The correct expression that represents the equivalent conductance at infinite dilution of Al2(SO4)3 is: (Given that ∧Al3+° and ∧SO42-° are the equivalent conductances at infinite dilution of the respective ions)
∧Al3+° + ∧SO42-°
∧Al3+° + ∧SO42-°×6
13∧Al3+° +12 ∧SO42-°
2∧Al3+° +3 ∧SO42-°
Consider the following relations for emf of a electrochemical cell :(a) emf of cell = (Oxidation potential of anode) – (Reduction potential of cathode)(b) emf of cell = (Oxidation potential of anode) + (Reduction potential of cathode)(c) emf of cell = (Reduction potential of anode) + (Reduction potential of cathode)(d) emf of cell = (Oxidation potential of anode) – (Oxidation potential of cathode)
The correct relation among the given options is :
(a) and (b)
(c) and (d)
(b) and (d)
(c) and (a)
The concentration of ZnCl2 solution will change when it is placed in a container which is made of :
The cell reaction of an electrochemical cell is \(Cu^{2+}(C_{1}) + Zn \to Cu + Zn^{2+}(C_{2})\).The change in free energy will be the function of :
\( ln (C_{1}+C_{2})\)
For the disproportionation of copper :
2Cu+→Cu+2+Cu, E° is :-(Given E° for Cu+2/Cu is 0.34 V & Eº for Cu+2/Cu+ is 0.15 V )
0.49 V
– 0.19 V
0.38 V
– 0.38 V
Cell reaction is spontaneous when :
∆Gº is negative
∆Gº is positive
ERed° is positive
ERed° is negative
At infinite dilution equivalent conductances of Ba+2 & Cl– ions are 127 & 76 ohm–1cm–1 eq–1 respectively. Equivalent conductance (ohm–1cm–1 eq–1)of BaCl2 at infinite dilution is :
139.5
101.5
203
279
The value of E0 cell for the following reaction is -\(Cu^{2+}+ Sn^{2+}\to Cu +Sn^{4+ }\)
(Given , equilibrium constant is 106)
0.17
The standard Emf of a galvanic cell involving cell reaction with n = 2 is found to be 0.295 V at 25ºC. The equilibrium constant of the reaction would be :-
4.0 × 1012
1.0 × 102
1.0 × 1010
2.0 × 1011
In the silver plating of copper, K[Ag(CN)2] is used instead of AgNO3. The reason is : -
A thin layer of Ag is formed on Cu
More voltage is required
Ag+ ions are completely removed from solution
Less availability of Ag+ ions, as Cu can not displace Ag from [Ag(CN)2]– ion
On the basis of the information available from the reaction :
43Al+O2→23Al2O3, ∆G=-827 KJ mol-1
of O2, the minimum e.m.f. required to carry out electrolysis of Al2O3 is : (F=96500 C mol–1)
2.14 V
4.28 V
6.42 V
8.56 V
The EMF of a Daniel cell at 298 K is E1 Zn|ZnSO4(0.01 M) || CuSO4(1.0 M)|Cu .When the concentration of ZnSO4 is 1.0 M and that of CuSO4 is 0.01 M, the EMF is changed to E2. The correct relationship between E1 and E2 is :
E1 > E2
E1 < E2
E1 = E2
E2 = 0 ≠ E1
Arrange the following metals in the order in which they displace each other from the solution of their salts
Al, Cu, Fe, Mg, and Zn.
Cu, Fe, Zn, Al, Mg
Zn, Fe, Cu, Mg, Al
Mg, Cu, Zn, Fe, Al
Al, Zn, Fe, Cu, Mg
2Cr(s) + 3Cd2+(aq) → 2Cr3+(aq) + 3Cd
E⊝Cr3+/Cr= -0.74 V; E⊝Cd2+/Cd=-0.40 V
The value of ∆Gro in the above reaction will be -
-196.83 kJ
196.83 kJ
186.83 kJ
-186.83 kJ
a. The unit of conductivity is S cm-2.
b. Specific Conductivity of weak and strong electrolytes always decreases with a decrease in concentration.
c. The unit of molar conductivity is S cm2 mol-1
d. Molar conductivity increases with an increase in concentration.
The incorrect statement (s) among the above is/ are :
a
a, d
b, d
a, c
The conductivity of 0.20 M solution of KCl at 298 K is 0.0248 S cm–1 . The molar conductivity will be -
124 S cm2 mol-1
134 S cm2 mol-1
128 S cm2 mol-1
136 S cm2 mol-1
The electricity required in coulombs for the oxidation of 1 mole of FeO to Fe2O3 is-
964.87 C
96487 C
96.487 C
9.6487 C
Pt(s) | Br-(0.010 M) | Br2 (l) || H+(0.030 M) | H2 (1 bar) | Pt(s)
EBr-/Br2o=-1.09 V
The value of Ecell in the above reaction will be :
+1.298 V
-1.398 V
-1.298 V
-1.198 V
Zn(s) + Ag2O(s) +H2O (l) → Zn+2(aq) +2Ag(aq) + 2OH-(aq)
Ecell° = 1.04 ; the value of ∆G° in the above reaction would be -
-2.13 kJ
-21.3 kJ
-213.04 kJ
-31.12 kJ
The mass of nickel deposited by electrolysis of a solution of Ni(NO3)2 using a current of 5 amperes for 20 min is (atomic mass of Nickle is 58.7) -
2.42 g
1.82 g
3.93 g
6.42 g
Consider the following graph.
The strong electrolyte in the above graph is represented by -
X
Y
Both X and Y
Data given is not sufficient to predict.
Consider the following graph of molar conductivity of KCl solution at different concentrations.
The value of limiting molar conductivity for KCl is 150.0 S cm2 mol-1. The value of the slope at the point A will be :
120
100
110
None of the above
The molar conductance of NaCl, HCI, and CH3COONa at infinite dilution are 126.45, 426.16, and 91.0 S cm mol-1 respectively. The molar conductance of CH3COOH at infinite dilution is. Choose the right option for your answer.
698.28 S cm2 mol-1
540.48 S cm2 mol-1
201.28 S cm2 mol-1
390.71 S cm2 mol-1
The molar conductivity of 0.007 M acetic acid is 20 S cm2 mol-1. The dissociation constant of acetic acid is -
Λ°H+=350 S cm2 mol-1Λ°CH3COO-=50 S cm2 mol-1
1.75×10-5 mol L-1
2.50×10-5 mol L-1
1.75×10-4 mol L-1
2.50×10-4 mol L-1
For a cell reaction involving a two-electron change, the standard Emf of the cell is found to be 0.295V at 25oC . The equilibrium constant of the reaction at 25oC will be :
1 \(\times\) 10-10
29.5 \(\times\) 10-2
10
1 \(\times\) 1010
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