The graph that represents the relationship between atomic number (Z) and magnetic moment of d-block elements among the following is-

[Outer electronic configuration : (n-1)dxns1 or 2]

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If the IUPAC name of an element is "unununium",then the correct statement regarding the element is 

 

  • It is an inner transition element .

  • It belongs to the 8th period in the periodic table .

  • It is a transition element .

  • It is a non-transition element.

The following property/ies decrease from left to right across the periodic table and increase from top to bottom:

(i) Atomic radius (ii) Electronegativity (iii) Ionisation energy (iv) Metallic character

  • (i) only                     

  • (i), (ii), and (iii)

  • (i), (iii), and (iv)         

  • (i), and (iv)

Consider the following information about element P and Q :

                        Period number            Group number

P                               2                                 15

Q                               3                                 2

Then formula of the compound formed by P and Q element is :

  • PQ         

  •  P3Q2           

  • Q3P2            

  • PQ2

Incorrect order of radius is :

  • 1
  • (1) Sr2+ <Rb+<Br <Se2-                   (2) Co>Ni>Cu>Zn

  • (3)  Co>Co2+>Co3+>Co4+                   (4) As3->Se2->Cs+>Ba2+

  • 4

The radius of which ion is closest to that of Li+ ion ?

  •  Na+                                       

  •  Be2+

  •  Mg2+                                       

  •  Al3+

The correct order of IE2 is:

  • Ne>F>O>N                     

  • O>F>Ne>N

  • Ne>O>F>N                     

  • O>Ne>F>N

Which of the following transformation least energy is required?

  •  F-g  Fg +e-                 

    (2) P-gPg+e-

  • 2
  •  S-gSg+e-                   

    (4) Cl-gClg+e-

  • 4

Which of the following represents correct order of electron affinity?

  • Cl>F>S>O                           

  • F>O>S>Cl

  • F>Cl>S>O                           

  • Cl>S>O>F

Correct expression of "Allred and Rochow's" scale is:

  • () Electronegativity =0.744Zeff.r2+0.359

  • () Electronegativity =0.359r2Zeff.+0.744

  • () Electronegativity =0.359Zeff.r+0.744

  • () Electronegativity =0.359Zeff.r2+0.744

The process that requires absorption of energy is:

  •  NN-                       

  •  FF-

  •  ClCl-                     

  •  HH-

Which of the following compound is most acidic?

  •  Cl2O7                             

  •  P4O10

  •  SO3                                 

  •  B2O3

If P and T are second period p-block elements then which of the following graph show correct relation between valence electrons in P2 to T2 (corresponding molecules) and their bond order is :

  • ()                                                  

  • () 

  • ()                                            

  • () 

Consider the following four elements, which are represented according to long form of periodic table.

Here W, Y and Z are left, up and right elements with respect to the element 'X' and 'X' belongs to 16th group and 3rd period.Then according to given information the incorrect statement regarding given elements is:

  • Maximum electronegativity :Y             

  • Maximum catenation property :X

  • Maximum electron affinity :Z               

  • Y exhibits variable covalency

The ground state electronic configurations of the elements, U,V,W,X,and Y (these symbols do not have any chemical significance) are as follows:

                             U        1s22s22p3V         1s22s22p63s1W        1s22s22p63s23p2X         1s22s22p63s23p63d54s2Y         1s22s22p63s23p63d104s24p6

Determine which sequence of elements satisfy the following statements :

(i) Element forms a carbonate that is not decomposed by heating

(ii) Element is most likely to form coloured ionic compounds

(iii) Element has a largest atomic radius

(iv) Element forms an only acidic oxide

  • V W Y U                                   

  • V X Y W

  • V W Y X                                   

  • V X W U

Which one will show variable oxidation state?

(I) Kr5s1                                 (II) Rn5f146d17s2
(III)Ar3d104s24p5                    (IV) Ar3d64s2

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In alkaline earth metals, the properties, from the following, that will increase from Be to Ba are-

(i) Atomic radius        (ii) Ionisation energy        (iii) Nuclear charge

  • (i) and (ii)                                 

  • (i) and (iii)

  • (ii) and (iii)                               

  • (i), (ii), and (iii)

Incorrect order of ionic size is :

(a)La3+>Gd3+>Eu3+>Lu3+           (b)V2+>V3+>V4+>V5+

(c)Tl+>In+>Sn2+>Sb3+                (d)K+>Sc3+>V5+>Mn7+

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Aqueous solutions of two compounds M1-O-H and M2-O-H are prepared in two different beakers. If, the electronegativity of M1=3.4 , M2=1.2, O=3.5 and H=2.1, then the nature of two solutions will be respectively:

(a) acidic, basic             (b) acidic, acidic

(c) basic, acidic             (d) basic, basic

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First three ionisation energies (in kJ/mol) of three representative elements are given below:

Element     IE1                    IE2                   IE3

P               495.8                4562                  6910
Q               737.7               1451                   7733
R               577.5                1817                  2745

Then incorrect option is :

  • Q: Alkaline earth metal.

  • P: Alkali metal.

  • R: s-block element.

  • All three: P,Q & R belong to the same period.

If the ionization enthalpy and electron gain enthalpy of an element are 275 and 86 kcal mol-1 respectively, then the electronegativity of the element on the Pauling scale is:

  • 2.8                                     

  • 0.0

  • 4.0                                     

  • 2.6

The incorrect statement is:

  • The second ionisation energy of Se is greater than that of second ionisation energy of As 

  • The first ionisation energy of C2+ ion is greater than that of first ionisation energy of N2+ ion

  • The third ionisation energy of F is greater than that of third ionisation energy of O

  • Helogens have highest I.E. in respective period

Consider the following ionisation reactions :

I.E. (kJ mol-1)

AgAg++e- ,       A1B(g)+B(g)2++e-,       B2C(g)+C(g)2++e-,      C2B(g)B(g)++e-,       B1C(g)C(g)++e-,      C1C(g)2+C(g)3++e-,      C3

If monovalent positive ion of A, divalent positive ion of B and trivalent positive ion of C have zero electron. Then incorrect order of corresponding I.E. is :

  •  C3>C2>B2                       

  •  B1>A1>C1

  •  C3>C2>B2                       

  •  B2>C3>A1

The incorrect match among the following options is : 

 

  •  Ar3d54s1 4th period, 6th group

  •   Kr4d10 5th period, 12th group

  •   Rn6d27s2 7th period, 3th group

  •   Xe4f145d26s2 6th period, 4th group

Which of the following order is correct for the property mentioned in brackets?

(a) S2->Cl->K+>Ca2+                 (Ionisation energy)

(b) C<N<F<O                              (2nd Ionisation energy)

(c) B>Al>Ga>In>Tl                     (Electronegativity)

(d)Na+>Li+>Mg2+>Be2+>Al3+    (Ionic radius)

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IP1 and IP2 for Mg are 178 and 348 Kcal mol-1 respectively. The energy required for the reaction, MgMg2+ + 2e- is :

  • +170 Kcal mol-1

  • +526 Kcal mol-1

  • -170 Kcal mol-1

  • -526 Kcal mol-1

Incorrect statement about characteristics regarding halogens is :

  • Ionization energy decreases with increase in atomic number.

  • Electronegativity decreases with increase in atomic number.

  • Electron affinity decreases with increase in atomic number.

  • Enthalpy of fusion increases with increase in atomic number. 

The process requiring the absorption of energy is :

  •  FF-

  •  HH-

  •  ClCl-

  •  OO2-

Consider the following statements:

(I) Rutherford name was associated with the development of periodic table.

(II) A metal M having electronic configuration 1s2, 2s2, 2p6, 3s2, 3p6 ,3d10, 4s1 is d-block element.

(III) Diamond is  an element.

(IV) The electronic configuration of the most electronegative elements is 1s2, 2s2, 2p5, 

and select the correct one from the given codes.

(A) I, II, IV                                      (B) I, II, III, IV

(C) II, IV                                         (D) I, III, IV

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Which of the following has the highest electron affinity?

  • F

  • O

  • O

  • Na

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