Relative rate of reaction of the following amine with methyl iodide is:

  • A > B > C

  • A > C > B

  • B > C > A

  • B > A > C

 

Major product of the above reaction is:

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Anisolerefluxexcess HI (conc.)Product

 

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Which of the following compounds would react faster with NaCN in an SN2 reaction?

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Product (A) and (B) respectively are:-
(a) 
(b)
(c)
(d)

 

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NH3(l)2 eq. KNH2then H3On-C4H9-Br(P);End product (P) of the above reaction is:

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What would be the major product of the given reaction?

    

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(A)In the above reaction, maximum Saytzeff product will obtained when
     (a) X = I    (b) X = -Cl      (c) X = -Br       (d) X = -F

(B) In the above reaction Hofmann product is major when X is:
      (a) -I          (b) -Cl            (c) -Br             (d) -F

  • A- a , B - d

  • A- b, B - c

  • A -c , B - a 

  • A - d, B -d

   Product; Product of the reaction is:

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  • No reaction

Major product of the reaction is:

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  •  Ph-CH-CH-Ph          |         |          CH3 OH

Product obtained in above reactions (1), (2) & (3) is:

  • () A = B, C is different
  • () A = C, B is different
  • () B = C, A is different
  • () A = B = C is same

          CH3           |CH3CCHCH3           |       |          CH3    Br      EtOHA

Major product (A) is:

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Which one of the following compound will be least susceptible to elimination of hydrogen bromide ?

 

  • Br-CH2-CH2-NO2
  • Br-CH2-CH2-CH3

  • Br-CH2-CH2-CN

  • Br-CH2-CH2-Co2Et

Two alkenes, X(91% yield) and Y(9% yield) are formed when the following compound is heated.

The structures of X and Y, respectively are:

In the dehydrohalogenation of 2-bromobutane; which conformation leads to the formation of cis-2-butene ?

End product (D) in the given sequence is:

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CH3-C|Br|Br-C|Br|Br-CH3xNaNH2yCH3lCH3-CC-CC-CH3

x and y mole consumed.

Value of x + y =

  • 5

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The major product obtained in the reaction of 1-phenyl-2-bromobutane with NaOMe is :

  • trans-1 -phenylbut-1-ene

  • cis-1-phenylbut-2-ene

  • 1-phenyl-2-ethoxybutane

  • cis-1-phenylbut-2-ene


Identify A:-

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Ph-CH-CH2-CH2     Product
      l            l    Zn-Cu
     Br          Br     Δ

Product of the above reaction is:-

  • Ph-CH=CH-CH2-Br

  • Ph-◁

  • PH-CHBr-CH=CH2

  • Ph-C C-CH3

alc.KOH(A), Product A is:

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+ CH3I (excess) product; The product is :

  • a primary amine

  • a tertiary amine

  • a secondary amine

  • a quaternary ammonium salt

Br                  Br
 l                    l   
CH2-CH=CH-CH2(A)
                       Zn(dust)
Above reaction is an example of 1,4-elimination.Predict the product.

  • CH3-CH=C=CH2
  • CH3-CC-CH3
  • CH3-CH2-CCH
  • H2C=CH-CH=CH2

Which is the major product expected from the following SN2 reaction?

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CH3C|XH·CH2CH3475KH2SO4 

The correct statement among the following is -

 

  • CH3-CH=CH-CH3 predominates

  • CH2=CH-CH2-CH3 predominates

  • Both are formed in equal amounts

  • The product ratio is dependent on the halogen X

Ethylidene dichloride on treatment with aqueous KOH gives:

  • CH3CHO

  •  CH2OH|CH2OH

  • HCHO

  •  CHO|CHO

Vicinal and geminal dihalides can be distinguished by:-

  • KOH (aq)

  • KOH(alc.)

  • Zn dust

  • None of the above

           CH3           |CH3CCH3           |          Br
        (a)
CH3-CH-CH3
         l
        Br
        (b)   
CH3-CH-Br     
       (c)
Compare rate of E2 reaction:-
(1)c>b>a

(2)a>b>c

(3)b>a>c

(4)c>a>b
           

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Which is the major product of the following reaction?

 H2OheatNaOH Product

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1-2-dichloro ethane + NaSCH2CH2SNa  P (C4H8S2

Unknown product (p) of the above reaction is:

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  •  H-S-CH=CH-CH=CH-S-H

  •  H-CH=CH-CH2-S-H

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