The structure of glycine (amino acid) is H3N⊕CH3C||OO⊝(zwitter ion). The correct statement among the following is-
Glycine, as well as other amino acids are amphoteric.
The acidic functional group in amino acids is -N⊕H3
The basic functional group in acids is -CO2⊝
All the statements are correct.
The above process in which a and b form remain in equilibrium with acyclic form and a change in optical rotation is observed which is called as–
Mutarotation
Epimerisation
Condensation
Inversion
How many moles of HIO4 is required to break down the following molecule?
1
2
3
4
Nitrous acid (HNO2) converts amino acids into hydroxy acids with retention of configuration.
Estimation of nitrogen gas evolved in the reaction is the basis of Van slyke estimation of amino acids. Which of the following amino acids cannot be analysed by Van slyke method?
Codes :
only I
only II
I and III
I, III, IV
Which of the following aldohexoses give the same osazone derivative ?
I and IV
II and III
III and IV
Which of the following is a non–reducing sugar ?
How many moles of acetic anhydride (Ac2O) is needed to react completely with tartaric acid, ribose, and glucose respectively?
2,4, 5
2, 3, 4
4, 5, 6
4, 5, 5
Glucose on reduction with Na/Hg and water gives-
Sorbitol
Fructose
Saccharic acid
Gluconic acid
What will be product when glycine, is heated–
O llNH2-CH-C-NH-CH2-CO2H l CH3
Identify the amino acid obtained by hydrolysis of the above compound :-
Glycine
Alanine
Both (1) and (2)
None of the above
At iso-electric point:
conc. of cation is equal to conc of anion
Net charge is zero.
Maximum conc. of di-polar ion (Zwitterion) will be present
All of the above
Which of the following amino acid has lowest iso-electric point?
Aspartic acid
Lysine
Find iso-electric point of given amino acid
CH3—CH—CO2H | N⊕H3pKa = 2.2 pKb = 4.4
3.3
5.9
9.6
11.8
Find an iso-electric point of the given amino acid
O ||H - O-C -CH2 - CH2 -CH - CO2H (pKa = 2) | NH3 (pKa = 4) ( p⊕Ka = 9)
5.5
6.5
5
H-C≡C-H →H2SO4HgSO4A →(2)H3O⊕1NH3+HCN(B) Product (B) of given reaction is:
valine
Leucine
Which amino acid does not contain a chiral center?
Valine
Iso-leucine
Which of the following pair gives same phenyl osazone ?
D-Glucose and D-Allose
D-Glucose and D-Alfrose
D-Glucose and D-Mannose
D-Glucose and D-Talose
Among the three compounds shown below, two yield the same product on reaction with warm HNO3. The exception is:-
For the complex conversion of D-glucose into the corresponding osazone, the minimum number of equivalents of phenyl hydrazine required is :
two
three
four
five
Which one of the following compounds will form an osazone derivative ?
CH3CH2COCH2OH
CH3COCH2CH2OH
CH3CH2CHOHCH2OH
CH3CH2COCH2OCH3
The configuration of the chirality centers in D-threose (shown) are:
2R, 3R
2R, 3S
2S, 3R
2S, 3S
Myoglobin is a
Catalyst for epoxidation reaction
Component in a photosynthetic system
Nitrogen fixation enzyme
Di-oxygen binding metalloprotein
Which of the following Fischer projection formula is same as D-Glyceraldehyde ?
Which reagent/s can be used to distinguish glucose and fructose?(I) Bromine water (II) furfural test(III) Schiff’s reagent
(I), (II) and (III)
(II) and (III)
(I) & (II)
Only (Ill)
Proteins mainly contain:
C, H, O and N
only C and H
C, H and O
N and H
In the human body, enzymes hydrolyse protein into:
a ketonic acid-like CH3COCOOH
a hydroxy acid like CH3CHOHCOOH
dicarboxylic acid-like HOOC—COOH
amino acid-like CH2NH2COOH
Which statement about protein is wrong?
Proteins occur in all living cells
Proteins invariably contain N, O, C and H
Proteins are synthesized by plant kingdom only
Proteins are also synthesized in laboratory
The main structural feature of protein is:
the ester linkage
the ether linkage
the peptide linkage
all of these
Proteins give ?
a violet colour with alkaline CuSO4 solution
form a purple colour on boiling with dilute ninhydrin solution
yellow colour on boiling with HNO3
all of the above
Which of the following is proteolytic enzyme?
Insulin
Diastase
Pepsin
Adenine
Please disable the adBlock and continue. Thank you.