The strongest hydrogen bond present among the following is-
O—H‐‐‐S
S—H‐‐‐O
F—H‐‐‐F
F—H‐‐‐O
Which of the following is the most basic oxide?
Al2O3
Sb2O3
Bi2O3
SeO2
In which of the process, the bond order increases and magnetic behaviour changes?
() N2→N2+
() C2→C2+
() NO→NO+
() O2→O2+
Among the following, which has the maximum hydration energy?
OH-
NH4+
F-
H+
Among the following oxides, which has the maximum lattice energy?
Which of the following pairs of species have similar shapes?
PCl3, NH3
CF4, SF4
PbCl2, CO2
PF5, IF5
Incorrect statement about resonance is :
The resonating structures are hypothetical.
The unpaired electrons in various resonating structures are same.
Hybrid structure is most energetic.
Hybrid structure is least energetic.
Which of the following species deviates from the octet rule?
CO32-
H2SO3
PCl3
O3
Which of the following species has a bent T-shape?
ICl4-
BrF3
I3-
In piperidine "N" atom has hybridization:
sp
sp2
sp3
dsp2
According to molecular orbital theory which of the following lists rank the nitrogen species in terms of increasing bond order ?
N2- < N2 < N22-
N22- < N2- < N2
N2 < N22- < N2-
N2- < N22- < N2
The correct order of increasing bond length of
C-H, C-O, C-C and C=C is
C-C<C=C<C-O<C-H
C-O<C-H<C-C<C=C
C-H<C-O<C-C<C=C
C-H<C=C<C-O<C-C
An element X is placed in group IA of the periodic table because it forms:
An oxide which is acid
A volatile chloride having formula XCl2
An ionic chloride having formula XCl
An insoluble chloride XCl4
Which of the following would have a permanent dipole moment ?
BF3
SiF4
SF4
XeF4
In the case of alkali metals, the covalent character decreases in the order
MCl > MI > MBr > MF
MF > MCl > MBr > MI
MF > MCl > MI > MBr
MI > MBr > MCl > MF
Which of the following two are isostructural?
XeF2, and IF2-
NH3, and BF3
CO2, and SiO2
PCl5, and IF5
Which one of the following species does not exist?
Be2+
Be2
B2
N2
Which one of the following is not paramagnetic ?
NO
N2+
CO
O2-
In a regular octahedral molecule MX6, the number of X-M-X bonds at 180° is-
3
2
6
4
Which of the following is not isostructural with SiCl4?
SCl4
SO42-
PO43-
In which of the following species the central atom has the type of hybridisation which is not the same as that present in the other three ?
SbCl52-
PCl5
Which of the following has pπ -dπ bonding?
4.CO32-
NO3-
SO32-
BO33-
In BrF3 molecule, the lone pairs occupy equatorial positions to minimize:
Lone pair-bond pair repulsion.
Bond pair-bond pair repulsion.
Lone pair-lone pair repulsion and lone pair-bond pair repulsion.
Lone pair-lone pair repulsion.
In which one of the following molecules, the central atom said to adopt sp2 hybridisation ?
BeF2
C2H2
NH3
Among the following molecules/ions BF3, NO2-, NH2- , and H2O, the central atom is sp2 hybridized in :
3. NO2- and H2O
NO2- and NH2-
NH2- and H2O
4. BF3 and NO2-
Which one of the following is planar ?
XeO4
XeO3
XeO3F2
In PO43- ion, the formal charge on each oxygen atom and P-O bond order respectively are :
-0.75, 0.6
-0.75, 1.0
-0.75, 1.25
-3.1, 1.25
The dielectric constant of H2O is 80. The electrostatic force of attraction between Na+ and Cl- will be
reduced to 140 in water than in air
reduced to 180 in water than in air
will be increased to 80 in water than in air
will remain unchanged
Which of the following is isoelectronic?
CO2, NO2
NO2-, CO2
CN-, CO
SO2, CO2
The correct order of the increasing bond angles in the following triatomic species is :
2. NO2- < NO2 < NO2+
NO2-< NO2+ < NO2
3. NO2+ < NO2 < NO2-
NO2+ < NO2- < NO2
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