Which of the following is paramagnetic?

  • CO               

  •  O2-

  • CN              

  • NO+

The correct order of solubility in an aqueous medium is: 

  • CuS > ZnS > Na2S

  • ZnS > Na2S > CuS

  • Na2S > CuS > ZnS

  • Na2S > ZnS > CuS

XeF2 is isostructural with : 

  • TeF2

  • ICI2-

  • SbCl3

  • BCl3

Which one of the following molecules contain no π -bond?

  • CO2

  • H2O

  • SO2

  • NO2

Which one of he following pairs is isostructural (i.e., having the same shape and

hybridization)?

  • [BCl3 and BrCl3]

  • [NH3 and NO3-]

  • [NF3 and BF3]

  • [BF4- and NH4+]

Considering the state of hybridisation of carbon atoms, find out the molecule among the

following which is linear.

  • HC≡CH

  • CH2 = CH—CH2—C = CH

  • CH3 — CH2 — CH2 — CH3

  • CH3—CH = CH—CH3

In which of the following pairs of molecules/ions, the central atoms have sp2 hybridisation?

1. NO2- and NH3                    2. BF3 and NO2-3. NH2- and H2O                     4. BF3 and NH2-

  • 1
  • 2
  • 3
  • 4

The correct increasing order of bond angles in the following species is:

2. ClO< Cl2O < ClO2-

  • Cl2O < ClOClO2-

  • 4. ClO2- < Cl2O < ClO2   

  • Cl2O < ClO2- < ClO2

  • 4

The tendency of BF3, BCl3, and BBr3 to behave as Lewis acid decreases in the sequence

  • BCl3 > BF3 > BBr3

  • BBr3 > BCI3 > BF3

  • BBr3 > BF3 > BCl3

  • BF3 > BCl3 > BBr3

Given the following hydrocarbon:
   
The state of hybridisation of carbons marked 2, 3, 5 and 6 in the following hydrocarbon are, respectively :

  • sp, sp3, sp2 and sp3

  • sp3, sp2, sp2 and sp

  • sp, sp2, sp2 and sp3

  • sp, sp2 sp3 and sp2

What is the dominant intermolecular force on bond that must be overcome in converting

liquid CH3OH to a gas?

  • Hydrogen bonding

  • Dipole-dipole interaction

  • Covalent bonds

  • London dispersion force

The angular shape of ozone molecule (O3) consists of

  • 1 sigma and 2 pi bonds

  • 2 sigma and 2 pi bonds

  • 1 sigma and 1 pi bonds

  • 2 sigma and 1 pi bonds

In the hydrocarbon

     CH3-CH=CH-CH2-CCH

The state of hybridisation of carbons 1,3 and 5 are in the following sequence

  • sp2, sp, sp3                       

    (2) sp, sp3, sp2

  •      6      5     4   3      2    1

  • sp, sp2, sp3                       

    (4) sp3, sp2, sp

  • 4

The correct order of increasing thermal stability of K2CO3, MgCO3, CaCO3 and BeCOis:

  • BeCO3 < MgCO3 < K2CO< CaCO3

  • BeCO3 < MgCO3 < CaCO3 < K2CO3

  • MgCO3 < BeCO3 < CaCO3 < K2CO3

  • K2CO3 < MgCO3 < CaCO3 < BeCO3

Which among the following compounds has higher hydration energy than the lattice energy?

  • BaSO4                           

  • MgSO4

  • CaSO4                           

  • SrSO4

In which of the following molecules are all the bonds not equal ?

  • ClF3

  • BF3

  • AlF3

  • NF3

The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:

  • in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction

  • in NH3 the atomic dipole and bond dipole are in the same direction whereas in NFthese are in opposite directions
  • in NH3 as well as NF3 the atomic dipole and bond dipole are in opposite directions
  • in NH3 the atomic dipole and bond dipole are in the opposite directions whereas in NF3 these are in the same directions

The correct order of electronegativity of hybrid orbitals of carbon is:

  • sp>sp2<sp3             

    (2) sp>sp2>sp3

  • 2
  • sp<sp2>sp3             

    (4) sp<sp2<sp3

  • 4

Which of the following species has a linear shape?

  •  NO2-

  • SO2

  •  NO2+

  • O3

Which of the following is the most basic oxide?

  • Al2O3

  • Sb2O3

  • Bi2O3

  • SeO2

Which of the following is not a correct statement?

  • The electron-deficient molecules can act as Lewis acids

  • The canonical structures have no real existence

  • Every AB5 molecule does, in fact, have square pyramid structure

  • Multiple bonds are always shorter than corresponding single bonds

The number unpaired electrons in a paramagnetic diatomic molecule of an element with atomic number 16 is :

  • 2

  • 3

  • 4

  • 1

Which of the following is not isostructural with SiCl4?

(a) SCl4            (b) SO42-               (c) PO43-                 (d) NH4+

  • 1
  • 2
  • 3
  • 4

Least stable hydride is:

  • stannane 

    (2) silane 

    (3)  plumbane 

    (4) germane

  • 2
  • 3
  • 4

Correct order of strength of H-bond in the following compounds is : 

  

  •  H2O  > H2O2 > HF > H2S 

  •  HF  H2O2 > H2O > H2S

  • HF >H2O > H2S > H2O2

  • HF >H2O2 > H2O > H2S

Molecule having non-polar as well as polar bonds but the molecule as a whole is polar:

  • () S2F2 

  • () N2O4

  • () Si2H6                                           

  • () I2Cl6

Choose the correct statement regarding SeOCl2 molecule:

  •  It does not contain a plane of symmetry

  •  'Cl-Se^-Cl' bond is greater than 'Cl-Se^-O' bond angle

  •  Lone pair has greater than 33.3% s-character

  •   Central atom used one d-orbital in bonding.

Which of the following compounds can form H-bonding with each other? 

  • () CH3 COOH and H2O

  • () Phenol and CH4

  • () CHF3 and acetone

  • () PH3 and HF

Which of the following compound is planar and non-polar?

  •  Xe O4

  •  Sf4

  •  Xe f4

  •  Cf4

The incorrect statement(s) regarding CX3 species is:

  • If electronegativity of surrounding element 'X' is less than 2.5, then central carbon atom used almost 33% s-character in their hybrid bonding orbitals

  •  If electronegativity of surrounding element 'X' is more than 2.5, then central carbon atom used almost 25% s-character in their hybrid bonding orbitals

  • If 'X' is 'F', then species should be polar and pyramidal

  • If 'X' is H, then species should be polar and planar

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