Cisplatin, an anticancer drug, has the molecular formula PtNH32 Cl2. What is the mass (in gram) of one molecule? (Atomic weights : Pt=195, H=1.0, N=14, Cl=35.5)
4.98×10-21
4.98×10-22
6.55×10-21
3.85×10-22
The conversion of oxygen to ozone occurs to the extent of 15% only. The mass of ozone that can be prepared from 67.2 L oxygen at 1 atm and 273 K will be:
14.4 gm
96 gm
640 gm
64 gm
A silver coin weighing 11.34 g was dissolved in nitric acid. When sodium chloride was added to the solution all the silver (present as AgNO3) was precipitated as silver chloride. The weight of the precipitated silver chloride was 14.35 g. Calculate the percentage of silver in the coin.
4.8%
95.2%
90%
80%
Rearrange the following (I to IV) in the order of increasing masses:
(I) 0.5 mole of O3(II) 0.5 gm atom of oxygen(III) 3.011×1023 molecules of O2(IV) 5.6 liter of CO2 at STP
II<IV<III<I
II<I<IV<III
IV<II<III<I
I<II<III<IV
It is known that atom contains protons, neutrons and electrons. If the mass of neutron is assumed to half of its original value whereas that of proton is assumed to be twice of its original value then the atomic mass of C614 will be:
same
14.28% less
14.28% more
28.56% less
Nitric acid can be produced NH3 in three steps process
(I) 4NH3(g) + 5O2(g)→4NO(g) + 6H2O(g)(II) 2NO(g) + O2(g)→2NO2(g)(III) 3NO2(g) + H2O(l) → 2HNO3(aq) + NO(g)
percent yield Ist, IInd and IIIrd are respectively 50%, 60% and 80% respectively then what volume of NH3(g) at 1 atm and 0°C required to produces 1575 g of HNO3
156.25
350 L
3500 L
None of these
Density of dry air containing only N2 and O2 is 1.15 g/L at 740 mm and 300 K. What is % composition of N2 by weight in the air?
78%
75.5%
70.02%
72.75%
In preparation of iron from haematite (Fe2O3)by the reaction with carbon Fe2O3 + C → Fe + CO2How much 80% pure iron could be produced from 120 kg of 90% pure Fe2O3 ?
94.5 kg
60.48 kg
116.66 kg
120 kg
A gaseous mixture of H2 and CO2 gas contains 66 mass % of CO2. The vapour density of the mixture is:
6.1
5.4
2.7
10.8
What volume of 75% alcohol by weight (d=0.80g/cm3) must be used to prepare 150 cm3 of 30% alcohol by weight (d=0.90 g/cm3)?
67.5 mL
56.25 mL
44.44 mL
Average atomic mass of magnesium is 24.31 a.m.u. This magnesium is compound of 79 mole% of Mg24 and remaining 21 mole % of Mg25 and Mg26. Calculate mole% of Mg26.
10
11
15
16
A mixture of NH4NO3 and (NH4)2HPO4 contain 30.40% mass per cent of nitrogen. What is the mass ratio of the two components in the mixture?
2 : 1
1 : 2
3 : 4
4 : 1
A mixture of O2 and gas "Y" (mol. wt. 80) in the mole ratio a : b has a mean molecular weight 40. What would be mean molecular weight, if the gases are mixed in the ratio b : a under identical conditions? (gases are non-reacting):
40
48
62
72
If 2.74 g of the metal oxide contains 1.53 g of metal, then the empirical formula of vanadium oxide is
(Atomic Mass of V = 52)
V2O3
VO
V2O5
V2O7
A gaseous mixture of propane and butane of volume 3 litre on complete combustion produces 11.0 litre CO2 under standard conditions of temperature and pressure. The ratio of volume of butane to propane is:
3 : 2
3 : 1
The percentage by volume of C3H8 in a gaseous mixture of C3H8, CH4 and CO is 20. When 100 mL of the mixture is burnt in excess of O2, the volume of CO2 produced is
90 mL
160 mL
140 mL
The percentage of oxygen present in the compound CaCO3.3Ca3 PO42 is-
23.3%
45.36%
41.94%
17.08%
0.607 g of a silver salt of tribasic organic acid was quantitatively reduced to 0.37 g of pure Ag.What is the mol. wt. of the acid?
207
210
531
324
A gaseous compound is composed of 85.7% by mass carbon and 14.3% by mass hydrogen. It's density is 2.28 g/litre at 300 K and 1.0 atm pressure. Determine the molecular formula of the compound:
C2H2
C2H4
C4H8
C4H10
Calculate the % of free SO3 in oleum (a solution of SO3 in H2SO4) that is labelled 109% H2SO4.
30
50
None
100 mL of 10% NaOH (w/V) is added to 100 mL of 10% HCl (w/V). The resultant solution becomes:
alkaline
strongly alkaline
acidic
neutral
1.44 gram of titanium (At. wt. =48) reacted with excess of O2 and produce x gram of non-stoichiometric compound Ti1.44 O. The value of x is:
2
1.77
1.44
None of the above
2.0 g sample contain mixture of SiO2 and Fe2O3, on very strong heating leave a residue weighing 1.96 g. The reaction responsible for loss of weight is Fe2O3 s → Fe3O4 s + O2 g (unbalance equation)
What is the percentage by mass of SiO2 in original sample?
10%
20%
40%
60%
For the reaction; \(2Fe{(NO_3)}_3 + 3Na_2CO_3 \rightarrow Fe_2{(CO3)}_3 + 6NaNO_3\)Initially if 2.5 mole of \(Fe{(NO_3)}_3 \) and 3.6 mole of \(Na_2CO_3\) is taken. If 6.3 mole of \(NaNO_3\) is obtained then % yield of given reaction is:
84
87.5
100
0.8 mole of a mixture of CO and CO2 requires exactly 40 gram of NaOH in solution for complete conversion of all the CO2 into Na2CO3. How many moles more of NaOH would it require for conversion into Na2CO3, if mixture (0.8 mole) is completely oxidised to CO2?
0.2
0.6
1
1.5
The impure 6 g of NaCl is dissolved in water and then treated with excess of silver nitrate solution. The weight of precipitate of silver chloride is found to be 14 g. The % purity of NaCl solution would be:
95%
85%
75%
65%
25.4 g of I2 and 14.2 g of Cl2 are made to react completely to yield a mixture of ICI and ICI3. The mole of ICI and ICI3 formed, is respectively -
0.5, 0.2
0.1, 0.1
0.1, 0.3
0.3, 0.4
The vapour density of a mixture containing NO2 and N2O4 is 38.3. The mole of NO2 in a 100 g mixture is -
[Vapour density = (Molar mass / 2)]
0.437
0.347
0.557
0.663
Copper forms two oxides. For the same amount of copper, twice as much oxygen was used to form first oxide than to form second one. What is the ratio of the valencies of copper in first and second oxides?
2:5
1:6
2:1
1:2
5 mL of a gaseous hydrocarbon was exposed to 30 mL of O2. The resultant gas, on cooling is found to measure 25 mL of which 10 mL is absorbed by NaOH and the remainder by pyrogallol. Determine molecular formula of hydrocarbon. All measurements are made at constant room temperature.
CH4
C3H4
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