When NaCl solution is electrolysed using Pt electrodes then pH of solution

  • Increases

  • Decreases

  • Remains same

  • Firstly increases and then decreases

By how much will the potential of half cell Cu2+|Cu change if the solution is diluted to 100 times at 298 K . It will  :

  • Increases by 59 mV.

  • Decreases by 59 mV.

  • Increases by 29.5 mV.

  • Decreases by 29.5 mV.

What will be the molar conductance at infinite dilution for NH4OH. If at infinite dilution the molar conductances of Ba(OH)2, BaCl2 and NH4Cl are 523.28, 280.0 and 129.8 ohm-1 cm-1 mol-1 respectively.

  •  502.88
  •  373.68
  •  251.44
  •  226.96

At 25°C the specific conductance of sturated solution of AgCl is 2.3 X 10-6 ohm-1cm-1. What will be the solubility of AgCl at 25°C if ionic conductances of Ag and Cl at infinite dilution are 61.9 and 76.3 ohm-1cm2mol-1 respectively.

  • 1.66 X 10-11M

  • 3.18 X 10-6M

  • 6.01 X 10-5M

  • 1.66 X 10-5M

2Ag(aq) + Cu(s)            Cu(aq)+2 + 2Ag(s)

The cell potential for this reaction is 0.46V. Which of the following change will increase the potential the most ?

  •  [Ag] concentration is doubled

  • [Cu2+] concentration is halved

  • Size of Cu(s) electrode is doubled

  •  size of Ag(s) electrode is decreased to half

Standard free energies of formation (in kJ/mol) at 298 K are -237.2, -394.4 and -8.2 for H2O(l), CO2(g) and pentane (g), respectively. The value of E°cell for the pentane-oxygen fuel cell is

  • (1) 968 V

  • (2) 0968 V

  • (3) 1.0968 V

  • (4) 0.0968 V

The equilibrium constant of the reaction:

 Cu (s) + 2Ag+ (aq) Cu2+ (aq) + 2Ag(s) ;

E° = 0.46 V at 298 K is:

  • 2.4 x 1010           

  • 2.0 x 1010

  • 4.0 x 1010             

  • 4.0 x 1015

Rusting of iron is envisaged as setting up of an electrochemical cell because: 

  • Oxidation of iron takes place during rusting.
  • Reduction of iron takes place.
  • Iron shows disproportionation reaction.
  • Oxygen is getting oxidised.

What will be the value of G° for the rection Cu+2 + Fe             Fe+2 + Cu , 

if ECu+2Cu = +0.34 V and EFe+2Fe = -0.44 V

  • -65.62 KJ

  • -75.27 KJ

  • -150.54 KJ

  • +150.54 KJ

At 298 K the Emf of following cell is :-

Pt|H2(1atm)|H(0.02M)||H(0.01M)|H2(1atm)|Pt

  • - 0.017 V

  • 0.0295 V

  • 0.1 V

  • 0.059 V

At 25°C temperature Zn electrode is placed in 0.1M solution of zinc salt then what will be the reduction potential ? If it is assumed that salt dissociates 25% at this dilution (EZn2+Zn° = -0.76 V)

  • -0.713 V

  • - 0.81 V

  • + 0.778 V

  • - 0.84 V

The reduction potential of Hydrogen electrode is -118mV then the concentration of Hion in solution will be :-

  • 10-4M

  • 2M

  • 0.01M

  • 10-3M

The maximum work which can be obtained from a Daniel cell -

Zn(s) | Zn+2(aq) || Cu+2(aq) | Cu(s) 

if : EZn+2Zn = -0.76 V and ECu+2Cu = 0.34 V

  • 106.15 KJ

  • -212.3 KJ

  • 424.6 KJ

  • +212.3 KJ

CuSO4 solution is treated separately with KCl and KI. In which case, Cu+2 will be reduced to Cu ?

  • with KCl

  • with KI

  • with KCl and KI both

  • None of these

How many coulombs are required to oxidise 1 mol H2O2 to O2 ?

  • 9.65 X 104 C

  • 9.3 X 104 C

  • 1.93 X 105 C

  • 19.3 X 102 C

The quantity of electricity required to reduce 12.3g of nitrobenzene to aniline with 50% current efficiency is :-

 

  • 0.6 F

  • 0.5 F

  • 1.2 F

  • 1 F

Electrolysis of hot aqueous solution of NaCl gives NaClO4 as-

NaCl +4H2O           NaClO4 + 4H2

How many faraday are required to obtain 1000 g of sodium perchlorate ?

  • 66 F

  • 122.5 F

  • 15.13 F

  • 1.86 F

The cell reaction of micro electrochemical cell formed during rusting of iron is:-

  •   O2(g) + 4H(aq)  + 4e-  2H2O (l)

  •  4Fe+2(aq)  + O2(g) + 2H2O(l)  4FeO + 4H(aq)

  •  2Fe(s) + O2(g) + 4H°(aq) 2Fe+2(aq)  + 2H2O(aq)

  •   Fe(s) Fe+2(aq) + 2e-

Which of the following is an incorrect statement :- 

  • Mercury cell is a primary cell providing a constant potential

  • During recharging lead storage cell works as electrolytic cell

  • Galvanised iron does not rust

  • In electrolytic cell reduction occurs at anode and in galvanic cell oxidation takes place at anode

For the cell reaction

Cuc1+2 (aq) +Zn(s)            ZnC2+2 (aq) + Cu(s)

the change in free energy at a given temperature is a function of 

  • lnC1

  • lnC2C1 

  • ln (C1 +C2)

  • lnC2

EMF of the following cell will be zero if

Pt(H2)|H+||H+|(H2)Pt

    P1   C1  C2    P2

  • C1P1 = C2P2

  • C1P2 = P2C1

  •  C12P2 = C22P1

  • None of these

During electrolysis of conc. H2SO4, perdisulphuric acid (H2S2O8), and O2 form in equimolar amount. The amount of H2 that will form simultaneously will be : 

  • Thrice that of O2 in moles.

  • Twice that of O2 in moles.

  • Equal to that of O2 in moles.

  • Half of that of O2 in moles.

ENi+2Ni0 = -0.25 V, EAu+3Au0 = 1.50 V

the emf of Voltaic cell

Ni | Ni+2(1M) || Au+3(1M) Au is:-

  • (1) 25 V

  • (2) -1.75 V

  • (3) 1.75 V

  • (4) 4 V

The same amount of electric current is apassed through aqueous solution of MgSO4 and AlCl3. If 2.8 g Mg metal is deposited at amount of Al metal deposited in second cell will be

  • 2.1 g

  • 2.49 g

  • 3.15 g

  • 3.73g

The potential of the following concentration cell at room temperature is-

Pt, H2(g) |H(10-6M)||H(10-4 M) | H2(g), Pt

  • -0.118V

  • -0.0591V

  • 0.118V

  • 0.0591V

Select the incorrect statement for dry cell

  • Mn is reduced from Mn+4 to Mn+3

  • NH3 gas libreted out

  • Zn is used as anode

  • Paste of NH4Cl and ZnCl2 is used

What is the current efficiency of an electrode deposition of Cu metal from CuSO4 solution in which 9.8 gm copper is deposited by the passage of 5 amperes current for 2 hours?

  • 41.4 %

  • 50%

  • 75%

  • 82.8 %

During electrolysis, 2A current is passed through an electrolytic solution for 965 s. The number of moles of electrons passed will be

  • 0.02

  • 0.01

  • 200

  • 0.037

The electrochemical cell:

Zn || ZnSO4 (0.01 M)lCuSO4(1.0M) Cu, the emf of this Daniel cell is E1 When the concentration ZnSO4 is changed to 1.0 M and that of CuSO4 changed to 0.01 M, the emf changes to E2. The relationship between E1 and E2 is : 
( Given, RTF=0.059)

  • E1 = E2

  • E1 < E2

  • E1 > E2

  • E2 = 0 E1

The molar conductivity of a 0.5 mol/dm3 solution of AgNO3 with electrolytic conductivity of 5.76x10-3 S cm-1 at 298 K is

 

  • 2.88 S cm2/mol

  • 11.52 S cm2/mol

  • 0.086 S cm2/mol

  • 28.8 S cm2/mol

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