Ph-CO2HSOCl2AMe2NHB(c)Ph-CHO, unknown reagent (c) is:

  • LiALH4

  • NaBH4

  • LiAlH4(t-BuO)3

  • PCC/CH2CL2

Hydrocarbon (A) reacts with bromine by substitution reaction to form an alkyl bromide B. B undergoes the Wurtz reaction to give a gaseous hydrocarbon containing less than four carbon atoms.
The formula of (A) is-
 
 
 

 

  •  CHCH
  •  CH2=CH2
  •  CH3-CH3
  •  CH4

AlCl3CH3-C||O-ClA80%triethylene glycol, heatNH2-NH2, NaOHB73%

The product (B) in the above mentioned reaction is -

 

 

  •  

  •  

  •  

  •  

Cl2 (A), Product (A) of this reaction is:

  • () 

  • () 

  • () 

  • () 

; Product (B) of this reaction is :

  • 1
  • 2
  • 3
  • 4

Cyclopentadiene is much more acidic than cyclopentane, beacuse -

  • Cyclopentadiene has conjugated double bonds.

  • Cyclopentadiene has both sp2 and sp3 hybridized carbon atoms.

  • Cyclopentadiene is a strain-free cyclic system.

  • Cyclopentadienyl anion ion, the conjugate base of cyclopentadiene, is an aromatic species and hence has higher stability.

 The compounds among the following that can be generated by Friedel craft acylation is/are -

I.

II.
III.

IV.

  • II, III and IV

  • I, III and IV
  • I and II
  • II and III

     
The product B in the above mentioned reaction is -



  •   

  •  
  •  

The major product obtained in the given reaction is-

  


  •  

  •  

  •  

  •  

The deactivating but ortho-para directing benzene ring substituent among the following is-

  • -N=O

  • -OCH3

  • -COCH3

  • -NO2

Which of the following organic chlorides will not give a Friedel-Craft alkylation product when heated with benzene and AlCl3/FeCl3 ?

 

 

 

  •  1. ( C H3)3CCl

  •   CH2=CHCH2Cl

  •  CH3CH2Cl

  •   CH2=CHCl

Which of the following is aromatic?

  •  

  •  (Carbene)

  •  

  •  (Carbene)                    

Which of the following substance will increase the acidity of phenol?

  • Dil. H2SO4       

  • Dil. HCl           

  • Conc. H2SO4           

  • Conc. CH3COOH

The compound X in the above reaction is-

  •   

  •  

  •           

  •  

Give a simple test to differentiate cyclohexane and cyclohexene :

 

  • Br2/H20

  • Baeyer's reagent

  • Tollen's reagent

  • Both (1) and (2)

Partial oxidation of methane with Ni/Al2O3 catalyst gives:

  • HCHO

  • HCOOH

  • H2O and CO2

  • CO and H2O

Predict the correct intermediate and product in the following reaction.

H3C-CCH HgSO4H2O, H2SO4 Intermediate Product

                                                    (A)                   (B)

  • 1
  • 2
  • 3
  • 4

An alkene reacts in accordance with the Markownikoff's rule,

to give a product 1-chloro-l-methylcyclohexane with HCl. The possible alkene is -

  •  

  •  

  • 1 and 2

2, 3-dimethyl-2-butene can be prepared by heating which of the following compounds

with a strong acid?

  •  

  • (CH3)3C-CH=CH2

  • (CH3)2C=CH-CH2-CH3

  • (CH3)2CH-CH2-CH=CH2

The oxidation of benzene by V2O5 in the presence of air produces-

  • Benzoic anhydride           

  •   Maleic anhydride

  • Benzoic acid                     

  • Benzaldehyde

What products are formed when the following compound is treated with Br2 in the

presence of FeBr3?

  •  

  •  

  •  

  •  

Identity Z in the sequence of reactions,
                          HBr/H2O2 
CH3CH2CH=CH2    →        Y    +   C2H5O-Na+→   Z
 

  • CH3-(CH2)3-O-CH2CH3
  • (CH3)2CH2-O-CH2CH3

  • CH3(CH2)4-O-CH3

  • CH3CH2-CH(CH3)-O-CH2CH3                  

Which of the following organic compounds has same hybridisation as its combustion product -(CO2)?

  • Ethane

  • Ethyne

  • Ethene

  • Ethanol

A compound among the following that does not undergo Friedel-Craft's reaction easily is-

  • Cumene               

  •   Xylene

  • Nitrobenzene         

  • Toluene

In the following reaction, What will be the major product?

  •  

  •   

  •  

  •  

In the following reactions:-

the major products (A) and (C) are respectively

  • 1
  • 2
  • 3
  • 4

Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by:-

  • oxidation

  • cracking

  • distillation under reduced pressure

  • hydrolysis

Nitrobenzene can be prepared from benzene by using a mixture of conc. HNO3 and conc.

H2SO4. In the mixture, nitric acid acts as a/an-

  • Reducing agent

  • Acid

  • Base

  • Catalyst

Benzene reacts with CH3Cl in the presence of anhydrous AlCl3 to form-

  • Toluene

  • Chlorobenzene

  • Benzylchloride

  • Xylene

H3C-C|H-CH=CH2 + HBr A             CH3

A (Predominantly) is

  •  CH3-C|CH3H-CH2-CH2Br

  •  CH3-C|CH3Br|-CH2CH3

  •  CH3-C|BrH-C|CH3H-CH3

  •  CH3-C|CH3H-C|BrH-CH3

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