The solubility product of a sparing soluble salt AX2 is 3.2×10-11. Its solubility (in mol L-1) is

  •  5.6×10-6

  •  3.1×10-4

  •  2×10-4

  •  4×10-4

An acid solution of 0.005 M has a pH of 5. The degree of ionization of acid is

  •  0.1×10-2

  •  0.2×10-2

  •  0.5×10-4

  •  0.6×10-6

pKa value of four acids are given below. The strongest acid is

(I) 4.0

(II) 3.5

(III) 2.5

(IV) 2

  • I

  • II

  • III

  • IV

A solution has hydrogen ion concentration 0.0005 M, its pOH is

 

  • 8.2798

  • 10.6990

  • 12.7854

  • 13.3344

At 25°C, the pH of a solution containing 0.10 M sodium acetate and 0.03 M acetic acid will be:

[pKa value of CH3COOH=4.57]-

  • 3.24

  • 4.59

  • 5.09

  • 6.67

Ionization constant of acetic acid is 1.8×10-5. The concentration of H+ ions in 0.1 M solution is

  •  1.8×10-3 M

  •  2.8×10-3 M

  •  1.3×10-3 M

  •  1.34×10-4 M

The dissociation constant of a weak acid is 4.9×10-8, its percentage ionization at 0.1 M is

  • 0.07%

  • 0.007%

  • 0.7%

  • 0.0007%

The pH of a 0.1 M aqueous solution of a weak acid (HA) is 3. What is its degree of dissociation?

  • 1%

  • 10%

  • 50%

  • 25%

75 ml of 0.2 M HCl is mixed with 25 ml of 1M HCl. To this solution, 300 ml of distilled water is added. What is the pH of the resultant solution?

  • 1

  • 2

  • 4

  • 0.2

The dissociation constant of two acids HA1 and HA2 are 3.0×10-4 and 1.8×10-5 respectively. The relative strengths of the acids is

  • 1:16

  • 1:4

  • 4:1

  • 16:1

0.005 M acid solution has 5 pH. The percentage ionization of acid is

  • 0.8%

  • 0.6%

  • 0.4%

  • 0.2%

100 ml of 0.015 M HCl solution is mixed with 100 ml of 0.005 M HCl. What is the pH of the resultant solution?

  • 2.5

  • 1.5

  • 2

  • 1

The solubility product of A2X3 is 1.08×10-23. Its solubility will be

  •  1.0×10-6 M

  •  1.0×10-3 M

  •  1.0×10-4 M

  •  1.0×10-5 M

M(OH) x has Ksp=4×10-12 and solubility 10-4 M, x is

  • 2

  • 3

  • 4

  • 1

The pH values of 1 M solutions of CH3COOH (I), CH3COONa (II), CH3COONH4 (III), and KOH (IV) will be in the order

  • IV>III>II>I

  • IV>II>III>I

  • I>III>II>IV

  • II>I>III>IV

What should be the ratio of the concentration of salt and acid for preparing a buffer solution of pH 6 by mixing sodium acetate and acetic acid?(Ka=10-5)

  • 1:10

  • 10:1

  • 100:1

  • 1:100

The strongest Bronsted base among the following ions is

  • CH3O-

  • (CH3)2CHO-

  • C2H5O-

  • (CH3)3CO-

The degree of ionization of water was found to be 1.8×10-9. The Ka (ionization constant) of water is

  •  1.8×10-9

  •  1.8×10-16

  •  1.8×10-14

  • cannot be calculated

The decreasing order of acidic nature of H2SO4 (I), H3PO4 (II), and HClO4 (III) is

  • I>II>III

  • I>III>II

  • III>I>II

  • III>II>I

The number of H+ ions present in 1cm3 of a solution whose pH is 10 is

  •  10-10

  •  10-13

  •  6.02×1010

  •  6.02×1013

The Ka value of formic acid and acetic acid are respectively 1.77×10-4 and 1.75×10-5. The ratio of the acid strength of 0.1 N acids is

  • 0.1

  • 0.3

  • 3.178

  • 100

ZnS is not precipitated by passing H2S in an acidic medium but CuS is precipitated. The reason for it is

  • Ksp CuS<<Ksp ZnS

  •  Ksp CuS>>Ksp ZnS

  • Ksp CuS=Ksp ZnS

  • None of these

Consider the following acids:

I. HCN

II. CH3COOH

III. HCOOH

IV. Cl-CH2COOH

The correct order of strength is

  • II>III>I>IV

  • IV>II>III>I

  • IV>III>II>I

  • III>II>IV>I

The hydrogen ion concentration is 0.2 M ethanoic acid (KC=2×10-5 mol dm-3) is approximately

  •  10-4

  •  2×10-2

  •  2×10-6

  •  2×10-3

The pH of a solution made by mixing 50 mL of 0.01 M barium hydroxide solution with 50 mL of H2O is

  • 3.0

  • 6.0

  • 12.0

  • 15.0

Find the molar solubility of Fe(OH)3 in a buffer solution that 0.10 M in NH4Cl and 0.10 M in NH3. If Kb (NH3)=1.8×10-5 and Ksp [Fe(OH)3]=2.6×10-39.

  •  4.458×10-25 M

  •  3.458×10-25 M

  •  2.229×10-24 M

  •  4.458×10-22 M

A base dissolved in water yields a solution with a hydroxyl ion concentration of 0.05 mol litre-1. The solution is

  • basic

  • acid

  • neutral

  • either 2 or 3

Ionization constant of CH3COOH is 1.7×10-5 and concentration of H+ ion is 3.4×10-4. Then initial concentration of CH3COOH is

  •  3.4×10-4

  •  3.4×10-3

  •  6.8×10-4

  •  6.8×10-3

At 25°C the dissociation constant of a base, BOH is 1.0×10-12, the concentration of hydroxyl ions 0.01 M aqueous solution of the base would become

  •  2.0×10-6 mol L-1

  •  1.0×10-5 mol L-1

  •  1.0×10-6 mol L-1

  •  1.0×10-7 mol L-1

The solubility product of AgI at 25°C is 1.0×10-16 mol2 L-2. The solubility of AgI in 10-4 N solution of KI at 25°C is :  (in mol L-1)

  •  1.0×10-10

  •  1.0×10-8

  •  1.0×10-16

  •  1.0×10-12

When 0.1 mole of CH3NH2 (ionization constant Kb=5×10-4) is mixed with 0.08 mol HCl and the volume is made up of 1 litre. The [H+] of resulting solution is -

(log 4 =  0.60)

  •  8×10-2

  •  2×10-11

  •  1.23×10-4

  •  8×10-11

Which of the following solutions will have a pH value that is close to 1.0?

  • 100 ml of (M/10) HCl + 100 ml of (M/10) NaOH

  • 55 ml of (M/10) HCl + 45 ml of (M/10) NaOH

  •  10 ml of (M/10) HCl + 90 ml of (M/10) NaOH

  • 85 ml of (M/10) HCl + 15 ml of (M/10) NaOH

If Ag++2NH3Ag(NH3)2+; K1=1.8×107

Ag++Cl-AgCl; K2=5.6×109

Then for

AgCl+2NH3[Ag(NH3)2]++Cl-,

Equilibrium constant will be

2. 3.11×102

  •  0.32×10-2

  •  10.08×1016

  • 3
  •  1.00×10-17

There sparingly soluble saltrs A2X, AX and AX3 have the same solubility product.Their solubilities will be in the order

  • AX3>AX>A2X

  • AX3>A2X>AX

  • AX>AX3>A2X

  • AX>A2X>AX3

Which of the following solution(s) have pH between 6 and 7?

I. 2×10-6 MNaOH

II. 2×10-6 MHCL

III. 10-8 MHCl

IV. 10-13 MNaOH

  • I, II

  • II, III

  • III, IV

  • II, III, IV

What is the pH value at which Mg(OH)2 begins to precipitate from a solution containing 0.10 M Mg+2 ion? Ksp of Mg(OH)2 is 1×10-11.

  • 3

  • 6

  • 9

  • 11

50 litres of 0.1 M HCl are mixed with 50 litres of 0.2 M NaOH. The pH of the resulting solution is

  • 12.70

  • 12.34

  • 8.7

  • 4.2

The pH of a 0.05 M aqueous solution of diethylamine is 12. Its Kb value will be:

  •  2×10-3

  •  2.5×10-3

  •  3×10-3

  •  4.5×10-3

Ka for HCN is 5×10-10 at 25°C. For maintaining a constant pH of 9, the volume of 5 M KCN solution required to be added to 10 mL of 2 M HCN solution is-

  • 2 mL

  • 3. 4.2 mL

  • 2. 3 mL

  • 5.6 mL

The approximate pH of a solution formed by mixing equal volumes of solutions of 0.1 M sodium propionate and 0.1 M propanoic acid (the dissociation constant of propanoic acid is 1.3×10-5 mol dm-3) will be

  • 2.45

  • 4.89

  • 5.98

  • 6.89

The dissociation constant of acetic acid is 1.6×10-5. The degree of dissociation (α) of 0.01 M acetic acid in the presence of 0.1 M HCl is equal to

  • 0.4

  • 0.026

  • 1.6

  • 0.016

If the equilibrium constant of the reaction of weak acid HA with strong base is 109, then pH of 0.1 M NaA is

  • 3

  • 9

  • 7

  • 6

If Ksp of Al(OH)3 is 1.0×10-15 M. Find at what pH does 1.0×10-3 M Al3+ precipitate on the addition of buffer of NH4Cl and NH4OH solution.

  • 10

  • 10.5

  • 11

  • 12

The solubility of CaF2 in water at 298 K is 1.7×10-3 gm per 100 cm3. The solubility product of CaF2 at 298 K is

  •  4.14×10-11

  •  4.14×1011

  •  4.14×10-6

  •  4.14×106

A solution of monoprotic weak acid has acidity constant Ka the minimum intial concentration 'c' in terms of Ka, such that the concentration of the undissociated acid can be equated to 'c' within a 10% limit of error, would be

  • 70 Ka

  • 90 Ka

  • 50 Ka

  • 30 Ka

The solubility product of PbI2 is 7.47×10-9 at 15°C and 1.39×108 at 25°C. The molar heat of solution of PbI2 is (use log 1.86=0.2695)

  • 44.29 kJ/mol

  • 46.25 kJ/mol

  • 29.37 kJ/mol

  • 21.15 kJ/mol

Which of the following compounds is in the correct sequence in terms of relative basic strength?

  •  C2H5O->CHC->OH-

  •  CHC->-OH>C2H5O-

  •  CHC->C2H5O->OH-

  •  C2H5O->OH->CHC-

The concentration of CH3COOH that will have the same [H+] as obtained from 10-2 M HCOOH, is-

(Ka(CH3COOH)=10-5, Ka(HCOOH)=10-4)

  • 10 M

  • 5 M

  • 10-1 M

  • 6 M

When NH4Cl is added to an aqueous solution of NH4OH, then

  • Concentration of [OH-] ions decreases.

  •  Concentration of [OH-] ions increases.

  • Concentration of [NH4+] ions as well as concentration [OH-] ions increase.

  • Concentration of [NH4+] ions decreases.

500 ml of 0.2 M HCl is mixed with 500 ml of 0.2 M CH3COOH. 25 ml of the mixture is titrated with 0.1 M NaOH solution. By how many units does the pH change from the start to the stage when HCl is just completely neutralized. Ka for acetic acid=2.0×10-5.

  • 3.7

  • 4.4

  • 2.0

  • 3.0

0:0:1


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