H2O has a net dipole moment while BeF2 has zero dipole moment because :

  • F is more electronegativity than oxygen 

  • Be is more electronegativity than oxygen 

  •  H2O  molecule is linear and BeF2 is bent 

  •  BeF2 molecule is linear and H2O is bent

Which of the following overlops is incorrect (assuming Z axis internuclear axis)?

(A) 2py +2pyπBond formation        (B) 2px+2pxσBond formation

(C) 3dxy+3dxyπ Bond formation        (D) 2s+2pyπBond formation

(E)3dxy+3dxyδBond formation             (F)2pz+2pzσ Bond formation

(a) A,B,C                      (b) C,F

(c) B,E                         (D) B,C,D

  • 1
  • 2
  • 3
  • 4

How many sigma bonds are in a molecule of diethyl ether, C2H5OC2H5

  • 14         

  • 12         

  • 8         

  • 16

The bond having the highest bond energy is :

  • C=C 

  • C=S

  • C=O

  • P=N

Which of the following species has a zero dipole moment?

(i) CO2 (ii) COCl2 (iii) CH2 Cl2 (iv) BCl3

  • (i) and (iv) 

  • (ii) and (iv) 

  • (iii) and (iv) 

  • (i), (iii) and (iv) 

The correct statement about carbene (CH2) is:

  • In singlet carbene, carbon is sp2-hybridized whereas in triplet carbene, carbon is sp-hybridized

  • Triplet carbene is less stable than singlet carbene

  • Stability of halocarbenes is: CHF>CHCL>CHBr

  • None of the above

Which of the following is a pair of polar molecules?

  •  CO2 and H2O

  •  BF3 and PCl3

  •  SO2 and SCl2

  •  CS2 and SO3

In which molecule does the chlorine atom has positive partial charge? 

  • HCl

  • BrCl 

  •  OCl2

  •  SCl2

The incorrect order of lattice energy among the following set is:

  •  AlF3>MgF2         

  •  Li3N>Li2O

  •  NaCl>LiF           

  •  TiC>ScN

Which of the following set of species have planar structures?

  • () I3-, CH3, CLO3-, SiF62-

  • () I3+, ICl4-, Al2Cl6, TeCl4

  • () SCl2, N2O5, SF4,XeOF4

  • () I2Cl6, XeF2, BrF4-

Both NSiH33 and NHSiH32compounds have trigonal planer skeleton. Incorrect statement about both compound is :

  • SiNSi bond angle in NHSiH32 > SiNSi bond angle in NSiH33

  •  N-Si bond length in NHSiH32>N-Si bond length in NSiH33

  •  N-Si bond length in NHSiH32<N-Si bond length in NSiH33

  • Back bonding strength in NHSiH32> Back bonding strength in NSiH33

Which ionic compound has the largest amount of lattice energy?

(a) NaF                      (b)AlF3  (c)AIN                       (d)MgF2

  • 1
  • 2
  • 3
  • 4

The incorrect statement regarding OSiH32 and OCl2 molecule is/are:

  • The strength of back bonding is more in OSiH32 molecule than OCl2 molecule

  •  SiOSi bond angle in OSiH32 is greater than ClOCl bond angle in OCl2

  • The nature of back bond in both molecules is 2pσ3dπ

  • Hybridisation of central Oatom in both molecules is same

Which of the following compound have the same no. of lone pair with their central atom?

(i) XeF5-              

(ii) BrF3                 

(iii) XeF2                     

(iv) H3S+               

(v) Triple Methylene     

options are as follows :        

  • (iv) and (v)                                     

  • (i) and (iii) 

  • (i) and (ii)                                     

  • (ii) (iv), (v)

The incorrect order of the force of attraction among the given species is -

  • HI > HBr> Cl2

  •  CCl4>CH2Cl2>CH3Cl>CH4

  • n- Pentane > iso-Pentane > neo-Pentane

  •  OH2>OCH32>OBr2

The "O-N-O" bond angle is maximum in:

(a) N2O       (b)NO2+    CNO2-    (d) NO3-

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  • 3
  • 4

Among following molecule NSi bond length is shortest:

  •  N(SiH3)3                           

    (2) N(SiH3)2

  • 2
  •  NH2(SiH3)                         

    (4) All have equal NSi bond length

  • 4

The geometry with respect to the central atom of the following molecules are:

N(SiH3)3;     Me3N;     (SiH3)3 P

  • planar, pyramidal, planar

  • planar, pyramidal, pyramidal 

  • pyramidal, pyramidal, pyramidal

  • pyramidal, planer, pyramidal

Incorrect statement regarding BF2NH2 molecule is :

  • FBF bond angle <120%                     

  • HNH bond angle >109°28'

  • Exhibits intermolecular H-bond             

  • Hybridization of N-atom is sp3

Molecule that has μ (observed) greater than μ (theoretical) is : 

                                                                                     

  •  CHCl3                                               

  •     

  •                                                    

  •  

The bond having minimum bond energy is :

  •  CC                             

    (2) OO

  • 2
  •  SS                               

    (4) PP 

  • 4

A gas that should not be collected over water is-

 

  •  H2

  •  N2

  •  CH4

  • HCl

The correct increasing order of extent of hydrolysis is :

(a) CCl4<MgCl2<AlCl3<SiCl4<PCl5           (b) CCl4<AlCl3<MgCl2<PCl5<SiCl4

(c) CCl4<SiCl4<PCl5<AlCl3<mgCl2            (d) CCl4<PCl5<SiCl4<AlCl3<MgCl2

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  • 4

Inorganic benzene reacts with HCl to form a compound B3N3H9Cl3. The protonation occurs at:

  • B-atom 

  • N-atom

  • First at B-atom then rearrangers into N-atom 

  • First N-atom then rearrangers into B-atom 

The correct order of initials or F for the following statements is -

(Use T if statement is true and F if it is false)

(i)(CH3)2P(CF3)3 is non-polar (CH3)3P(CF3)2  is polar molecule 

(ii) CH3P^CH3 bond angles are equal in a molecule

(iii) PF3 will be more soluble in the polar solvent than SiF4

  • TTF               

  • FFT                     

  • FFF                           

  • FTT

Which substance has the strongest London dispersion forces?

  •  SiH4

  •  CH4

  •  SnH4

  •  GeH4

The compound that has the lowest boiling point is-

  • HF

  • HCl

  • HBr 

  • HI 

Which of the following is the correct order for increasing bond angle?

(a) NH3<PH3<AsH3<SbH3                    (b)H2O<OF2<Cl2O(c) H3Te+<H3Se+<H3S+<H3O+            (d) BF3<BCI3<BBr3<BI3

  • 1
  • 2
  • 3
  • 4

The correct statement about hydrolysis of BCl3 and NCl3 is-

  •  NCl3 is hydrolysed and gives HOCl but BCl3 is not hydrolysed

  • Both NCl3 and BCl3 on hydrolysis gives HCl

  •  NCl3 on hydrolysis gives HOCl  but BCl3 gives HCl

  • Both NCl3 and BCl3 on hydrolysis gives HOCl

a. Benzene                         

b. Inorganic Benzene

c. PCl3F2                            

d. PCl2F3

The correct sequence of the polarity of the following molecule is -

      a           b            c            d                           

(Where P=polar, NP=non-polar)

  •    P          NP          NP           P                         

  •    NP        NP          NP           P

  •    NP        P            NP           P                         

  •    NP        P             P            NP

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