -

  •  2-Phenylethanenitrile and Benzoic acid

  • Benzonitrile and Benzoic acid

  •  2-Phenylethanenitrile and 2-Phenylethanamine

  • Benzonitrile and 2-Phenylethanamine

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