(ii) CH3Br(i) NaNH2.NH2 (A) Lindiar catalystH2 (B) ; Product (B) is :

  •  

A compound that gives an optically inactive compound on treatment with H2(2 moles)/ Pt is-

  • 3-Methyl-1-pentyne

  • 4-Methyl-1-hexyne

  • 3-Methyl-1-heptyne

  • None of the above

Compound (x) will be:

  • () 

  • () 

  • () 

  • () 

Which alkyne yields butanoic acid (CH3CH2CH2CO2H) as the only organic product on treatment with ozone followed by the hydrolysis?

  • 1-Butyne             

  • 4-Octyne               

  • 1-Pentyne               

  • 2-Hexyne

 

The degree of unsaturation in compound (A) is -

 

  • 7                       

  • 8                       

  • 9                             

  • 10

Correct order of rate of EASR (electrophilic aromatic substitution) is : 

  • c > b > a > d

  • c > d > a > b

  • a > b > c > d

  • c> d> b > a

The compound that will react most readily with gaseous bromine has the formula-

  •   C3H6

  •   C2H2

  •   C4H10

  •   C2H4

Rank the following reactions A,B and C in order of increasing rate,
(A)
(B)


(C)

  • ()B>A>C
  • ()B>C>A
  • ()A>B>C
  • ()A>C>B

     

Identify the position where E.A.S. can take place.

  • () 1
  • () 2
  • () 3
  • () 4

 

The rate of nitration will be:

 

  • () a>b>c

  • () a>c>b

  • () a=b=c

  • () c>a>b

 + HO-  (A);      Product (A) of the given reaction is:  

      (2 mole)       (4 mole)   (major)

  • 1
  • 2
  • 3
  • 4

Which of the following compounds is the slowest to react with nitrosonium ion (NO+)?

  •  

  •  

  •  

  •  

     

The final product in the above sequence of reactions is-

  •     

  •   
  •  
  •  

 AlCl3

What is the major product of the above Friedel-Craft reaction?

  • 1
  • 2
  • 3
  • 4

 The strongest acid among the following is -

  •  

  •  

  •  

  •  

 


Product (C) is:-

  •  

  •  

  •  

  •  

The reaction of toluene with chlorine in the presence of light gives:

  •  

  •        

  •  

  •  

 

Product (B) in the above mentioned reaction is-

  •  

  •  

  •  

  •  

 Product (A) in the above mentioned reaction is-

  •  

  • No reaction

  •  

  •  

,vant't-Hoff factor (i) for the reaction is:-

  • 3

  • 4

  • 5

  • 2

A non-aromatic compound among the following compounds is-

  •  

  •  

  •  

  •  

A compound among the following that gives maximum % of meta product on nitration

(using HNO3/H2SO4) is -

  • Toluene

  • Aniline

  • Benzene

  • Isopropyl benzene

The action of AlCl3 in Friedel Craft's reaction is:

 

  • To absorb HCl

  • To release HCl

  • To produce an eleçtrophile

  • To produce nucleophile

n-Butylbenzene on oxidation with hot alkaline KMnO4 gives:-

 

  • Benzoic acid

  • Butanoic acid

  • Benzyl alcohol

  • Benzaldehyde

The compound among the following that undergoes bromination of its aromatic ring

(electrophilic aromatic substitution) at the fastest rate is-

 

 

  •    

  •  

  •   

  •  

Consider the following sequence of reactions.

C6H6 + CH3CH=CH2heatH3PO4A2.H3O+, heat1.O2,HeatB+C

The products (B) and (C) are respectively-

  • Benzaldehyde, and acetaldehyde

  • Benzoic acid, and acetic acid

  • Phenol, and propionaldehyde

  • Phenol, and acetone

Consider the following sequence of reactions.

NaHSO3OsO4A2. NaOH, heat1. HIO4B. The final product (B) is:

  •  

  •  

  •  

  •  

In the above compound, Cl will liberate easily in the form of-

  •  Cl

  • Cl-

  • Cl

  • Cl2+

The major product expected from the  mono-bromination of phenyl  benzoate is:

  • () 

  • () 

  • () 

  • () 

(A) C8H10 KMnO4 (B)  C8H6O4FeBr2  C8H5BrO4  (C)  (one-product only)

The structure of A in the above-mentioned reaction is-

 

  •  

  •  

  •  

  •   

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