The correct expression that  represents the equivalent conductance at infinite dilution of Al2(SO4)3 is: (Given that Al3+° and SO42-° are the equivalent conductances at infinite dilution of the respective ions)

  •  Al3+° + SO42-°

  •  Al3+° + SO42-°×6

  •  13Al3+° +12 SO42-°

  •  2Al3+° +3 SO42-°

Consider the following relations for emf of a electrochemical cell :
(a) emf of cell = (Oxidation potential of anode) – (Reduction potential of cathode)
(b) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)
(c) emf of cell = (Reduction potential of anode) + (Reduction potential of cathode)
(d) emf of cell = (Oxidation potential of anode) – (Oxidation potential of cathode)

The correct relation among the given options is : 

  • (a) and (b)

  • (c) and (d)

  • (b) and (d)

  • (c) and (a)

The concentration of ZnCl2 solution will change when it is placed in a container which is made of :

  •   Al
  •   Cu
  •   Ag
  •   None

The cell reaction of an electrochemical cell is \(Cu^{2+}(C_{1}) + Zn \to Cu + Zn^{2+}(C_{2})\).
The change in free energy will be the function of :

  • \( ln (C_{1}+C_{2})\)

  • \(ln (\frac{C_{2}}{C_{1}})\)
  • \( ln C_{2}\)
  • \( lnC_{1}\)

For the disproportionation of copper :

2Cu+Cu+2+Cu, E° is :-
(Given E° for Cu+2/Cu is 0.34 V & Eº for Cu+2/Cuis 0.15 V )

  • 0.49 V

  • – 0.19 V

  • 0.38 V

  • – 0.38 V

Cell reaction is spontaneous when :

  • ∆Gº is negative

  • ∆Gº is positive

  • ERed° is positive

  • ERed° is negative

At infinite dilution equivalent conductances of Ba+2 & Cl ions are 127 & 76 ohm–1cm–1 eq–1 respectively. Equivalent conductance (ohm–1cm–1 eq–1)of BaCl2 at infinite dilution is :

  • 139.5

  • 101.5

  • 203

  • 279

The value of E0 cell for the following reaction is -
\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ }\)

(Given , equilibrium constant is 106)

  •   0.17

  •   0.01
  •   0.05
  •   1.77

(Given F = 96500 C mol–1; R = 8.314 JK–1 mol–1

The standard Emf of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25ºC. The equilibrium constant of the reaction would be :-

  • 4.0 × 1012

  • 1.0 × 102

  • 1.0 × 1010

  • 2.0 × 1011

In the silver plating of copper, K[Ag(CN)2] is used instead of AgNO3. The reason is : -

  • A thin layer of Ag is formed on Cu

  • More voltage is required

  • Ag+ ions are completely removed from solution

  • Less availability of Ag+ ions, as Cu can not displace Ag from [Ag(CN)2] ion

On the basis of the information available from the reaction :

43Al+O223Al2O3, G=-827 KJ mol-1

of O2, the minimum e.m.f. required to carry out electrolysis of Al2O3 is : (F=96500 C mol–1)

  • 2.14 V

  • 4.28 V

  • 6.42 V

  • 8.56 V

The EMF of a Daniel cell at 298 K is E Zn|ZnSO4(0.01 M) || CuSO4(1.0 M)|Cu .
When the concentration of ZnSO4 is 1.0 M and that of CuSO4 is 0.01 M, the EMF is changed to E2. The correct relationship between E1 and E2 is :

  •  E1 > E2

  •  E1 < E2

  •  E1 = E2

  •  E2 = 0 ≠ E1

Arrange the following metals in the order in which they displace each other from the solution of their salts 

Al, Cu, Fe, Mg, and Zn.

  • Cu, Fe, Zn, Al, Mg

  • Zn, Fe, Cu, Mg, Al

  • Mg, Cu, Zn, Fe, Al

  • Al, Zn, Fe, Cu, Mg

Statement 1: The standard electrode potential of the system Mg2+ | Mg can be measured with respect to hydrogen electrode.
Statement 2: The standard electrode potential for hydrogen electrode is zero.
  • Both statements are true.
  • Statement 1 is true, statement 2 is false.
  • Statement 1 is false, statement 1 is true.
  • Both statements are false.

 2Cr(s) + 3Cd2+(aq)  2Cr3+(aq) + 3Cd

ECr3+/Cr= -0.74 VECd2+/Cd=-0.40 V

The value of Gro in the above reaction will be - 

  • -196.83 kJ

  • 196.83 kJ

  • 186.83 kJ

  • -186.83 kJ

a. The unit of conductivity is S cm-2.

b. Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration.

c. The unit of molar conductivity is S cm2 mol-1

d. Molar conductivity increases with an increase in concentration.

The incorrect statement (s) among the above is/ are : 

  • a

  • a, d

  • b, d

  • a, c

The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1 . The molar conductivity will be -

  • 124 S cm2 mol-1

  • 134 S cm2 mol-1

  • 128 S cm2 mol-1

  • 136 S cm2 mol-1

The electricity required in coulombs for the oxidation of 1 mole of FeO to Fe2O3  is-

  • 964.87 C

  • 96487 C

  • 96.487 C

  • 9.6487 C

Pt(s) | Br-(0.010 M) | Br2 (l) || H+(0.030 M) | H2  (1 bar) | Pt(s)  

EBr-/Br2o=-1.09 V

The value of Ecell  in the above reaction will be : 

  • +1.298 V 

  • -1.398 V

  • -1.298 V

  • -1.198 V

Zn(s) + Ag2O(s) +H2O (l)  Zn+2(aq) +2Ag(aq) +2OH-(aq) 

Ecell° = 1.04  ; the value of G° in the above reaction would be -

 

 

  • -2.13 kJ

  • -21.3 kJ

  • -213.04 kJ

  • -31.12 kJ

The mass of nickel deposited by electrolysis of a solution of Ni(NO3)2 using a current of 5 amperes for 20 min is (atomic mass of Nickle is 58.7) -

  • 2.42 g

  • 1.82 g

  • 3.93 g

  • 6.42 g

Consider the following graph.

The strong electrolyte in the above graph is represented by -

  • X

  • Y

  • Both X and Y

  • Data given is not sufficient to predict.

Consider the following graph of molar conductivity of KCl solution at different concentrations. 

  

The value of limiting molar conductivity for KCl is 150.0 S cm2 mol-1.  The value of the slope at the point A will be : 

  • 120

  • 100

  • 110

  • None of the above

The molar conductance of NaCl, HCI, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm mol-1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.

  

  •  698.28 S cm2 mol-1

  •  540.48 S cm2 mol-1

  •  201.28 S cm2 mol-1

  •  390.71 S cm2 mol-1

The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol-1. The dissociation constant of acetic acid is -

Λ°H+=350 S cm2 mol-1Λ°CH3COO-=50 S cm2 mol-1

  •  1.75×10-5 mol L-1 

  •  2.50×10-5 mol L-1 

  •  1.75×10-4 mol L-1 

  •  2.50×10-4 mol L-1 

For a cell reaction involving  a two-electron change, the standard Emf of the cell is found to be 0.295V at 25oC . The equilibrium constant of the reaction at 25oC will be : 

  • \(\times\) 10-10  

  • 29.5 \(\times\) 10-2   

  •   10 

  •  1 \(\times\) 1010   

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