The correct statement about radius is

  • Radius increases during cation and anion formation.

  • Radius increases during anion formation and decreases during cation formation.

  • Radius decreases in cation as well as anion.

  •  Radius decreases during anion formation and increases during cation formation.

The values of first ionization enthalpies for two isotopes would be -

  • Same.

  • Different .

  • Same values but positive for first and negative for the second.

  • Same values but negative for first and positive for the second.

The general outer electronicconfiguration of s, p, d and f-block elements respectively would be 

  • ns1-2, nd2np1-6, (n-1)d1-10np0-2, (n-2)f1-14(n-1)d0-10ns2

  • ns1-2, ns2np1-6, (n-1)f1-10ns0-2, (n-2)g1-14(n-1)d0-1ns2

  • ns1-2, ns2np1-6, (n-1)d1-10ns1-2, (n-2)f1-14(n-1)d0-1 ns2

  • np1-2, nd2np1-6, (n-1)d1-10ns0-2, (n-2)f1-14(n-1)d0-10ns2

The position of elements with an outer electronic configuration as (n-2) f7(n-1)d1ns2, n = 6

 

  • 6th period and 10th group.

  •   7th period and 3rd group.

  •   6th period and 3rd group.

  •  7th period and 9th group.

1st (H1) and 2nd  (H2) Ionization Enthalpies (in kJ mol–1) and the (egH) Electron Gain Enthalpy (in kJ mol–1) of a few elements are given below:

ElementsΔH1ΔH2ΔegH
I5207300-60
II4193051-48
III16813374-328
IV10081846-295
V23725251+48
VI7381451-40

The most reactive element is - 

 

  • VI 

  •   III

  •   I

  • II

The formula of the stable binary compounds that would be formed by an element having atomic number 71 and fluorine-

  • LuF6

  •  LuF2

  •  LuF3

  •  LuF4

The factor that does not affect the valence electron is 

  • Azimuthal quantum number 

  • Nuclear charge (Z)

  • Nuclear mass

  • Number of core electrons

The size of isoelectronic species: F, Ne and Na+, is affected by :

  • Nuclear charge (Z)

  • Valence principal quantum number (n)

  • Electron-electron interaction in the outer orbitals

  • None of the above factors because their size is the same

The incorrect statement about ionization enthalpy is -

  • Ionization enthalpy increases for each successive electron.

  • Noble gases have the highest ionization enthalpy.

  • A big jump in ionization enthalpy indicates a stable configuration.

  • Ionization enthalpy of oxygen is higher than that of nitrogen.

The ionic radii vary in-

(a) Inverse proportion to the effective nuclear charge.

(b) Inverse proportion to the square of effective nuclear charge.

(c) Direct proportion to the screening effect.

(d) Direct proportion to the square of screening effect.

Choose the correct option :

  • (a), (c)

  • (b), (c)

  • (c), (d)

  • (b), (d)

Match the following isoelectronic species in column I and column II : 

Column IColumn II
i. F-a. Br-
ii. Arb.  Si2+
iii. Mgc. O2-
iv. Rb+d. S2-
  • i = b, ii = c, iii = a, iv = d

  •  i = c, ii = b, iii = a, iv = d

  •  i = c, ii = d, iii = b, iv = a

  •  i = b, ii = c, iii = d, iv = a

The correct order of ionization energy of W, X,Y and Z is -

  • W >X> Y> Z

  •  W <X < Y> Z

  •  W <X> Y< Z

  •  W >X> Y< Z

Consider the following curve:
   
X represents group with highest atomic radius. The element that belongs to Y group can be : 

  • Na

  • Mg

  • Br

  • Si

In the following graph of variation of ionization energy with atomic number, X, Y, and Z represent elements.

 

The group number of X, Y, and Z elements is:

  • 1st group

  • 15th group

  • 17th group

  •  18th group

The graph between ionization energy and atomic number for the first group elements is shown below    

The element represented by Y in the graph above is -

  • Cs 

  • Rb

  • Ca

  •   K 

Abnormally high ionization enthalpy of B as depicted in the graph below can be due to : 

  • Completely filled 2p subshell.

  • Completely filled 2s subshell.

  • Completely filled 3d subshell.

  • Completely filled 4f subshell.

The correct graph depicting ionization energies for 2nd period elements is-

  •  

  •  

  • None of the above.

Correct statement among the following regarding P, S, Cl, F is -

  • F has most negative electron gain enthalpy, and S has least negative electron gain enthalpy.
  • Cl has most negative electron gain enthalpy, and S has least negative electron gain enthalpy.
  • Cl has most negative electron gain enthalpy, and P has least negative electron gain enthalpy.
  • F has most negative electron gain enthalpy, and P has least negative electron gain enthalpy.

The formula of a compound that is formed by the aluminium and sulphur is-

  •  AlS2
  •  Al2S3
  •  Al3S2
  •  Al3S4

An incorrect properties of p-block elements among the following is -
 
  • Include both metals and non-metals.

  • Form mainly covalent bonds with other elements.

  • The ionisation enthalpies are relatively lesser than s-block elements.

  • Some of the p-block elements show variable or more than one oxidation states.

The correct order of atomic radii of fluorine and neon (in pm) is respectively-
  • 72, 72
  • 160, 160
  • 72, 160
  • 160, 72
Oxygen has lower ionisation enthalpy than nitrogen due to -
 
  • Half filled p subshell of oxygen atom.
  •  Half filled p subshell of nitrogen atom.
  • Complete filled p subshell of oxygen atom.
  •  Complete filled p subshell of nitrogen atom.
 Factor among the following that doesnot affect the ionization enthalpy of an element is -
  •   Effective nuclear charge
  •  2 . Atomic radius
  •   Half filled and completely filled sub shell
  •   Atomic number
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