→(ii) CH3Br(i) NaNH2.NH2 (A) →Lindiar catalystH2 (B) ; Product (B) is :
A compound that gives an optically inactive compound on treatment with H2(2 moles)/ Pt is-
3-Methyl-1-pentyne
4-Methyl-1-hexyne
3-Methyl-1-heptyne
None of the above
Compound (x) will be:
()
Which alkyne yields butanoic acid (CH3CH2CH2CO2H) as the only organic product on treatment with ozone followed by the hydrolysis?
1-Butyne
4-Octyne
1-Pentyne
2-Hexyne
The degree of unsaturation in compound (A) is -
7
8
9
10
Correct order of rate of EASR (electrophilic aromatic substitution) is :
c > b > a > d
c > d > a > b
a > b > c > d
c> d> b > a
The compound that will react most readily with gaseous bromine has the formula-
C3H6
C2H2
C4H10
C2H4
Rank the following reactions A,B and C in order of increasing rate,(A)(B)
(C)
Identify the position where E.A.S. can take place.
The rate of nitration will be:
() a>b>c
() a>c>b
() a=b=c
() c>a>b
+ HO- → (A); Product (A) of the given reaction is:
(2 mole) (4 mole) (major)
Which of the following compounds is the slowest to react with nitrosonium ion (NO+)?
The final product in the above sequence of reactions is-
→AlCl3
What is the major product of the above Friedel-Craft reaction?
The strongest acid among the following is -
Product (C) is:-
The reaction of toluene with chlorine in the presence of light gives:
Product (B) in the above mentioned reaction is-
Product (A) in the above mentioned reaction is-
No reaction
,vant't-Hoff factor (i) for the reaction is:-
3
4
5
2
A non-aromatic compound among the following compounds is-
A compound among the following that gives maximum % of meta product on nitration
(using HNO3/H2SO4) is -
Toluene
Aniline
Benzene
Isopropyl benzene
The action of AlCl3 in Friedel Craft's reaction is:
To absorb HCl
To release HCl
To produce an eleçtrophile
To produce nucleophile
n-Butylbenzene on oxidation with hot alkaline KMnO4 gives:-
Benzoic acid
Butanoic acid
Benzyl alcohol
Benzaldehyde
The compound among the following that undergoes bromination of its aromatic ring
(electrophilic aromatic substitution) at the fastest rate is-
Consider the following sequence of reactions.
C6H6 + CH3CH=CH2→heatH3PO4A→2.H3O+, heat1.O2,HeatB+C
The products (B) and (C) are respectively-
Benzaldehyde, and acetaldehyde
Benzoic acid, and acetic acid
Phenol, and propionaldehyde
Phenol, and acetone
→NaHSO3OsO4A→2. NaOH, heat1. HIO4B. The final product (B) is:
In the above compound, Cl will liberate easily in the form of-
Cl⊕
Cl-
Cl
Cl2+
The major product expected from the mono-bromination of phenyl benzoate is:
(A) C8H10 →KMnO4 (B) C8H6O4→FeBr2 C8H5BrO4 (C) (one-product only)
The structure of A in the above-mentioned reaction is-
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