4 gm of NaOH is dissolved in 1000 ml of water. The H+ ion concentration will be -

  •  10-1 M

  •  10-13 M

  •  10-4 M

  •  10-10 M

The solubility product of a sparingly soluble salt AX2 is 3.2 ×10–11. It's solubility (in moles/litre) is:-

  • 3.1×10–4

  • 2 × 10–4

  • 4 × 10–4

  • 5.6 × 10–6

A compound BA2 has \(K_{sp} = 4\times 10^{-12}\) ; solubility of this compound will be :

  • 10-3

  • 10-4

  • 10-5

  • 10-6

For a reaction , BaO2(s)BaO(s)+O2(g); ∆H = + ve.
At equilibrium condition, pressure of O2  depends on : -

  • Increase mass of BaO2

  • Increase mass of BaO

  • Increase temperature on equilibrium.

  • Increase mass of BaO2 and BaO both.

The compound with highest pH among the following is : -

  • CH3COOK

  • Na2CO3

  • NH4Cl

  • NaNO3

Solution of 0.1 N NH4OH and 0.1 N NH4Cl has pH 9.25. Then pkb of NH4OH is : -

  •  9.25

  •  4.75

  •  3.75

  •  8.25

A compound among the following that can be classified as not a protonic acid,is  :

  • B(OH)3

  • PO(OH)3

  • SO(OH)2

  • SO2(OH)2

The volume of the container containing a liquid and its vapours at a constant temperature is suddenly increased. The effect of the change on vapour pressure would be :

 

  • It would decrease initially.

  • It would increase initially.

  • It would remain the same.

  • None of the above.

For the following reaction, 

2SO2(g) + O2(g) ⇋ 2SO3(g)

The value of Kc at equilibrium with a concentration of [SO2]= 0.60M,[O2] = 0.82M and [SO3] = 1.90M

would be:

  • 8.5 

  • 3. 12 

  • 4. 16.3 

  • 2. 9.4 

Pure liquids and solids are ignored while writing the expression for the equilibrium constant because 

  • Size and shape of a pure substance are always fixed.

  • Volume of solids and liquids is relatively fixed.

  • Charges and masses of pure substances are always fixed 

  •   All of the above

 For a given reaction, 2N2 (g) + O2 (g)  ⇋ 2N2O (g), if a mixture of 0.482 mol N2 and 0.933 mol of O2 is placed in a 10 L vessel and allowed to form N2O at a temperature for which Kc= 2.0 × 10–37 L mol-1, the concentration of N2O at equilibrium will be -

  •   6.6 X 10-21 M

  •   0.6 X 10-21 M

  • 4.6 X 10-11 M

  • 3.6 X 10-31 M

For a reaction, 2NO (g) + Br2 (g)  2NOBr (g)

When 0.087 mol of NO and 0.0437 mol of Br2 are mixed in a closed container at a constant temperature, 0.0518 mol of NOBr is obtained at equilibrium. The concentration of NO and Br2 at equilibrium will be:

  •  NO = 0.0352 mol; Br2= 0.0178 mol

  •  NO = 0.352 mol; Br2= 0.178 mol

  •  NO = 0.0634 mol; Br2= 0.0596 mol

  •  NO = 0.634 mol; Br2= 0.596 mol

For the reaction: H2 (g) + I2 (g)  ⇌ 2HI (g) ; Kc54.8 at 700K .

If 0.5 mol L–1 of HI(g) is present at equilibrium at 700 K, the concentration of H2(g) and I2(g)  would be:

  • [H2]= [I2]=0.05 mol L-1

  • [H2]= 0.5 mol L-1, [I2] = 0.05 mol L-1

  • [H2] = 0.068 mol L-1, [I2]= 0.55 mol L-1

  • [H2] = [I2] =0.068 mol L-1

When the initial concentration of ICl is 0.78 M, what will be the equilibrium concentration of ICl?

2ICl(g) ⇋ I2(g) + Cl2(g); Kc = 0.14

  • 0.446 M

  • 0.876 M

  • 0.345 M

  • 0.986 M

Given the reaction: CH3COOH (l) + C2H5OH (l)  CH3COOC2H5 (l) + H2O (l)

At 293 K, if one starts with 1.00 mol of acetic acid and 0.18 mol of ethanol, there is 0.171 mol of ethyl acetate in the final equilibrium mixture. The equilibrium constant of the reaction will be-

  • 0.78

  • 1.3

  • 2.47

  • 3.92

(a) PCl5 (g) PCl3 (g) + Cl2 (g)

(b) CaO (s) + CO2 (g)   CaCO3 (s)

(c) 3Fe (s) + 4H2O (g)  Fe3O4 (s) + 4H2 (g)

The effect of an increase in the volume on the number of moles of products in the above-mentioned reactions would be, respectively:

  • a) Increase,  b) decrease, c) same

  • a) Decrease,  b) same, c) increase

  • a) Increase,  b) increase, c) same

  • a) Increase,  b) decrease, c) increase

Consider the following reactions.

(i) COCl2 (g)  ⇋ CO (g) + Cl2 (g)

(ii) CO2 (g) + C (s)  2CO (g)

(iii) 2H2 (g) + CO (g)  CH3OH (g)

Which reaction(s) shift in a backward manner when the pressure is increased?

  • Only (iii)

  • Only (ii)

  • Both (i) and (ii) 

  • None of the above

Given an endothermic reaction:

CH4 (g) + H2O (g)  ⇋ CO (g) + 3H2 (g)

If the temperature is increased, then 

  •  The equilibrium will not be disturbed.

  • The equilibrium will shift in the backward direction.

  • The equilibrium will shift in the forward direction.

  • None of the above

For the given reaction: 

PCl5 (g)  PCl3 (g) + Cl2 (g), ∆r = 124.0 kJ mol–1 and Kc = 8.3 × 10-3 mol L-1 at 473 K

The effect on Kc if (i) pressure is increased  and (ii) the temperature is increased will be, respectively-

  •  (i) Will increase; (ii) will decrease

  • (i) Will decrease; (ii) will remain the same 

  •  (i) Will remain the same; (iii) will increase

  • (i) Will decrease; (ii) will remain the same

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