In which of the following has maximum electronegativity:-

  • C

  • O

  • B

  • F

The electronic configuration of Palladium is:

  • [Rn] 5f3 6d1 7s2

  • [Rn] 5f5 6d1 7s2

  • [Rn] 5f6d1 7s2

  • None of the above.

Zeff of Na+ and Na0 are respectively-

  •  1.95 and 1.22

  •  0.85 and 0.35

  •  1 and 0.35

  •  6.85 and 2.2

Removal of 2nd electron is always :-

  • Endothermic

  • Endothermic for Mg, Be, N

  • Exothermic for Mg, Be, N and noble gases

  • Depends of electronic configuration

Atomic radius of Be, O, C, N, B are respectively (in pm) :-

  • 111, 66, 77, 74, 88

  • 74, 84, 111, 77,66

  • 111, 88, 77, 74, 66

  • 111, 66, 88, 77,74

The first four IP values of an element are 19, 190, 2000 and 2600 eV/atom. Element belongs to:-

  • Amphoteric elements

  • Four electron donor group

  • s-block

  • All of the above

A large difference between fifth and sixth ionisation energies indicate the element having :-

  • 15 proton in nucleus

  • 13 proton in nucleus

  • 11 proton in nucleus

  • Ionisation energy is NOT related to number of proton in nucleus

If atomic number of an element of He-family is Z then which of the following atomic number will highest EA?

  • Z - 2

  • Z - 1

  • Z + 1

  • Z + 2

The element having very high electron affinity but zero ionisation enthalpy is :-

  • He (due to inert gas configuration)

  • Be (due to fully filled subshell)

  • H (due to presence of allotropes)

  • None of the above

The pair of which addition of 2nd electron in both the atoms are endothermic :-

  • All of the above

  • N, Ne

  • Be, F

  • B, C

The correct order in which the O-O bond

length increases in the following is

  • H2O2<O2<O3

  • O3<H2O2<O2

  • O2<O3<H2O2

  • O2<H2O2<O3

The incorrect match among the following is -

  • B < C < N < O (increasing first ionisation enthalpy)

  • I < Br < F < Cl (increasing electron gain enthalpy)

  • Li < Na < K < Rb (increasing metallic radius)

  • Al3+ < Mg2+ < Na+ <F- (increasing ionic size)

Which one of the following orders is correct for the bond dissociation enthalpy of halogen

molecules?

  • Cl2>Br2>F2>I2               

  • Br2>I2>F2>Cl2

  • F2>Cl2>Br2>I2               

  • I2>Br2>Cl2>F2

The correct sequence of increasing radii is -

  • Ar < K+ < Ca2+

  • Ca2+ < Ar < K+

  • Ca2+ < K+ < Ar

  • K< Ar < Ca2+

The formation of the oxide ion O2-(g), from oxygen atom requires first an exothermic and

then an endothermic step as shown below,

O(g) + e-           O-(g); fH° = -141kJmol-1O-(g) +e-           O2-(g); fH° = +780 kJ mol-1

Thus, process of formation of O2- in gas phase is unfavourable even though O2- is

isoelectronic with neon. It is due to the fact that

  • electron repulsion outweighs the stability gained by achieving noble gas configuration

  • O- ion has comparatively smaller size than oxygen atom

  • Oxygen is more electronegative

  • addition of electron in oxygen result in large size of the ion

Be2+ is isoelectronic with which of the following ions?

  • H+

  • Li+

  • Na+

  • Mg2+

The ease of adsorption of the hydrated alkali metal ions on an ion-exchange resins

follows the order

  • Li+<K+<Na+<Rb+

  • Rb+<K+<Na+<Li+

  • K+<Na+<Rb+<Li+

  • Na+<Li+<K+<Rb+

The correct order of the decreasing ionic radii among the following isoelectronic species is : 

  • Ca2+ > K+ > S2- > Cl-

  • Cl- > S2- > Ca2+ > K+

  • S2- > Cl- > K+ > Ca2+

  • K+ > Ca2+ > Cl- > S2-

The correct order of increasing electron gain enthalpy with negative sign for the elements O, S, F and Cl is : 

  • Cl < F < O < S                   

  • O < S < F < Cl

  • F < S < O < Cl                   

  • S < O < Cl < F

Which one of the following compounds is a peroxide ?

  • KO2

  • BaO2

  • MnO2

  • NO2

The sequence of ionic mobility in aqueous solution is

  • K+>Na+>Rb+>Cs+

  • Cs+>Rb+>K+>Na+

  • Rb+>K+>Cs+>Na+

  • Na+>K+>Rb+>Cs+

Which one of the following arrangements does not give the correct picture of the trends indicated against it?

  • F> Cl> Br> I:Oxidising power

  • F2 < Cl2 > Br2 > I: Electron gain enthalpy

  • F> Cl> Br> I: Bond dissociation energy

  • F> Cl> Br> I2: Electronegativity

Identify the correct order of the size of the following:

  • Ca2+<K+<Ar<S2-<Cl-

  • Ca2+<K+<Ar<Cl-<S2-

  • Ar<Ca2+<K+<Cl-<S2-

  • Ca2+<Ar<K+<Cl-<S2-

An element whose IUPAC name is Ununtrium (Uut) belongs to:

  • s-Block elements                       

  • p-Block elements

  • d-Block elements                              

  • Inner transition elements .

Which among the following is not a representative element?

  • Tellurium                                         

  • Tantalum

  • Thallium                                         

  • Astatine

The period number and group number of "Tantalum" (Z=73) are respectively :

  • 5, 7                                                 

  • 6, 13                 

  • 6, 5                                                 

  • None of the above.

Consider the following electronic configuration of an element (P) :

Xe4f145d16s2

The correct statement about element 'P' is :

  • It belongs to the 6th period and the 1st group.

  • It belongs to the 6th period and the 2nd group.

  • It belongs to the 6th period and the 3rd group.

  • None of the above.

Which of the following metal is highest electropositive (metallic) in nature ?

  • Be                                       

  • Rb

  • Mn                                       

  • Tl

The pair that has both members from the same period of the Periodic Table is 

  • Cl, Br

  • Ca, Cl

  • Na, Ca

  • Na, Cl

Isoelectronic pair, among the following, is : 

  •  ClO2-, ClF2+

  •  IF2-, I3-

  •  Cl2O, ICl2-

  •  ICl2-, ClO2

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