H2O has a net dipole moment while BeF2 has zero dipole moment because :
F is more electronegativity than oxygen
Be is more electronegativity than oxygen
H2O molecule is linear and BeF2 is bent
BeF2 molecule is linear and H2O is bent
Which of the following overlops is incorrect (assuming Z axis internuclear axis)?
(A) 2py +2py→π‐Bond formation (B) 2px+2px→σ‐Bond formation
(C) 3dxy+3dxy→π‐ Bond formation (D) 2s+2py→π‐Bond formation
(E)3dxy+3dxy→δBond formation (F)2pz+2pz→σ Bond formation
(a) A,B,C (b) C,F
(c) B,E (D) B,C,D
How many sigma bonds are in a molecule of diethyl ether, C2H5OC2H5
14
12
8
16
The bond having the highest bond energy is :
C=C
C=S
C=O
P=N
Which of the following species has a zero dipole moment?
(i) CO2 (ii) COCl2 (iii) CH2 Cl2 (iv) BCl3
(i) and (iv)
(ii) and (iv)
(iii) and (iv)
(i), (iii) and (iv)
The correct statement about carbene (CH2) is:
In singlet carbene, carbon is sp2-hybridized whereas in triplet carbene, carbon is sp-hybridized
Triplet carbene is less stable than singlet carbene
Stability of halocarbenes is: CHF>CHCL>CHBr
None of the above
Which of the following is a pair of polar molecules?
CO2 and H2O
BF3 and PCl3
SO2 and SCl2
CS2 and SO3
In which molecule does the chlorine atom has positive partial charge?
HCl
BrCl
OCl2
SCl2
The incorrect order of lattice energy among the following set is:
AlF3>MgF2
Li3N>Li2O
NaCl>LiF
TiC>ScN
Which of the following set of species have planar structures?
() I3-, CH3, CLO3-, SiF62-
() I3+, ICl4-, Al2Cl6, TeCl4
() SCl2, N2O5, SF4,XeOF4
() I2Cl6, XeF2, BrF4-
Both NSiH33 and NHSiH32compounds have trigonal planer skeleton. Incorrect statement about both compound is :
SiNSi bond angle in NHSiH32 > SiNSi bond angle in NSiH33
N-Si bond length in NHSiH32>N-Si bond length in NSiH33
N-Si bond length in NHSiH32<N-Si bond length in NSiH33
Back bonding strength in NHSiH32> Back bonding strength in NSiH33
Which ionic compound has the largest amount of lattice energy?
(a) NaF (b)AlF3 (c)AIN (d)MgF2
The incorrect statement regarding OSiH32 and OCl2 molecule is/are:
The strength of back bonding is more in OSiH32 molecule than OCl2 molecule
Si—O—Si bond angle in OSiH32 is greater than Cl—O—Cl bond angle in OCl2
The nature of back bond in both molecules is 2pσ‐3dπ
Hybridisation of central O‐atom in both molecules is same
Which of the following compound have the same no. of lone pair with their central atom?
(i) XeF5-
(ii) BrF3
(iii) XeF2
(iv) H3S+
(v) Triple Methylene
options are as follows :
(iv) and (v)
(i) and (iii)
(i) and (ii)
(ii) (iv), (v)
The incorrect order of the force of attraction among the given species is -
HI > HBr> Cl2
CCl4>CH2Cl2>CH3Cl>CH4
n- Pentane > iso-Pentane > neo-Pentane
OH2>OCH32>OBr2
The "O-N-O" bond angle is maximum in:
(a) N2O (b)NO2+ CNO2- (d) NO3-
Among following molecule N—Si bond length is shortest:
N(SiH3)3
(2) N(SiH3)2
NH2(SiH3)
(4) All have equal N—Si bond length
The geometry with respect to the central atom of the following molecules are:
N(SiH3)3; Me3N; (SiH3)3 P
planar, pyramidal, planar
planar, pyramidal, pyramidal
pyramidal, pyramidal, pyramidal
pyramidal, planer, pyramidal
Incorrect statement regarding BF2NH2 molecule is :
FBF bond angle <120%
HNH bond angle >109°28'
Exhibits intermolecular H-bond
Hybridization of N-atom is sp3
Molecule that has μ (observed) greater than μ (theoretical) is :
CHCl3
The bond having minimum bond energy is :
C—C
(2) O—O
S—S
(4) P—P
A gas that should not be collected over water is-
H2
N2
CH4
The correct increasing order of extent of hydrolysis is :
(a) CCl4<MgCl2<AlCl3<SiCl4<PCl5 (b) CCl4<AlCl3<MgCl2<PCl5<SiCl4
(c) CCl4<SiCl4<PCl5<AlCl3<mgCl2 (d) CCl4<PCl5<SiCl4<AlCl3<MgCl2
Inorganic benzene reacts with HCl to form a compound B3N3H9Cl3. The protonation occurs at:
B-atom
N-atom
First at B-atom then rearrangers into N-atom
First N-atom then rearrangers into B-atom
The correct order of initials T or F for the following statements is -
(Use T if statement is true and F if it is false)
(i)(CH3)2P(CF3)3 is non-polar (CH3)3P(CF3)2 is polar molecule
(ii) CH3P^CH3 bond angles are equal in a molecule
(iii) PF3 will be more soluble in the polar solvent than SiF4
TTF
FFT
FFF
FTT
Which substance has the strongest London dispersion forces?
SiH4
SnH4
GeH4
The compound that has the lowest boiling point is-
HF
HBr
HI
Which of the following is the correct order for increasing bond angle?
(a) NH3<PH3<AsH3<SbH3 (b)H2O<OF2<Cl2O(c) H3Te+<H3Se+<H3S+<H3O+ (d) BF3<BCI3<BBr3<BI3
The correct statement about hydrolysis of BCl3 and NCl3 is-
NCl3 is hydrolysed and gives HOCl but BCl3 is not hydrolysed
Both NCl3 and BCl3 on hydrolysis gives HCl
NCl3 on hydrolysis gives HOCl but BCl3 gives HCl
Both NCl3 and BCl3 on hydrolysis gives HOCl
a. Benzene
b. Inorganic Benzene
c. PCl3F2
d. PCl2F3
The correct sequence of the polarity of the following molecule is -
a b c d
(Where P=polar, NP=non-polar)
P NP NP P
NP NP NP P
NP P NP P
NP P P NP
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