With F highest stable oxidation state of Mn is
+6
+4
+7
+3
Cr2O72-+X→H+Cr3++H2O + oxidized product of X. X in the above reaction cannot be
C2O42-
Fe2+
SO42-
S2-
Basic oxide amongst the following is:
CrO
Cr2O3
CrO3
Cr2O4
The pair having similar magnetic moment is
Ti3+,V3+
Cr3+,Mn2+
Mn2+,Fe3+
Fe2+,Mn2+
Lanthanoid which is radioactive is
Promethium
Europium
Plutonium
Neptunium
Actinide contraction is mainly related to :-
Poor shielding by 5f subshell
Extraordinary decrement in Zeff
Both of the above
Strong shielding by 5f subshell
The most basic hydroxide among the following is -
Ce(OH)3
Lu(OH)3
Yb(OH)3
Tb(OH)3
Which is colorless in water?
Ti3+
V3+
Cr3+
Sc3+
CrO42- and MnO4- are strong yellow and intense purple respectively in aqueous solution The darkening of colour is due to
charge transfer
d-d transition
half-filled d-sub shells
increasing number of unpaired electron
In the dichromate ion Cr2O72-,
4 Cr-O bonds are equivalent
6 Cr-O bonds are equivalent
All Cr-O bonds are equivalent
None of Cr-O bonds are equivalent
Electronic configuration of a transition element X in +3 Oxidation state is [Ar]3d5.
What is its atomic number?
25
26
27
24
Magnetic moment of K3[Fe(CN)5(H2O)] is
0
4.92
3.87
2.83
Name the gas that can readily decolourise acidified KMnO4 solution.
CO2
SO2
NO2
P2O5
HgCl2 and I2 both when dissolved in water containing I- ions the pair of species formed is
(a) HgI2, I3- (b) HgI2, I-
(c) HgI42-, I3- (d) Hg2I2, I-
A pair among the following has the same size is -
Fe2+ , Ni2+
Zr4+ , Ti4+
Zr4+ , Hf4+
Zn2+, Hf4+
A metal M and its compound can give the following observable changes in a consequence of reactions
M →HNO3dilute [Colourless solutions] →NaOHaqueous [White precipitate] →NaOH (aq)excess [Colourless solutions] →H2S [White precipitate]
Mg
Pb
Zn
Sn
Which two sets of reactants best represent the amphoteric character of Zn(OH)2?
Set 1: Zn(OH)2(s) and OH-(aq)
Set 2: Zn(OH)2(s) and H2O(l)
Set 3: Zn(OH)2(s) and H+(aq)
Set 4: Zn(OH)2(s) and NH3(aq)
() 1 and 2
Which compound is formed when iron reacts with carbon?
FeC2
Fe3C
FeC3
Fe2C
(X)+K2CO3+Air→heat(Y)(Y)+Cl2→(Z)Pink
Which of the following is correct?
(a) X= black, MnO2,Y=Blue, K2CrO4, Z = KMnO4
(b) X= green, Cr2O3, Y=Yellow ,K2CrO4, Z = K2Cr2O7
(c) X= black, MnO2, Y = green, K2MnO4, z = KMnO4
(d) x = black, Bi2O3, Y = Colourless, KBiO2, z = KBiO3
Consider the following transformation:
2CuX2→Room temperature2CuX+X2
Then&nsp;X- can be:
(1) F-, Br-
(2) Cl-,Br-
(3) CN-,I-
(4) Cl-,F-
Acidified permanganate solution does not oxidize:
C2O42-(aq)
NO2-(aq)
S2-(aq)
F-(aq)
Which of the following is true for the species 3d4 configuration ?
Cr2+ is reducing in nature
Mn3+ is oxidising in nature.
Both (A) and (B)
None of these
In which compound does vanadium have an oxidation number of +4?
() NH4VO2
() K4VCN6
() VSO4
() VOSO4
Among the following, the species that is both paramagnetic and coloured is :
() MnO42-
() TiCl62-
() VO43-
() CrO2Cl2
Arrange the following species in the increasing order of their magnetic properties.
VCl3 VOSO4 Na3VO4 VH2O6SO4.H2O
I II III IV
III<II<I<IV
III<IV<II<I
II<III<I<IV
IV<I<II<III
Which of the following increasing order of oxidising power is correct for the following species?
VO2+, MnO4-, Cr2O72-
(A) VO2+<Cr2O72-<MnO4-
(B) VO2+<MnO4-<Cr2O72-
(C) Cr2O72-<VO2+<MnO4-,
(D) Cr2O72-<MnO4-<VO2+
In which of the following oxoanions the oxidation state of the central atom is not the same as that of its group number in the periodic table?
() MnO4-
() Cr2O72-
() FeO42-
At 300°C, FeCl3 :
Decomposes into FeCl2 and Cl2.
Decomposes into Fe and Cl2.
Sublimes go give liquid FeCl3
Sublimes to give gaseous dimmer FeCl32.
Anhydrous ferric chloride is prepared by
Heating hydrated ferric chloride at a high temperature in a stream of air.
Heating metallic iron in a stream of dry chlorine gas.
Reaction of ferric oxide with HCl (aq).
Reaction of metallic iron with HCl (aq).
Anhydrous ferrous sulphate on heating gives :
(A) Both SO2 and SO3
(B)&nsp;SO2 only
(C) SO3 only
(D) Fe2SO43 only
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