Which of the following has the minimum bond length?
O2
O2-
O22-
O2+
Which of the following are isoelectronic and isostructural?
NO3-, CO3-2, ClO3-, SO3
NO3-, CO3-2
SO3, NO3-
ClO3-, CO3-2
CO3-2, ClO3-
Which of the following has largest bond angle.
H2O
F2O
Cl2O
H2S
In the molecular orbital diagram for O2+ ion. the HOMO is :-
σ MO orbital
π MO orbital
π* MO orbital
σ* MO orbital
The correct order of H-bond strength in the following compounds is:
H2O > H2O2 > HF > H2S
HF > H2O2 > H2O > H2S
HF > H2O > H2S > H2O2
HF > H2O > H2O2 > H2S
A pair of species that have identical shapes is :
NO2+ and NO2-
PCl5 and BrF5
XeF4 and ICI4-
TeCl4 and XeO4
Which of the following is correct :-
Extent of hydration is PCl5 > SiCl4 and BCl3 < CCl4
K+ ion will be more Hydrated than Li+
In BCl3 there are no vacant d-orbitals but still it can undergo expansion
None
Carbon atom in C2(CN)4 are
sp hybridised
sp2 hybridised
sp and sp2 hybridised
sp, sp2 and sp3 hybridised
The correct order in which the O-O bond length increases in the following is
H2O2 < O2 < O3
O3 < H2O < O2
O2 < O3< H2O2
O2 < H2O2 < O3
Carbon suboxide (C3O2) has
Linear structure
Bent structure
Trigonal structure
Disorted tetrahedral structure
N2 and O2 are converted to monocations N2+ and O2+ respectively. Which of the following is incorrect?
In N2+, the N-N bond weakens.
In O2+, the O-O bond order increases.
In O2+, the paramagnetism decreases.
N2+ becomes diamagnetic.
The species, having bond angles of 120° is :
PH3
ClF3
NCl3
3. BCl3
Which of the following pairs of compounds is isoelectronic and isostructural?
Which one of the following pairs of species have the same bond order?
CO, NO
O2- , CN-
CN- , NO+
N+ , CN+
In which of the following compounds is an intramolecular hydrogen bond present?
H2O2
HCN
Cellulose
Concentrated acetic acid
The hybridisations of atomic orbitals of nitrogen in NO2+, NO3- and NH4+ are
(a) sp, sp3 and sp2 (b) sp2, sp3 and sp
(c) sp, sp2 and sp3 (d) sp2, sp and sp3
The correct shape and hybridisation for XeF4 are
octahedral, sp3d2
trigonal bipyramidal, sp3d2
planar triangle, sp3d3
square planar, sp3d2
In which of the following molecules, all atoms are coplanar ?
Predict the correct order among the following.
lone pair-lone pair>bond pair-bond pair>lone pair-bond pair
bond pair-bond pair>lone pair-bond pair>lone pair-lone pair
lone pair-bond pair>bond pair-bond pair>lone pair-lone pair
lone pair-lone pair>lone pair-bond pair>bond pair-bond pair
The pair of electrons in the given carbanion, CH3C≡C-, is present in which of the following orbitals?
sp3
sp2
sp
2p
Consider the molecules CH4, NH3, and H2O. The incorrect statement among the following is -
The H-O-H bond angle in H2O is larger than the H-C-H bond angle in CH4
The H-O-H bond angle in H2O is smaller than the H-N-H bond angle in NH3
The H-C-H bond angle in CH4 is larger than the H-N-H bond angle in NH3
The H-C-H bond angle in CH4, the H-N-H bond angle in NH3, and the H-O-H bond angle in H2O are all greater than 90°
Which of the following species contains equal number of σ and π bonds?
HCO3-
XeO4
(CN)2
CH2(CN)2
The correct bond order in the following species is
O22+>O2+>O2-
O22+<O2-<O2+
O2+>O2-<O22+
O2-<O2+>O22+
The total number of π-bond electrons in the following structure is
2. 8
4
3. 12
16
In which of the following pairs, both the species are not isostructural?
SiCl4, PCl4+
Diamond, silicon carbide
NH3, PH3
XeF4, XeO4
Decreasing order of stability of O2, O2-, O2+ and O22- is
O2+ > O2 > O2- > O22-
O22- > O2- > O2 > O2+
O2 > O2+ > O22- > O2-
O2- > O22- > O2+ > O2
Aqueous solution of which of the following compounds is the best conductor of electric
current?
Acetic acid, C2H4O2
Hydrochloric acid, HCl
Ammonia, NH3
Fructose, C6H12O6
A molecule having the maximum dipole moment among the following is -
CO2
CH4
NH3
NF3
Which among the following species has a triangular planar shape?
N3-
NO3-
NO2-
Dipole-induced dipole interactions are present in which of the following pairs?
H2O and alcohol
Cl2 and CCl4
HCl and He atoms
SiF4 and He atoms
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