Which of the following has the minimum bond length?

  • O2

  • O2-

  •  O22-

  • O2+

Which of the following are isoelectronic and isostructural?

NO3-, CO3-2, ClO3-, SO3

  •  NO3-, CO3-2

  •  SO3, NO3-

  •  ClO3-, CO3-2

  •  CO3-2, ClO3-

Which of the following has largest bond angle.

  • H2O

  • F2O

  • Cl2O

  • H2S

In the molecular orbital diagram for O2+ ion. the HOMO is :-

  •  σ MO orbital

  •  π MO orbital

  •   π* MO orbital

  •  σ* MO orbital

The correct order of H-bond strength in the following compounds is:

  • H2O > H2O2 > HF > H2S

  • HF >  H2O2 > H2O > H2S

  • HF > H2O > H2S > H2O2

  • HF > H2O > H2O2 > H2S

 A pair of species that have identical shapes is : 

  • NO2+ and NO2-

  • PCl5 and BrF5

  • XeF4 and ICI4-

  • TeCl4 and XeO4

Which of the following is correct :-

  • Extent of hydration is PCl5 > SiCl4 and BCl3 < CCl4

  • K+ ion will be more Hydrated than Li+

  • In BCl3 there are no vacant d-orbitals but still it can undergo expansion

  • None

Carbon atom in C2(CN)4 are

  • sp hybridised

  • sp2 hybridised

  • sp and sp2 hybridised

  • sp, sp2 and sp3 hybridised

The correct order in which the O-O bond length increases in the following is

  • H2O2 < O2 < O3

  • O3 < H2O < O2

  • O2 < O3< H2O2

  • O2 < H2O2 < O3

Carbon suboxide (C3O2) has

  • Linear structure

  • Bent structure

  • Trigonal structure

  • Disorted tetrahedral structure

N2 and O2 are converted to monocations N2+ and O2+ respectively. Which of the following is incorrect?

  • In N2+, the N-N bond weakens.

  • In O2+, the O-O bond order increases.

  • In O2+, the paramagnetism decreases.

  •  N2+ becomes diamagnetic.

The species, having bond angles of 120° is : 

  • PH

  • ClF3

  • NCl3

  • 3. BCl3

Which of the following pairs of compounds is isoelectronic and isostructural?

  • BeCl2, XeF2
  • Tel2, XeF2
  • IBr2-XeF2
  • IF3, XeF2

Which one of the following pairs of species have the same bond order?

  • CO, NO

  • O2-  , CN-

  • CN- , NO+

  • N+ , CN+

In which of the following compounds is an intramolecular hydrogen bond present?

  • H2O2                                 

  • HCN

  • Cellulose                             

  • Concentrated acetic acid

The hybridisations of atomic orbitals of nitrogen in NO2+, NO3- and NH4+ are

(a) sp, sp3 and sp2               (b) sp2, sp3 and sp

(c) sp, sp2 and sp3               (d) sp2, sp and sp3

  • 1
  • 2
  • 3
  • 4

The correct shape and hybridisation for XeF4 are

  • octahedral, sp3d2

  • trigonal bipyramidal, sp3d2

  • planar triangle, sp3d3

  • square planar, sp3d2

In which of the following molecules, all atoms are coplanar ?

  • 1
  • 2
  • 3
  • 4

Predict the correct order among the following.

  • lone pair-lone pair>bond pair-bond pair>lone pair-bond pair

  • bond pair-bond pair>lone pair-bond pair>lone pair-lone pair

  • lone pair-bond pair>bond pair-bond pair>lone pair-lone pair

  • lone pair-lone pair>lone pair-bond pair>bond pair-bond pair

The pair of electrons in the given carbanion, CH3CC-, is present in which of the following orbitals?

  •  sp3

  •  sp2

  •  sp

  • 2p 

Consider the molecules CH4, NH3, and H2O. The incorrect statement among the following is -

  • The H-O-H bond angle in H2O is larger than the H-C-H bond angle in CH4

  • The H-O-H bond angle in H2O is smaller than the H-N-H bond angle in NH3

  • The H-C-H bond angle in CH4 is larger than the H-N-H bond angle in NH3

  • The H-C-H bond angle in CH4, the H-N-H bond angle in NH3, and the H-O-H bond angle in H2O are all greater than 90°

Which of the following species contains equal number of σ and π bonds?

  •  HCO3-                                   

  • XeO4

  • (CN)2                                     

  • CH2(CN)2

The correct bond order in the following species is

  •  O22+>O2+>O2-

  •  O22+<O2-<O2+

  •  O2+>O2-<O22+

  •  O2-<O2+>O22+

The total number of π-bond electrons in the following structure is

2. 8         

 

 

  • 4       

  • 3. 12         

  • 3
  • 16

In which of the following pairs, both the species are not isostructural?

  •  SiCl4, PCl4+

  • Diamond, silicon carbide

  •  NH3, PH3

  •  XeF4, XeO4

Decreasing order of stability of O2, O2-, O2+ and O22- is

  •  O2+ > O2 > O2- > O22-

  •  O22- > O2- > O2 > O2+

  •  O2 > O2+ > O22- > O2-

  •  O2- > O22- > O2+ > O2

Aqueous solution of which of the following compounds is the best conductor of electric

current?

  • Acetic acid, C2H4O2

  • Hydrochloric acid, HCl

  • Ammonia, NH3

  • Fructose, C6H12O6

A molecule having the maximum dipole moment among the following is -

  • CO2

  • CH4

  • NH3

  • NF3

Which among the following species has a triangular planar shape?

  • N3-    

  • NO3- 

  • NO2-

  • CO2

Dipole-induced dipole interactions are present in which of the following pairs?

  • H2O and alcohol                       

  • Cl2 and CCl4

  • HCl and He atoms                     

  • SiF4 and He atoms

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