When 0.1 mole of MnO2-4 is oxidised, the quantity of electricity required to completely oxidise MnO2-4 to MnO-4 is 

  • 96500 C

  • 2*96500 C 

  • 9650 C

  • 96.50 C

The Zn acts as sacrificial or cathodic protection to prevent rusting of iron because:

  •  EOP of Zn < EOP of Fe

  •  EOP of Zn > EOP of Fe

  •  EOP of Zn = EOP of fe

  • Zn is cheaper than iron

The standard reduction potential for Fe2+|Fe and Sn2+|Sn ,electrodes are -0.44 V and -0.14 V respectively. For the cell reaction, Fe2+ + Sn            Fe + Sn2+, the standard Emf is:

  • +0.30 V

  • 0.58 V

  • + 0.58 V

  • -0.30 V

On electrolysing a solution of dilute H2SO4 between platinum electrodes, the gas evolved at the anode and cathode are respectively:

  • SO2 and O2

  • SO3 and H2

  • O2 and H2

  • H2 and O2

What mass of copper will be deposited by passing 2 faraday of electricity through a solution of Cu(II) salt?

 

  • 35.6 g

  • 63.5 g

  • 6.35 g

  • 3.56 g

In electrolysis of NaCl when Pt electrode is taken then H2 is liberated at cathode while with Hg cathode it forms sodium amalgam because :

  • Hg is more inert than Pt

  • More voltage is required to reduce H+ at Hg than at Pt

  • Na is dissolved in Hg while it does not dissolve in Pt

  • Concentration of H+ ions is larger when Pt electrode is taken.

The same amount of electricity was passed through two cells containing molten Al2O3 and molten NaCl. If 1.8g of Al were liberated in one cell, the amount of Na liberated in the other cell is:

  • 4.6 g

  • 2.3 g

  • 6.4 g

  • 3.2 g

If mercury is used as cathode in the electrolysis of aqueous NaCl solution, the ions discharged at cathode are:

  • H+

  • Na+

  • OH-

  • Cl-

A gas X at 1 atm is bubbled through a solution containing a mixture of 1MY- and 1MZ- at 25°C. If the reduction potential of Z > Y > X, then:

  •  Y will oxidise X and not Z

  •  Y will oxidise Z and not X

  •  Y will oxidise both X and Z

  •  Y will reduce both X and Z

The solution of CuSO4 in which copper rod is immersed is diluted to 10 times, the reduction electrode potential:

  • increases by 0.030 V

  • decreases by 0.030 V

  • increases by 0.059 V

  • decreases by 0.059 V

A solution containing one mole per litre each of Cu(NO3)2, AgNO3, Hg2(NO3)2 and Mg(NO3)2 is being electrolysed by using inert electrodes. The values of standard electrode potentials in volt (reduction potentials) are,

Ag/Ag= 0.80, Hg22+/2Hg = 0.79,

Cu2+/Cu = +0.34 and Mg2+/Mg =-2.37

With increasing voltage, the sequency of deposition of metals on the cathode wil be:

  • Ag, Hg, Cu, Mg

  • Mg, Cu, Hg, Ag

  • Ag, Hg, Cu

  • Cu, Hg, Ag

The highest electrical conductivity of the following aqueous solution is of:

  • 0.1 M acetic acid

  • 0.1 M chloroacetic acid

  • 0.1 M fluoro acetic acid

  • 0.1 M difluoro acetic acid

How many columbs of electricity are consumed when 100 mA current is passed through a solution of AgNO3 for 30 minute during an electrolysis experiment?

  • 108

  • 18000

  • 180

  • 3000

Standard reduction potentials at 25°C of Li+/Li, Ba2+/Ba, Na+/Na and Mg2+/Mg are -3.05, -2.90, -2.71 and -2.37 V respectively. Which one of the following is the strongest oxidising agent ?

  • Mg2+

  • Ba2+

  • Na+

  • Li+

Equivalent conductances of NaCl, HCl and C2H5COONa at infinite dilution are 126.45, 426.16 and 91Ω-1cm2. The equivalent conductance of C2H5COOH is : 

  • 201.28 Ω-1cm2

  • 390.71 Ω-1cm2

  • 698.28 Ω-1cm2

  • 540.48 Ω-1cm2

When an electric current is passed through acidulated water, 112 mL of hydrogen gas at STP collects at the cathode in 965 second. The current passed, in ampere is:

  • 1.0

  • 0.5

  • 0.1

  • 2.0

The electric charge for electrode deposition of 1g equivalent of a substance is:

  • 1 ampere per second

  • 96,500 coulomb per second

  • 1 ampere for 1 hour

  • charge on 1 mole of electrons

The change in reduction potential of a hydrogen electrode change when its solution initialy at pH=0 is neutralised to pH =7 , is -

  • Increase by 0.059 V

  • Decrease by 0.059 V

  • Increase by 0.41 V

  • Decrease by 0.41 V

 The cell reaction for the given cell is spontaneous if:

Ptcl2|cl-(1M)||Cl-(1M)|PtCl2

  • P1 > P2 

  • P1 < P2

  • P1 = P2

  • P1 = 1 atm

Each of the three metals X, Y and Z were put in turn into aqueous solution of the other two.

X + Salt of Y (or Z)   Y (or Z) + Salt of X.

Which observation is probably incorrect?

  • Y + Salt of X = No action observed

  • Y + Salt of Z = Z + Salt of Y

  • Z + Salt of X = X + Salt of Z

  • Z + Salt of Y = No action observed

Cu+(aq) is unstable in solution and undergoes simultaneous oxidation and reduction according to the reaction 

2Cu+(aq) Cu2+(aq) + Cu(s)

Choose the correct E0 for above reaction if E0cu2+/cu = 0.34 V and E0cu2+/cu+ = 0.15 V 

  • -0.38 V

  • +4.9 V

  • +0.38 V

  • -0.19 V

On the basis of the information available from the reaction.

43Al + O2           23Al2O3, G =-827kJ mol-1 

of O2, the minimum EMF required to carry out the electrolysis of Al2O3 is : (F=96500 C mol-1

  • 2.14 V

  • 4.28 V

  • 6.42 V

  • 8.56 V

4.5 g of aluminium (atomic mass 27u) is deposited at cathode from Al3+ solution by a certain quantity of electric charge. The volume of hydrogen produced at STP from H+ ions in solution by the same quantity of electric charge will be

  • 44.8 L

  • 22.4 L

  • 11.2 L

  • 5.6 L

A certain current liberates 0.504 g of hydrogen in 2 hr. How many gram of copper can be liberated by the same current flowing for the same time in CuSO4 solution?

  • 12.7

  • 16

  • 31.8

  • 63.5

For the reductidon of silver ions with copper metal, the standard  cell potential was found to be + 0.46 V at 250C. The value of standard Gibbs energy, -Gwill be (F = 96500 Cmol-1)

  • -89.0 KJ

  • -89.0 J

  • -44.5 KJ

  • -98.0 KJ

A solution of sodium sulphate in water is electrolysed using inert electrodes. The products at the cathode and anode are respectively:

  • H2, O2

  • O2, H2

  • O2, Na

  • O2, SO2

If a salt bridge is removed from the two half cells, the voltage:

  • drops to zero

  • does not change

  • increases gradually

  • increases rapidly

Two electrolytic cells, one containing acidified ferrous chloride and another acidified ferric chloride are connected in series. The ratio of iron deposited at cathodes in the two cells when electricity is passed through the cells will be:

  • 3:1

  • 2:1

  • 1:1

  • 3:2

If the half-cell reaction A+eA- has a large negative reduction potential, it follows that:

  • A is readily reduced

  • A is readily oxidized

  • A- is readily reduced

  • Ais readily oxidized

Pick out the incorrect statement

  • Equivalent conductance increases with dilution

  • Molar conductance increases with dilution

  • Specific conductance increases with dilution

  • Specific resistance increases with dilution

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