Which of the following is paramagnetic?
CO
O2-
CN-
NO+
The correct order of solubility in an aqueous medium is:
CuS > ZnS > Na2S
ZnS > Na2S > CuS
Na2S > CuS > ZnS
Na2S > ZnS > CuS
XeF2 is isostructural with :
TeF2
ICI2-
SbCl3
BCl3
Which one of the following molecules contain no π -bond?
CO2
H2O
SO2
NO2
Which one of he following pairs is isostructural (i.e., having the same shape and
hybridization)?
[BCl3 and BrCl3]
[NH3 and NO3-]
[NF3 and BF3]
[BF4- and NH4+]
Considering the state of hybridisation of carbon atoms, find out the molecule among the
following which is linear.
HC≡CH
CH2 = CH—CH2—C = CH
CH3 — CH2 — CH2 — CH3
CH3—CH = CH—CH3
In which of the following pairs of molecules/ions, the central atoms have sp2 hybridisation?
1. NO2- and NH3 2. BF3 and NO2-3. NH2- and H2O 4. BF3 and NH2-
The correct increasing order of bond angles in the following species is:
2. ClO2 < Cl2O < ClO2-
Cl2O < ClO2 < ClO2-
4. ClO2- < Cl2O < ClO2
Cl2O < ClO2- < ClO2
The tendency of BF3, BCl3, and BBr3 to behave as Lewis acid decreases in the sequence
BCl3 > BF3 > BBr3
BBr3 > BCI3 > BF3
BBr3 > BF3 > BCl3
BF3 > BCl3 > BBr3
Given the following hydrocarbon: The state of hybridisation of carbons marked 2, 3, 5 and 6 in the following hydrocarbon are, respectively :
sp, sp3, sp2 and sp3
sp3, sp2, sp2 and sp
sp, sp2, sp2 and sp3
sp, sp2 sp3 and sp2
What is the dominant intermolecular force on bond that must be overcome in converting
liquid CH3OH to a gas?
Hydrogen bonding
Dipole-dipole interaction
Covalent bonds
London dispersion force
The angular shape of ozone molecule (O3) consists of
1 sigma and 2 pi bonds
2 sigma and 2 pi bonds
1 sigma and 1 pi bonds
2 sigma and 1 pi bonds
In the hydrocarbon
CH3-CH=CH-CH2-C≡CH
The state of hybridisation of carbons 1,3 and 5 are in the following sequence
sp2, sp, sp3
(2) sp, sp3, sp2
6 5 4 3 2 1
sp, sp2, sp3
(4) sp3, sp2, sp
The correct order of increasing thermal stability of K2CO3, MgCO3, CaCO3 and BeCO3 is:
BeCO3 < MgCO3 < CaCO3 < K2CO3
MgCO3 < BeCO3 < CaCO3 < K2CO3
K2CO3 < MgCO3 < CaCO3 < BeCO3
Which among the following compounds has higher hydration energy than the lattice energy?
BaSO4
MgSO4
CaSO4
SrSO4
In which of the following molecules are all the bonds not equal ?
ClF3
BF3
AlF3
NF3
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because:
in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction
The correct order of electronegativity of hybrid orbitals of carbon is:
sp>sp2<sp3
(2) sp>sp2>sp3
sp<sp2>sp3
(4) sp<sp2<sp3
Which of the following species has a linear shape?
NO2-
NO2+
O3
Which of the following is the most basic oxide?
Sb2O3
Bi2O3
SeO2
Which of the following is not a correct statement?
The electron-deficient molecules can act as Lewis acids
The canonical structures have no real existence
Every AB5 molecule does, in fact, have square pyramid structure
Multiple bonds are always shorter than corresponding single bonds
The number unpaired electrons in a paramagnetic diatomic molecule of an element with atomic number 16 is :
2
3
4
1
Which of the following is not isostructural with SiCl4?
(a) SCl4 (b) SO42- (c) PO43- (d) NH4+
Least stable hydride is:
stannane
(2) silane
(3) plumbane
(4) germane
Correct order of strength of H-bond in the following compounds is :
H2O > H2O2 > HF > H2S
HF ≥ H2O2 > H2O > H2S
HF > H2O > H2S > H2O2
HF > H2O2 > H2O > H2S
Molecule having non-polar as well as polar bonds but the molecule as a whole is polar:
() S2F2
() N2O4
() Si2H6
() I2Cl6
Choose the correct statement regarding SeOCl2 molecule:
It does not contain a plane of symmetry
'Cl-Se^-Cl' bond is greater than 'Cl-Se^-O' bond angle
Lone pair has greater than 33.3% s-character
Central atom used one d-orbital in bonding.
Which of the following compounds can form H-bonding with each other?
() CH3 COOH and H2O
() Phenol and CH4
() CHF3 and acetone
() PH3 and HF
Which of the following compound is planar and non-polar?
Xe O4
Sf4
Xe f4
Cf4
The incorrect statement(s) regarding CX3 species is:
If electronegativity of surrounding element 'X' is less than 2.5, then central carbon atom used almost 33% s-character in their hybrid bonding orbitals
If electronegativity of surrounding element 'X' is more than 2.5, then central carbon atom used almost 25% s-character in their hybrid bonding orbitals
If 'X' is 'F', then species should be polar and pyramidal
If 'X' is H, then species should be polar and planar
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