The IUPAC name of p -ClC 6 H 4 CH 2 CH(CH 3 ) 2 is -

1−Chloro−4−(2−methylpropyl) benzene

4−Chloro−1−(2−methylpropyl) benzene

1−Chloro−4−(3−methylpropyl) benzene

4−Chloro−4−(3−methylpropyl) benzene

The IUPAC name of CH 3 C( p -ClC 6 H 4 ) 2 CH(Br)CH 3 is -

2−Bromo−3,3−bis(4−chlorophenyl) butane

4−Bromo−3,3−bis(2−chlorophenyl) butane

2−Bromo−1,1−bis(4−chlorophenyl) butane

4−Bromo−1,1−bis(2−chlorophenyl) butane

Chemistry - Haloalkanes Haloarenes - Quiz-7

2-Bromopentane reacts with alcoholic KOH to give-

0%

Cis-2-Pentene
0%

Trans-2-Pentene
0%

1-Pentene
0%

None of the above

Isopropyl chloride undergoes hydrolysis by -

0%

$S_{N} 1$ and $S_{N} 2$ mechanisms
0%

Neither $S_{N} 1$ nor $S_{N} 2$ mechanisms
0%

3, $S_{N} 1$ mechanism only
0%

$S_{N} 2$ mechanism only

Chloroform is slowly oxidized by air in the presence of light and air to form

0%

Phosgene
0%

Formyl chloride
0%

fFormaldehyde
0%

Trichloroethanol

Isobutyl bromide may be obtained from isobutylene and HBr in the presence of

0%

Hydroquinone
0%

Diphenylamine
0%

Peroxide
0%

All of the above

The reaction of 4-bromobenzyl chloride with NaCN in ethanol leads to-

0%

4-Bromo-2-cyanobenzyl chloride
0%

4-Cyanobenzyl cyanide
0%

4-Cyanobenzyl chloride
0%

4-Bromobenzyl cyanide

Propene upon heating with ${Cl}_{2}$ at 500^oC forms -

0%

${CH}_{3} - CHCl - {CH}_{2} Cl$
0%

${CH}_{2} Cl - CH = {CH}_{2}$
0%

${CH}_{2} Cl - CHCl - {CH}_{2} Cl$
0%

All of the above

2-Bromopentane is heated with KOH in ethanol. The major product obtained is-

0%

2-Ethoxypentane
0%

1-Pentane
0%

cis-2-Pentane
0%

trans-2-Pentene

Ethyl bromide reacts with lead-sodium alloy to form

0%

tetramethyl bromide
0%

tetraethyl lead
0%

both (1.) and (2.)
0%

none of these

Butanenitrile is formed by the reaction of KCN with -

0%

Butyl chloride
0%

Propyl chloride
0%

Butyl alcohol
0%

Propyl alcohol

A molecule among the following having the highest melting point is -

0%

Chlorobenzene
0%

o-Dichlorobenzene
0%

m-Dichlorobenzene
0%

p-Dichlorobenzene

Toluene refluxed with ${Br}_{2}$ in the presence of light generate mainly -

0%

p-Bromotoluene
0%

Benzyl bromide
0%

o-Bromotoluene
0%

Mixture of o- and p-bromotoluene

Chloroform when reacts with nitric acid, gives

0%

$C_{2} H_{5} C {(NO)}_{5} SH$
0%

$(C H$ ₃)2CHOH
0%

${CCl}_{3} {NO}_{2}$
0%

${CCl}_{3} {NO}_{3}$

On sulphonation of $C_{6} H_{5} Cl$ , the product obtained is-

0%

m-Chlorobenzene sulphonic acid is formed
0%

Benzene sulphonic acid is formed
0%

o-Chlorobenzene sulphonic acid is formed
0%

o-and p-Chlorobenzene sulphonic acid is formed

Toluene on reaction with N-Bromosuccinimide gives

0%

Phenyl bromomethane
0%

o-Bromomethyl benzene
0%

p-Bromomethyl benzene
0%

m-Bromomethyl benzene

The IUPAC name of p-ClC₆H₄CH₂CH(CH₃)₂ is -

0%

1−Chloro−4−(2−methylpropyl) benzene
0%

4−Chloro−1−(2−methylpropyl) benzene
0%

1−Chloro−4−(3−methylpropyl) benzene
0%

4−Chloro−4−(3−methylpropyl) benzene

The IUPAC name of CH₃C(p-ClC₆H₄)₂CH(Br)CH₃ is -

0%

2−Bromo−3,3−bis(4−chlorophenyl) butane
0%

4−Bromo−3,3−bis(2−chlorophenyl) butane
0%

2−Bromo−1,1−bis(4−chlorophenyl) butane
0%

4−Bromo−1,1−bis(2−chlorophenyl) butane

The correct IUPAC name of the above-mentioned compound is -

0%

1−Chloro−4−(1−iodophenyl)−3, 3−dimethylbut−1−ene
0%

1−Chloro−1−(4−iodophenyl)−3, 3−dimethylbut−1−ene
0%

1−Chloro−2−(3−iodophenyl)−3, 3−dimethylbut−1−ene
0%

4−Chloro−1−(1−iodophenyl)−1, 1−dimethylbut−3−ene

The number of structural isomers possible for the compound with the formula C₄H₉Br, is-

0%

5
0%

6
0%

4
0%

2

n-BuBr + KCN $\overset{E t O H - H_{2} O}{\to}$ nBuCN

Above reaction is an example of -

0%

Addition reaction
0%

$S_{N} 1$
0%

Elimination reaction
0%

$S_{N} 2$

Match the compounds given in Column I with the effect given in Column II.

Column l	Column lI
A. Chloramphenical	1. Malaria
B. Thyroxine	2. Anaesthetic
C. Chloroquine	3. Typhoid fever
D. Chloroform	4. Goiter
	5. Blood substituent

Codes

A B C D

0%

2 3 4 1
0%

3 4 1 2
0%

5 4 3 2
0%

4 5 3 2

Match the items of Column I and Column II

Column l	Column ll
A. $S_{N} 1$ reaction	1. vic-dibromide
B. Elimination of HX from an alkyl halide	2. Chlorobromocarbons
C. Bromination of alkenes	3. Racemisation
D. Chemicals in fire extinguisher	4. Saytzeff rule

Codes

A B C D

0%

2 3 4 1
0%

3 4 1 2
0%

1 4 3 2
0%

4 1 3 2

Match the structures of compounds given in Column I with the classes of compounds given in Column II.

Column l	Column ll
A.	1. Aryl halide
B. $C H_{2} = C H — C H_{2} — X$	2. Alkyl halide
C.	3. Vinyl halide
D. $C H_{2} = C H — X$	4. Allylic halide

Codes

A B C D

0%

2 4 1 3
0%

3 4 1 2
0%

1 4 3 2
0%

4 1 3 2

Match the reactions given in Column I with the types of reactions given in column II

COLUMN I

COLUMN II

1. Nucleophilic
aromatic
substitution
reaction

2. Electrophilic
aromatic
substitution

3. Saytzeff
elimination

4. Electropillic
addition

5. Nucleophilic
substitution
reaction

Codes

A B C D

0%

2 4 5 1
0%

3 1 5 2
0%

5 4 3 2
0%

4 5 3 2

Match the reactions given in Column I with the names given in Column

COLUMN I

D. C₂H₅Cl + NaI $\overset{dry acetone}{\to}$ C₂H₅I + NaCl

COLUMN II

1. Fittig reaction

2. wurtz-Fittig reaction

3. Finkelstein reaction

4. Sandmeyer reaction

Codes

A B C D

0%

2 1 4 3
0%

3 1 5 2
0%

5 4 3 2
0%

4 5 3 2

Assertion: Phosphorus chlorides (tri and Penta) are preferred over thionyl chloride for the preparation of alkyl chlorides from alcohols.

Reason: Phosphorus chlorides give pure alkyl halides.

0%

Both assertion and reason are true and the reason is the correct explanation of assertion.
0%

Both assertion and reason are true and the reason is not the correct explanation of assertion.
0%

Assertion is true but the reason is false.
0%

Assertion and reason both are false.

Assertion: The boiling points of alkyl halides decrease in the order RI> RBr > RCl > RF

Reason: The boiling points of alkyl chlorides, bromides, and iodide are considerably higher than that of the hydrocarbon of comparable molecular mass.

0%

Both assertion and reason are true and the reason is the correct explanation of assertion.
0%

Both assertion and reason are true and the reason is not the correct explanation of assertion.
0%

Assertion is true but the reason is false.
0%

Assertion is false but the reason is true.

Assertion: KCN reacts with methyl chloride to give methyl isocyanide

Reason: CN^- is an ambident nucleophile.

0%

Both assertion and reason are true and the reason is the correct explanation of assertion.
0%

Both assertion and reason are true and the reason is not the correct explanation of assertion.
0%

Assertion is true but the reason is false.
0%

Assertion is false but the reason is true.

Assertion: The presence of a nitro group at ortho or para position increases the reactivity of haloarenes towards nucleophilic substitution.

Reason: Nitro group, being an electron-withdrawing group decreases the electron density over the benzene ring.

0%

Both assertion and reason are true and the reason is the correct explanation of assertion.
0%

Both assertion and reason are true and the reason is not the correct explanation of assertion.
0%

Assertion is true but the reason is false.
0%

Assertion is false but the reason is true.

Assertion: It is difficult to replace chlorine with -OH in chlorobenzene in comparison to that in chloroethane.

Reason: Chlorine carbon (—Cl) bond in chlorobenzene has a partial double bond character due to resonance

0%

Both assertion and reason are true and the reason is the correct explanation of assertion.
0%

Both assertion and reason are true and the reason is not the correct explanation of assertion.
0%

Assertion is true but the reason is false.
0%

Assertion is false but the reason is true.

Sulphuric acid is not used during the reaction of alcohols with KI and acts as-

0%

Reducing agent
0%

Electron donor
0%

Electron acceptor
0%

Oxidising agent

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Practice Chemistry Quiz Questions and Answers

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Practice Chemistry Quiz Questions and Answers

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