Transition elements show:

  • variable valency

  • paramagnetism

  • catalytic properties

  • all of these

The transition elements are more metallic than the representative elements because they have:

  • The electrons in d-orbitals

  • Electron pairs in d-orbitals

  • Availability of d-orbitals for bonding

  • Unpaired electrons in metallic orbitals

Which pair has elements containing a same number of electrons in the outermost orbit?

  • N, O

  • Na, Ca

  • As, Bi

  • Pb, Sb

The correct arrangement of increasing order of atomic radius among Na, K, Mg and Rb is 

  • Mg<K<Na<Rb

  • Mg<Na<K<Rb

  • Mg<Na<Rb<K

  • Na<K<Rb<Mg

Which of the following statement is correct with respect to the property of elements with increase in atomic number in carbon family.

  • Their metallic character decreases

  • The stability of +2 oxidation state increases

  • Their ionisation energy increases

  • Their atomic size decreases

The correct order of second ionization potential of carbon, nitrogen, oxygen and fluorine is

  • C > N > O > F

  • O > N > F > C

  • O > F > N > C

  • F > O > N > C

The electronic configuration of the element which is just above the element with atomic 43 in the same group is ____________.

  • 1s2s2p3s3p3d4s2

  • 1s2s2p3s3p3d5 4s3 4p6

  • 1s2s2p3s3p3d6 4s2

  • 1s2s2p3s3p3d7 4s2

Generally, the ionization enthalpy increases along a period but there are some exceptions. The one which is not an exception is-

  • Be and B

  • N and O

  • Mg and Al

  • Na and Mg

Sodium generally does not show an oxidation state of +2, because of:

  • High first ionization potential.

  • High second ionization potential.

  • Large ionic radius.

  • High electronegativity.

The electronegativity of the following elements increases in the order of - 

  • S < P < N < O   

  • P < S < N < O

  • N < O < P < S

  • N < P < S < O

 

The graph of the first ionization enthalpy versus atomic number as follows:

Which of the following statement is correct?

  • Alkali metals are at the maxima and noble gases at the minima.

  • Noble gases are at the maxima and alkali metals at the minima.

  • Transition element are at the maxima.

  • Minima and Maxima do not show any regular behaviour.

What is the combining ratio of a number of elements in group l with elements in group 17th of the periodic table ?

  • 1 : 2

  • 1 : 3

  • 2 : 1

  • 1 : 1

The First ionisation enthalpies of Na,Mg,Al and Si are in the order

  • Na<Mg>Al<Si

  • Na>Mg>Al>Si

  • Na<Mg<Al<Si

  • Na>Mg>Al<Si

The electronic configuration of chalcogens in their outermost shell is : 

  • ns2np3       

  • ns2np4        

  • ns2np5           

  • ns2np6

Among the following species, the smallest ion is : 

  • Na+
  • F-
  • O2-
  • N3-

 The correct order for electron affinity of halogens is :

  • Br > F

  • F > Cl

  • Br > Cl

  • F > I

Which one of the elements has the highest ionization energy?

 

  • [Ne]3s23p1

  • [Ne]3s23p2

  • [Ne]3s23p3

  • [Ar]3d104s24p2

Element/Ion that has the highest electron affinity is : 

  • F-

  • O-

  • O

  • Na

The correct order of second ionisation energies of B, C, N, & O is

  • O > N > C > B

  • O > C > N > B

  • O > B > C > N

  • O > N >B > C

Consider the following changes:

  •  M(s)M(g)                                                   .....(i)M(s)M2+(g)+2e-                                    .....(ii)M(g)M+(g)+e-                                      .....(iiii)M+(g)M2+(g)+e-                                     ......(iv)M(g)M2+(g)+2e-                                  ......(v)

  • The second ionization energy of M could be calculated from the energy values associated with :

  • (a) 1+3+4                  (b) 2-1+3

  • (c) 1+5                      (d) 5-3

Incorrect statement among the following is -

  • Van der Waals' radius of iodine is more than its covalent radius

  • All isoelectronic ions belong to the same period of the periodic table

  •  I.E1 of N is higher than that of O while I.E2 of O is higher than that of N

  • The electron affinity N is almost zero while that of P is 74.3 kJ mol-1

An atom of the element A has 3 electrons in its outermost shell while another atom X has 6 electrons in its outermost shell. The formula of the compound between A and X could be.

  • A2X3

  • AX3

  • A3X2

  • A2X

Match list-I with list II and select the correct answer using codes given below:

1. List-I Ions                                List-II Radius (in pm)

(I) Li+                                         (a) 216

(II) Na+                                      (b) 195

(III) Br-                                      (c) 60

(IV) I-                                        (d) 95

     Codes:

      I   II   III   IV

  •    a   b    d    c

  •    b   c    a    d

  •    c   d    b    a

  •    d   c    b    a 

The screening effect of d-electrons is :

  • Equal of the p-electrons

  • Much more than p-electrons

  • Same as f-electron

  • Less than p-electrons 

Values of electronegativity like 3.0, 2.8, 2.5 are related to :-

  • Elements having low IP in the periodic table

  • Elements having high EA in the periodic table

  • Chalcogens

  • None of the above

Allred Rochow's scale is related to:-

  • Electronegativity, radius, and Z*

  • Resonance energy of the molecule, ionisation potential and electron affinity.

  • Bond Polarity, diagonal relationship and periodicity.

  • None of the above.

In scandium series, maximum distance between neutrons containing site and valence shell is of :-

  • Sc

  • Mn

  • Fe

  • Zn

Which of the following ionisation energy order is NOT correct :-

  • Cu+ > Cu+2

  • Mn+2 > Mn+3

  • N+N

  • All of the above

Which of the following would not proceed in the forward direction spontaneously?

  •  Si++ClSi+Cl+

  •  F+I-F-+I

  • both

  • none

Increasing order of ionic radii and decreasing order of number of protons of the given isoelectronic species is:-

  • Ca+2, K+, Cl-, S-2

  • Cl-, Ca+2, K+, S-2

  • S-2, Cl-, Ca+2, K+

  • None of the above

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Practice Chemistry Quiz Questions and Answers