Ph-CO2H→SOCl2A→Me2NHB→(c)Ph-CHO, unknown reagent (c) is:
LiALH4
NaBH4
LiAlH4(t-BuO)3
PCC/CH2CL2
→AlCl3CH3-C||O-ClA80%→triethylene glycol, heatNH2-NH2, NaOHB73%
The product (B) in the above mentioned reaction is -
→Cl2 (A), Product (A) of this reaction is:
()
; Product (B) of this reaction is :
Cyclopentadiene is much more acidic than cyclopentane, beacuse -
Cyclopentadiene has conjugated double bonds.
Cyclopentadiene has both sp2 and sp3 hybridized carbon atoms.
Cyclopentadiene is a strain-free cyclic system.
Cyclopentadienyl anion ion, the conjugate base of cyclopentadiene, is an aromatic species and hence has higher stability.
The compounds among the following that can be generated by Friedel craft acylation is/are -
I.
II.III.
IV.
II, III and IV
The product B in the above mentioned reaction is -
The major product obtained in the given reaction is-
The deactivating but ortho-para directing benzene ring substituent among the following is-
-N=O
-OCH3
-COCH3
-NO2
Which of the following organic chlorides will not give a Friedel-Craft alkylation product when heated with benzene and AlCl3/FeCl3 ?
1. ( C H3)3CCl
CH2=CHCH2Cl
CH3CH2Cl
CH2=CHCl
Which of the following is aromatic?
(Carbene)
Which of the following substance will increase the acidity of phenol?
Dil. H2SO4
Dil. HCl
Conc. H2SO4
Conc. CH3COOH
The compound X in the above reaction is-
Give a simple test to differentiate cyclohexane and cyclohexene :
Baeyer's reagent
Tollen's reagent
Both (1) and (2)
Partial oxidation of methane with Ni/Al2O3 catalyst gives:
HCHO
HCOOH
H2O and CO2
CO and H2O
Predict the correct intermediate and product in the following reaction.
H3C-C≡CH →HgSO4H2O, H2SO4 Intermediate →Product
(A) (B)
An alkene reacts in accordance with the Markownikoff's rule,
to give a product 1-chloro-l-methylcyclohexane with HCl. The possible alkene is -
1 and 2
2, 3-dimethyl-2-butene can be prepared by heating which of the following compounds
with a strong acid?
(CH3)3C-CH=CH2
(CH3)2C=CH-CH2-CH3
(CH3)2CH-CH2-CH=CH2
The oxidation of benzene by V2O5 in the presence of air produces-
Benzoic anhydride
Maleic anhydride
Benzoic acid
Benzaldehyde
What products are formed when the following compound is treated with Br2 in the
presence of FeBr3?
Identity Z in the sequence of reactions, HBr/H2O2 CH3CH2CH=CH2 → Y + C2H5O-Na+→ Z
(CH3)2CH2-O-CH2CH3
CH3(CH2)4-O-CH3
CH3CH2-CH(CH3)-O-CH2CH3
Which of the following organic compounds has same hybridisation as its combustion product -(CO2)?
Ethane
Ethyne
Ethene
Ethanol
A compound among the following that does not undergo Friedel-Craft's reaction easily is-
Cumene
Xylene
Nitrobenzene
Toluene
In the following reaction, What will be the major product?
In the following reactions:-
the major products (A) and (C) are respectively
Liquid hydrocarbons can be converted to a mixture of gaseous hydrocarbons by:-
oxidation
cracking
distillation under reduced pressure
hydrolysis
Nitrobenzene can be prepared from benzene by using a mixture of conc. HNO3 and conc.
H2SO4. In the mixture, nitric acid acts as a/an-
Reducing agent
Acid
Base
Catalyst
Benzene reacts with CH3Cl in the presence of anhydrous AlCl3 to form-
Chlorobenzene
Benzylchloride
H3C-C|H-CH=CH2 + HBr →A CH3
A (Predominantly) is
CH3-C|CH3H-CH2-CH2Br
CH3-C|CH3Br|-CH2CH3
CH3-C|BrH-C|CH3H-CH3
CH3-C|CH3H-C|BrH-CH3
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