A solution of Ni(NO3)2 is electrolysed between platinum electrodes using a current of 5 amperes for 20 minutes. What mass of Ni is deposited at the cathode?

  • 1.82 g

  • 1.95 g

  • 2.01 g

  • 1.16 g

The resistance of a cell containing 0.001M KCl solution at 298 K is 1500 Ω. The conductivity is 0.146 × 10–3 S cm–1. The cell constant would be-

1. 0.12 cm-1

2. 0.56 cm-1

3. 0.22 cm-1

4. 1.36 cm-1

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The number of Faradays required to produce 20.0 g of Ca from molten CaCl2 is-

  • 2F

  • 1F

  • 4F

  • 3F

Three electrolytic cells A, B, C containing solutions of ZnSO4, AgNO3, and CuSO4, respectively are connected in series. A steady current of 1.5 amperes was passed through them until 1.45 g of silver was deposited at the cathode of cell B. The current flow time is-

  • 14 minutes

  • 25 minutes

  • 20 minutes

  • 11 minutes

If a current of 0.5 ampere flows through a metallic wire for 2 hours, then how many electrons would flow through the wire?

1. 2.35 × 10-222. 2.25 × 10223. 1.34 × 10214. 3.16 × 1024

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What is the quantity of electricity in coulombs needed to reduce 1 mol of Cr2O72-? Consider the reaction: Cr2O72- + 14H+ + 6e-  → 2Cr+3 + 7H2O

  • 578992 C

  • 289461 C

  • 192974 C

  • 96487 C

What is the potential of hydrogen electrode in contact with a solution whose pH is 10?

  • 0.591 V

  • -0.591 V

  • 0.295 V

  • -0.295 V

What will be the emf of the cell in which the following reaction takes place? Given Ecell° = 1.05 V

Ni(s)+2Ag+(0.002 M) →Ni2+(0.160 M) + 2Ag(s)

  • 0.80 V

  • 0.91 V

  • 0.45 V

  • 0.36 V

The cell in which the following reactions occurs:

2Fe3+(aq)+2I-(aq)→2Fe2+(aq)+I2(s) has Ecell⊝= 0.236 V at 298 K.

The equilibrium constant of the cell reaction is : 

1. 9.57 × 1072. 8.43 × 1063. 3.68 × 10-74. 1.74 × 105

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The correct statement about the given galvanic cell equation is -

Zn(s) + 2Ag+­­­(aq) → Zn2+(aq) + 2Ag(s)

 

  • The current will flow from silver to zinc in the external circuit.

  • The current will flow from zinc to silver in the external circuit.

  • The current will flow from silver to zinc in the internal circuit.

  •  The current will flow from zinc to silver in the internal circuit.

The molar conductivity of 0.025 mol L−1 methanoic acid is 46.1 S cm2 mol−1.

What is the dissociation constant of methanoic acid? Given λ°(H+)= 349.6 S cm2 mol−1 and λ°(HCOO−) = 54.6 S cm2 mol-1

1. 2.43 × 104 mol L-12. 1.15 × 10-5 mol L-13. 3.67 × 10-4 mol L-14. 2.44 × 10-6 mol L-1

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The cell that will measure the standard electrode potential of a copper electrode is : 

 

  •   Pt (s) | H2(g, 0.1 bar) | H+(aq., 1M) || Cu2+(aq, 1 M)| Cu

  •   Pt (s) | H2(g, 1 bar) | H+(aq, 1M) || Cu2+ (aq, 2 M) | Cu
  •   Pt (s) | H2(g, 1 bar) | H+(ag, 1 M)|| Cu2+ (aq, 1 M)| Cu
  •   Pt (s) | H2(g, 0.1 bar) | H+(aq, 0.1 M) || Cu2+(aq, 1M) | Cu

Electrode potential for Mg electrode varies according to the equation .EMg2+| Mg=EMg2+|Mg0-0.0592log1Mg2+ .

The graph of EMg2+ / Mg vs log [Mg2+] among the following is -

 

 

 

 

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The correct statement among the following options is: 

  • Ecell and ∆rG of cell reaction both are extensive properties.

  • Ecell and ∆rG of cell reaction both are intensive properties.

  • Ecell is an intensive property while ∆rG of cell reaction is an extensive property.

  • Ecell is an extensive property while ∆rG of cell reaction is an intensive property.

The difference between the electrode potentials of two electrodes when no current is drawn through the cell is called : 

  •   Cell potential.

  •   Cell emf.

  •   Potential difference.

  •   Cell voltage.

The incorrect statement about an inert electrode in a cell is : 

  •   It does not participate in the cell reaction.

  •   It provides surface neither for oxidation or for the reduction reaction.

  •   It provides a surface for the conduction of electrons.

  •   It provides a surface for redox reaction.

An electrochemical cell can behave like an electrolytic cell when -

  •   Ecell > Eext

  •   Eext > Ecell

  •   Ecell = Eext

  •   Ecell =O

The incorrect statement about the solution of electrolytes is : 

 

  • Conductivity of solution depends upon the size of ions.

  • Conductivity depends upon the viscosity of solution.

  • Conductivity does not depend upon the solvation of ions present in solution.

  • Conductivity of solution increases with temperature.

ECr2O72-/Cr3+⊝=1.33V  ;  ECl2/Cl-⊖=1.36VEMnO4-/Mn2+⊝=1.51V    ;  ECr3+/Cr⊖=-0.74V

Use the data give above, the most stable oxidized species is : 

 

  • Cr3+ 

  •   MnO4-

  •   Cr2O72-

  •   Mn2+ 

The quantity of charge required to obtain one mole of aluminium from Al2O3 is :

 

  •   1 F

  •   6 F

  •   3 F

  •   2 F

The cell constant of a conductivity cell-

 

  •   Changes with the change of electrolyte.

  •   Changes with the change of concentration of electrolyte.

  •   Changes with the temperature of the electrolyte.

  •   Remains constant for a cell.

Correct statement about charging of the lead storage battery is -

 

  •   PbSO4 anode is reduced to Pb

  •    PbSO4 cathode is reduced to Pb

  •   PbSO4 cathode is oxidised to Pb

  •   PbSO4 anode is oxidised to PbO2

Λm°NH4OH is equal to -

  •   Λ°°mNH4OH+Λ°mNH4Cl-Λ°(HCl)

  •   Λ°mNH4Cl+Λ°m(NaOH)-Λ°(NaCI)

  •   ΛmNH4Cl0+Λm(NaCl)0-Λ0NaOH

  •   Λm(NaOH)°+Λm(NaCl)°-Λ°NH4Cl

In the electrolysis of concentrated aqueous sodium chloride solution, the  half cell reaction will occur at the anode is : 

 

  •  Na+aq+e-⟶Nas   ;   Ecell⊖=-2.71V

  •  2H2Ol⟶O2 g+4H+aq+4e-  ;   E°cell=1.23V

  •  H+aq+e-⟶12H2 g     ;    Ecell °=0.00V

  •  Cl-aq⟶12Cl2g+e-   ;      Ecell°=1.36V

Match the terms given in Column I with the items given in Column II.

Column I

Column II

A. Λm

B. Eocell 

C. κ

D. ∆rGcell

1. Intensive property

2. Depends on number of ions/volume

3. Extensive property

4. Increases with dilution

Codes

          A          B          C           D

  •        2          3           4           1

  •        1          2           3           5

  •        5          4           3           2

  •        4          1           2           3

Assertion: Current stops flowing when Ecell = 0.

Reason: Equilibrium of the cell reaction is attained.

  •   Both assertion and reason are true and the reason is the correct explanation of assertion.

  •   Both assertion and reason are true and the reason is not the correct explanation of assertion.

  •   Assertion is true but the reason is false.

  •   Both assertion and reason are false.

Assertion: Copper sulphate can be stored in a zinc vessel.

Reason: Zinc is less reactive than copper.

  • Both assertion and reason are true and the reason is the correct explanation of assertion.

  •   Both assertion and reason are true and the reason is not the correct explanation of assertion.

  •   Assertion is true but the reason is false.

  •   Both assertion and reason are false.

In a typical fuel cell, the reactants (R) and product (P) are :-

  •  R=H2(g), O2(g); P=H2O2(l)

  •  R=H2(g), O2(g); P=H2O(l)

  •  R=H2(g), O2(g), Cl2(g); P=HClO4(aq)

  •  R=H2(g), N2(g); P=NH3(aq)

The Gibb's energy for the decomposition of Al2O3 at 500°C is as follows: 

23Al2O3→43Al + O2;∆rG = +960 kJ mol-1

The potential difference needed for the electrolytic reduction of aluminium oxide
(Al2O3) at 500°C is at least,

  •   3.0 V 

  •   2.5 V 

  •   5.0 V 

  •   4.5 V 

Molar conductivities (∧°m) at infinite dilution of NaCl, HCl and CH3COONa are 126.4, 425.9 and 91.0 S cm2 mol-1 respectively. (∧°m)  for CH3COOH  will be:

  •   180.5 S cm2mol-1

  •   290.8 S cm2mol-1

  •   390.5 S cm2mol-1

  •   425.5  S cm2mol-1

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