Transition elements show:
variable valency
paramagnetism
catalytic properties
all of these
The transition elements are more metallic than the representative elements because they have:
The electrons in d-orbitals
Electron pairs in d-orbitals
Availability of d-orbitals for bonding
Unpaired electrons in metallic orbitals
Which pair has elements containing a same number of electrons in the outermost orbit?
N, O
Na, Ca
As, Bi
Pb, Sb
The correct arrangement of increasing order of atomic radius among Na, K, Mg and Rb is
Mg<K<Na<Rb
Mg<Na<K<Rb
Mg<Na<Rb<K
Na<K<Rb<Mg
Which of the following statement is correct with respect to the property of elements with increase in atomic number in carbon family.
Their metallic character decreases
The stability of +2 oxidation state increases
Their ionisation energy increases
Their atomic size decreases
The correct order of second ionization potential of carbon, nitrogen, oxygen and fluorine is
C > N > O > F
O > N > F > C
O > F > N > C
F > O > N > C
The electronic configuration of the element which is just above the element with atomic 43 in the same group is ____________.
1s2 2s2 2p6 3s2 3p6 3d5 4s2
1s2 2s2 2p6 3s2 3p6 3d5 4s3 4p6
1s2 2s2 2p6 3s2 3p6 3d6 4s2
1s2 2s2 2p6 3s2 3p6 3d7 4s2
Generally, the ionization enthalpy increases along a period but there are some exceptions. The one which is not an exception is-
Be and B
N and O
Mg and Al
Na and Mg
Sodium generally does not show an oxidation state of +2, because of:
High first ionization potential.
High second ionization potential.
Large ionic radius.
High electronegativity.
The electronegativity of the following elements increases in the order of -
S < P < N < O
P < S < N < O
N < O < P < S
N < P < S < O
The graph of the first ionization enthalpy versus atomic number as follows:
Which of the following statement is correct?
Alkali metals are at the maxima and noble gases at the minima.
Noble gases are at the maxima and alkali metals at the minima.
Transition element are at the maxima.
Minima and Maxima do not show any regular behaviour.
What is the combining ratio of a number of elements in group l with elements in group 17th of the periodic table ?
1 : 2
1 : 3
2 : 1
1 : 1
The First ionisation enthalpies of Na,Mg,Al and Si are in the order
Na<Mg>Al<Si
Na>Mg>Al>Si
Na<Mg<Al<Si
Na>Mg>Al<Si
The electronic configuration of chalcogens in their outermost shell is :
ns2np3
ns2np4
ns2np5
ns2np6
Among the following species, the smallest ion is :
The correct order for electron affinity of halogens is :
Br > F
F > Cl
Br > Cl
F > I
Which one of the elements has the highest ionization energy?
[Ne]3s23p1
[Ne]3s23p2
[Ne]3s23p3
[Ar]3d104s24p2
Element/Ion that has the highest electron affinity is :
F-
O-
O
Na
The correct order of second ionisation energies of B, C, N, & O is
O > N > C > B
O > C > N > B
O > B > C > N
O > N >B > C
Consider the following changes:
M(s)→M(g) .....(i)M(s)→M2+(g)+2e- .....(ii)M(g)→M+(g)+e- .....(iiii)M+(g)→M2+(g)+e- ......(iv)M(g)→M2+(g)+2e- ......(v)
The second ionization energy of M could be calculated from the energy values associated with :
(a) 1+3+4 (b) 2-1+3
(c) 1+5 (d) 5-3
Incorrect statement among the following is -
Van der Waals' radius of iodine is more than its covalent radius
All isoelectronic ions belong to the same period of the periodic table
I.E1 of N is higher than that of O while I.E2 of O is higher than that of N
The electron affinity N is almost zero while that of P is 74.3 kJ mol-1
An atom of the element A has 3 electrons in its outermost shell while another atom X has 6 electrons in its outermost shell. The formula of the compound between A and X could be.
A2X3
AX3
A3X2
A2X
Match list-I with list II and select the correct answer using codes given below:
1. List-I Ions List-II Radius (in pm)
(I) Li+ (a) 216
(II) Na+ (b) 195
(III) Br- (c) 60
(IV) I- (d) 95
Codes:
I II III IV
a b d c
b c a d
c d b a
d c b a
The screening effect of d-electrons is :
Equal of the p-electrons
Much more than p-electrons
Same as f-electron
Less than p-electrons
Values of electronegativity like 3.0, 2.8, 2.5 are related to :-
Elements having low IP in the periodic table
Elements having high EA in the periodic table
Chalcogens
None of the above
Allred Rochow's scale is related to:-
Electronegativity, radius, and Z*
Resonance energy of the molecule, ionisation potential and electron affinity.
Bond Polarity, diagonal relationship and periodicity.
None of the above.
In scandium series, maximum distance between neutrons containing site and valence shell is of :-
Sc
Mn
Fe
Zn
Which of the following ionisation energy order is NOT correct :-
Cu+ > Cu+2
Mn+2 > Mn+3
N+< N
All of the above
Which of the following would not proceed in the forward direction spontaneously?
Si++Cl→Si+Cl+
F+I-→F-+I
both
none
Increasing order of ionic radii and decreasing order of number of protons of the given isoelectronic species is:-
Ca+2, K+, Cl-, S-2
Cl-, Ca+2, K+, S-2
S-2, Cl-, Ca+2, K+
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