Which is hydrazoic acid's conjugate base?
HN3-
N2-
Azide ion
Nitride ion
Among the following , the compound with highest pH is :
CH3COOK
Na2CO3
NH4Cl
NaNO3
The phenomenon of interaction of anions and cations furnished by an electrolyte with the H+ and OH- ions of water to produce acidic nature or alkalinity is known as hydrolysis. In hydrolysis:
the pH may either increase or decrease
all the salts (except those made up with strong acid and base) undergo hydrolysis
the variation of pH depends upon the nature of salts as well as on the temperature
all of the above
The degree of dissociation of PCl5 (α) obeying the equilibrium,
PCl5 (g) ⇌ PCl3 (g) + Cl2 (g), is approximately related to the pressure at equilibrium by:
α∝P
α∝1/P
α∝1/P2
α∝1/P4
In a system: A(s)⇌ 2B(g) + 3C(g). If the concentration of C at eqilibrium is increased by a factor 2, it will cause the eqilibrium concentration of B to change to:
two times of its original value
one half of its original value
22 times of its original value
122 times of its original value
A weak acid, HA has a Ka of 1.00 x 10-5. If 0.100 mole of this acid is dissolved in one litre of water, the percentage of acid dissociated at equibrium is closest to
99.9%
1.00%
0.100%
If little heat is added to ice ⇌ liquid equilibrium in a sealed container, then:
Pressure will rise
Temperature will rise
Temperature will fall
No change in P and T
In the equilibrium,
2SO2(g) + O2 (g) ⇌2SO3(g), the partial pressure of SO2, O2 and SO3 are 0.662, 0.101 and 0.331 atm respectively. What should be the partial pressure of oxygen so that the equilibrium concentration of SO2 and SO3 are equal.
0.4 atm
1.0 atm
0.8 atm
0.25 atm
Ionisation constant of CH3COOH is 1.7 X 10-5 and concentration of H+ ions is 3.4 X 10-4.Then, find out initial concentration of CH3COOH molecules.
3.4 X 10-4
3.4 X 10-3
6.8 X 10-4
6.8 X 10-3
The formation of phosgene is represented as,
CO + Cl2 ⇌COCl2
The reaction is carried out in 500 mL flask. At equilibrium o.3 mole of phosgene, 0.1 mole of CO and 0.1 mole of Cl2 are present. The equilibrium constant of the reaction is:
30
15
5
3
For the equilibrium, PCl5 ⇌ PCl3 + Cl2,
KC=α2/(1-α)V, temperature remaining constant:
Kc will increase with the increase in volume
Kc will increase with the decrease in volume
Kc will not change with the change in volume
Kc may increase or decrease with the change in volume depending upon its numerical value.
For the reaction,
PCl5(g) ⇌ PCl3(g) + Cl2 (g)
The forward reaction at constant temperature is favoured by
Introducing an inert gas at a constant volume
Introducing chlorine gas at a constant volume
Introducing an inert gas at constant pressure
None of the above
In the dissociation of 2HI ⇌H2 + I2, the degree of dissociation will be influenced by the:
addition of inert gas at constant volume
addition of inert gas at constant pressure
increase of temperature
increase of pressure
The correct order of increasing [H3O+] in the following aqueous solutions is:
0.01 M H2S < 0.01 M H2SO4<0.01 M NaCl<0.01M NaNO2
0.01 M NaCl< 0.01 M NaNO2<0.01 M H2S< 0.01 M H2SO4
0.01 M NaNO2<0.01 M NaCl<0.01 M H2S<0.01 M H2SO4
0.01 M H2S<0.01 M NaNO2<0.01 M NaCl<0.01 M H2SO4
If the pressure of N2 and H2 mixture in a closed apparatus is 100 atm and 20% of the mixture then reacts, the pressure at the same temperature would be:
100
90
85
80
The following reactions are known to occur in the body,
CO2 + H2O⇌H2CO3⇌H+ + HCO3-
If CO2 escapes from the system, then:
pH will decrease
hydrogen ion concentration will diminish
H2CO3 concentration will be unaltered
the forward reaction will be promoted
Which salt undergoes hydrolysis?
CH3COONa
KNO3
NaCl
K2SO4
Buffer solution among the following options is :
HNO2 and NaNO2
NaOH and NaCl
HNO3 and NH4NO3
HCl and KCl
According to Le-Chatelier's principle, adding heat to a solid ⇌ liquid equilibrium will cause the
Temperature to increase
Temperature to decrease
Amount of liquid to decrease
Amount of solid to decrease
Ostwald's solution dilution law is applicable in the case of the solution of:
CH3COOH
NaOH
H2SO4
The pKa of acetylsalicylic acid (aspirin) is 3.5. The pH of gastric juice in the human stomach is about 2-3 and the pH in the small intestine is about 8. Aspirin will be:
Unionized in the small intestine and in the stomach
Completely ionized in the small intestine and in the stomach
Ionized in the stomach and almost unionized in the small intestine
Ionized in the small intestine and almost unionized in the stomach
What is [H+] in mol/L of a solution that is 0.20 M in CH3COONa and 0.10 M in CH3COOH?
(Ka for CH3COOH = 1.8 x 10-5)
3.5x10-4
1.1x10-5
1.8x10-5
9.0x10-6
The hydrolysis of the salt of strong acid and a weak base is called:
anionic hydrolysis
cationic hydrolysis
amphoteric hydrolysis
none of the above
For the reaction, A+B⇌3C at 25° C, a 3 litre vessel contains 1,2, 4 mole of A, B and C respectively. If Kc for the reaction is 10, the reaction will proceed in:
forward direction
backward direction
in either direction
in equilibrium
The pH of 0.1M soution of the folowing salts increases in the order:
NaCl < NH4Cl < NaCN < HCl
HCl < NH4Cl < NaCl < NaCN
NaCN < NH4Cl < NaCl < HCl
HCl < NaCl < NaCN < NH4Cl
The equilibrium constant Br2 ⇌2Br at 500 K and 700 K are 10-10 and 10-5 respectively. The reaction is:
(a) endothermic (b) exothermic
(c) fast (d) slow
a,b
c,b
a,d
4 c,d
Three reactions involving H2PO4- are given below:
(i) H3PO4 + H2O →H3O+ + H2PO4-
(ii) H2PO4- + H2O →HPO42- + H3O+
(iii) H2PO4- + OH- →H3PO4 +O2-
In which of the above does H2PO4- act as an acid?
(i) only
(ii) only
(i) and (ii)
(iii) only
Which of the following is most soluble in water?
MnS (Ksp = 8x10-37)
ZnS (Ksp = 7x10-16)
Bi2S3 (Ksp = 1x10-70)
Ag2S (Ksp = 6x10-51)
The compound that does not act as Lewis acid is:
AlCl3
BF3
NH3
FeCl3
For which salt the pH of its solution does not change with dilution?
CH3COONH4
None of these
For a sparingly soluble salt ApBq, the relationship of its solubility product (Ls) with its solubility (s) is:
Ls =sp+q.pp.qq
Ls =sp+q.pq.qp
Ls =spq.pp.qq
Ls = spq.(pq)p+q
For the reaction, N2 + 3H2 ⇌2NH3 in a vessel, after the addition of an equal number of mole of N2 and H2, the equilibrium state is formed. Which of the following is correct?
[H2] = [N2]
[H2] < [N2]
[H2] > [N2]
[H2] > [NH3]
The conjugate base of [Al(H2O)3(OH)3] is:
[Al(H2O)3(OH)2]+
[Al(H2O)3(OH)2O]-
[Al(H2O)3(OH)3]-
[Al(H2O)2(OH)4]-
For NH4HS(s) ⇌NH3 (g) + H2S(g), the observed pressure for reaction mixture in equilibrium is 1.12 atm at 106°C. The value of Kp for the reaction is:
3.136 atm2
0.3136 atm2
31.36 atm2
6.98 atm2
Which oxide of nitrogen is the most stable?
2NO2(g) ⇌N2(g) + 2O2(g); K=6.7x1016 mol litre-1
2NO(g) ⇌N2(g) + O2(g); K=2.2x1030 mol litre-1
2N2O5(g) ⇌2N2(g) + 5O2(g); K=1.2x1034 mol-5 litre-5
2N2O(g) ⇌2N2(g) + O2(g); K=3.5x1033 mol litre-1
On adding A to the reaction at equilibrium, AB(s) ⇌ A(g) + B(g), the new equilibrium concentration of A becomes double, the equilibrium concentration of B would become:
1/2 of its original value
1/4 of it s original value
1/8 of its original value
twice of its original value
2 mole of PCl5 were heated in a closed vessel of 2 litre capacity. At equilibrium 40% of PCl5 dissociated into PCl3 and Cl2. The value of the equilibrium constant is :
0.267
0.53
2.63
5.3
Given, HF + H2O→KaH3O+ + F-
F- + H2O →KbHF + OH-
which relation is correct?
Kb =Kw
Kb =1/Kw
Ka x Kb =Kw
Ka/Kb = Kw
The value sf Kp1 and Kp2 for the reactions
X⇌Y+Z ....(1)
and A⇌2B ......(2)
are in the ratio 9:1. If the degree of dissociation of X and A be equal, then total pressure at equilibrium (1) and (2) are in the ratio:
1. 1:9
3. 1:1
2. 36:1
4. 3:1
The relation for calculating pH of a solution containing weak acid and its salt is:
pH = pKa + log[Conjugate Base][Acid]
pH = pKa - log[Conjugate Base][Acid]
pH = pKa + log[Conjugate Base][Salt]
pOH = pKa - log[Acid][Conjugate Base]
The equilibrium constants for the reaction,
A2 ⇌2A at 500 K and 700 K are 1x10-10 and 1x10-5. The given reaction is
(a) exothermic (b) slow
(c) endothermic (d) fast
2.c,b
3.a,d
For the chemical reaction, 3X(g) + Y(g) ⇌X3Y(g) ;
the amount of X3Y at equilibrium is affected by :
Temperature and pressure
Temperature only
Pressure only
Temperature, pressure and catalyst
H2S gas when passed through a solution of cations containing HCl precipitates the cations of the second group in qualitative analysis but not those belonging to the fourth group. It is because-
Presence of HCl decreases the sulphide ion concentration
Presence of HCl increases the sulphide ion concentration
Solubility product of group II sulphides is more than that of group IV sulphides
Sulphides of group IV cations are unstable in HCl
Solubility of a gas in liquid increases on:
Addition of a catalyst
Increasing the pressure
Decreasing the pressure
Increasing the temperature
A solution is called saturated if:
ionic concentration product < solubility product
ionic concentration product > solubility product
ionic concentration product ≥ solubility product
1L of an aqueous solution contains 0.15mole of CH3COOH (pKa = 4.8) and 0.15 mole of CH3COONa. After the addition of 0.05 mole of solid NaOH to this solution, the pH will be
4.5
4.8
5.1
5.4
The concentration of [H+] and concentration of [OH-] of a 0.1M aqueous solution of 2% ionised weak monobasic acid is
[ionic product of water = 1x 10-14]
0.02x10-3 M and 5x10-11 M
1x10-3 M and 3x10-11 M
2x10-3 M and 5x10-12 M
3x10-2 M and 4x10-13 M
The relation for calculating pH of a weak base is:
pH =pKw -1/2 pKb + 1/2 logc
pH =pKw +1/2 pKb - 1/2 logc
pH =pKw -1/2 pKa + 1/2 logc
Eight mole of a gas AB3 attain equilibrium in a closed container of volume 1 dm3 as,
2 AB3 ⇌ A2(g) + 3B2(g). If at equilibrium 2 mole of A2 are present then, equilibrium constant is:
72 mol2L-2
36 mol2L-2
3 mol2L-2
27 mol2L-2
Which is Lewis base?
HCl
HNO3
HF
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