Which of the following reagents will be able to distinguish between 1-butyne and 2-butyne?
NaNH2
HCl
O2
Br2
+(CH3)3COH→ X
The product X in the above reaction is -
The products formed when meta-xylene is treated with Br2 in the presence of FeBr3 are:-
A compound that is formed on passing chlorine through propene at 400°C is -
PVC
Allyl chloride
Nickel chloride
1,2-Dichloro ethane
The reactants used in Friedel-Craft's alkylation are -
C6H6 + NH2
C6H6 + CH4
C6H6 + CH3Cl
C6H6 + CH3COCl
→KOHKMnO4B→FeCl3Br2C→H+C2H5OHD
The D in the above mentioned reaction is -
Nitrobenzene on reaction with conc. HNO3/H2SO4 at 80-100°C forms -
1,2-Dinitrobenzene
1,3-Dinitrobenzene
1,4-Dinitrobenzene
1,2,4-Trinitrobenzene
In the following reaction,
Product A is-
The monochlorinated products (excluding stereo-isomers) obtained from the reaction is:
4
5
6
7
3-Hexyne can be converted to trans-3-Hexene by the action of:
H2 - Pd/ BaSO4
Li-Liq. NH3
H2 - Pt O2
NaBH4
A compound having the shortest carbon-carbon bond length among the following is -
Benzene
Ethene
Ethyne
Ethane
Reaction of HBr with propene in the presence of peroxide gives
iso-propyl bromide
3-bromo propane
allyl bromide
n-propyl bromide
The reaction of toluene with Cl2 in the presence of FeCl3 gives 'X' and reaction in presence of light gives 'Y'. Thus, 'X' and 'Y' are
X = benzal chloride, Y= o-chlorotoluene
X = m-chlorotoluene, Y= p-chlorotoluene
X = o and p-chlorotoluene, Y = trichloromethyl benzene
X = benzal chloride, Y = m-chlorotoluene
When acetylene is passed through dil. H2SO4 in presence of HgSO4, the compound formed is
ether
ketone
acetic acid
acetaldehyde
Acetylenic hydrogens are acidic because
sigma electron density of C-H bond in acetylene is nearer to carbon which has 50% s-character
acetylene has only one hydrogen on each carbon
acetylene contains least number of hydrogens among the possible hydrocarbons having two carbons
acetylene belong to the class of alkynes with molecular formula CnH2n-2
A compound is treated with NaNH2 to give sodium salt. Identify the compound.
C2H2
C6H6
C2H6
C2H4
Ethylene forms ethylene chlorohydrin by the action of:
dry chlorine gas
dry hydrogen chlorine gas
solution of chlorine gas in water
dilute hydrochloric acid
Which alkene on ozonolysis gives CH3CH2CHO and CH3CCH3 || O ?
CH3CH2CH=CHCH2CH3
CH3CH2CH=CHCH3
Hydroxylation of propyne in the presence of HgSO4/H2SO4 is initiated by the attack of:
carbene
free radical
electrophile
nucleophile
Ozonolysis of buta-1,3-diene gives:
HCHO and glyoxal
CH3CHO and glyoxal
CO2 and glyoxal
HCHO + glyoxal + CH3CHO
A mixture of ethane, ethene and ethyne is passed through an ammoniacal AgNO3 solution. The gases that remain unreacted are-
Ethane and Ethene
Ethane and Ethyne
Ethene and Ethyne
Ethane only
The most suitable reagent among the following that is used to distinguish compound (III) from the rest of the compounds is -
I. CH3-C≡C-CH3
II. CH3-CH2-CH2-CH3
III. CH3-CH2-C≡CH
IV. CH3-CH=CH2
Br2/CCl4
Br2/CH3COOH
Alk.KMnO4
Ammoniacal AgNO3
Alkene-1 on hydroboration followed with action of H2O2 gives:
alkanol-2
alkanol-1
alkanal
alkanone
Which of the following is a correct statement regarding the relative acidic character of cyclopropane and propane?
Cyclopropane is more acidic than propane
Propane is more acidic than cyclopropane
Both are equally acidic
Bothe are neutral
The reaction,
C6H6 + CH3Cl→AlCl3AnhydrousC6H5CH3 + HCl
is an example of:
Friedel-Crafts reaction
Kolbe's synthesis
Wurtz's reaction
Grignard synthesis
Ozonolysis of will give:
+
OC-CH2-CH3-CH3-CO | |CH2— CH2 — CH2
none of the above
2-Methylpropene and But-1-ene can be distinguished by -
Baeyer's reagent
Br2 solution
O3, Zn/H2O
An octane number 100 is given to:
n-hexane
Iso-octane
neo-pentane
neo-octane
Which of the following molecules/species are aromatic in character?
A B C D
B
C
D
A
Xylene on oxidation with acidic KMnO4 gives:
Phthalic acid
Isophthalic acid
Terephthalic acid
All of the above
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