If a compound of molecular formula C7H16 shows optical isomerism, the compound will be-

  •   2,3-Dimethyl pentane

  •   2,2-Dimethyl butane

  •   2-Methyl hexane

  •   None of the above

The compound  on reaction with NaIO4 in the presence of KMnO4 given :

  • CH3COCH3

  • CH3COCH3 + CH3COOH

  • CH3COCH3 + CH3CHO

  • CH3CHO + CO2

Among the following the free-radical substitution reaction is-

  •  

  •  

  •  

  •  CH3CHO+HCNCH3CH(OH)CN

 An alkene ‘A’ on ozonolysis gives a mixture of ethanal and pentan-3-one. The IUPAC name of   ‘A’ is -

  • 3-Ethylpent-2-ene

  • 3-Ethylpent-2- yne

  • 2-Ethylpent-3-ene

  • 3-Ethylpent-4-yne

An alkene ‘A’ contains 3 C – Cσ bonds, 8 C – H σ bonds, and 1 C – C π bond,

 ‘A’ on ozonolysis gives two moles of an aldehyde of molar mass 44 u. The IUPAC name of ‘A’ is -

  • Prop-2-yne

  • But-2-ene

  • But-2-yne

  • Prop-2-ene

Propanal and pentane-3-one are the products of ozonolysis of an alkene. The structural formula of the alkene is  

 

 

 

 

  •     

  •    , 

  •  

  •    

Benzene is extraordinarily stable, though it contains three double bonds, because of -

  • Delocalized protons

  • Delocalized neutrons

  • Resonance

  • None of these

Out of benzene, m–dinitrobenzene and toluene, the one that will undergo nitration most easily is -

  • Benzene

  •  m–Dinitrobenzene

  • Toluene

  • None of these

Lewis acid that can be used during ethylation of benzene is -

  •  FeCl3

  • SnCl4 

  •  BF3

  • All of the above

The IUPAC names of the following compounds are?

(a) CH3CH=C(CH3)2

(b) CH2=CH-CC-CH3

 

(c)

(d)

(e)

 

(g) CH3 – CH = CH – CH2 – CH = CH – CH – CH2 – CH = CH2

                                                                  |

                                                             C2H5

 

  •   2-Methylbut-2-ene, Pen-1-ene-3-yne, 1, 3-Butadiene, 4-Phenyl but-1-ene , 2-Methyl phenol, 5-(2-Methylpropyl)-decane and 4-Ethyldeca-1, 5, 8-triene

  • 4-Phenyl but-1-ene, Pen-1-ene-3-yne, 1, 3-Butadiene, 2-Methylbut-2-ene, Pen-1-ene-3-yne, 2-Methyl phenol, 5-(2-Methylpropyl)-decane and 4-Ethyldeca-1, 5, 8-triene

  •  2-Methylbut-2-ene, 4-Phenyl but-1-ene, 1, 3-Butadiene, Pen-1-ene-3-yne, 2-Methyl phenol, 5-(2-Methylpropyl)-decane and 4-Ethyldeca-1, 5, 8-triene

  • 4-Ethyldeca-1, 5, 8-triene, Pen-1-ene-3-yne, 1, 3-Butadiene, 4-Phenyl but-1-ene, 2-Methyl phenol, 5-(2-Methylpropyl)-decane and 2-Methylbut-2-ene

The numbers of isomers of C4H8 (one double bond) and C5H8 (one triple bond) are -

4. C4H8 = 4 ; C5H8 = 3

    

  • C4H8 = 3 ; C5H8 = 3

  • C4H8 = 4 ; C5H8 = 4

  • C4H8 = 3 ; C5H8 = 4

  • 4

The balanced chemical equation for the combustion reaction of Butane is 

  • 1.  2C4H10(g) + 13O2(g)     8CO2(g) + 10H2O + Heat    Butane

  • 2. 2C4H10(g) + 13O2(g)     9CO2(g) + 10H2O + Heat    Butane

  • 3. 2C4H10(g) + 14O2(g)     8CO(g) + 10H2O + Heat    Butane

  • 4. C4H10(g) + 13O2(g)     8CO(g) + 10H2O + Heat    Butane

The dihedral angle of the least stable conformer of ethane is-

  • 60°

  • 0°

  • 120°

  • 180°

The major product of the following chemical reaction is:

  •  
  •  
  •  
  •  

Reactant A in the following reaction is-

A  + NaOH \(\xrightarrow[\Delta ]{CaO}\) CH3CH2CH3 + Na2CO3

  • Sodium ethanoate

  • Sodium propanoate

  • Sodium butanoate

  • Sodium methanoate

The IUPAC name of the given compound is-

  • cis-2,3-Diethylbut-2-ene
  • trans-2,3-Diethylbut-2-ene
  • cis-3,4-Dimethylhex-3-ene
  • trans-3,4-Dimethylhex-3-ene
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