Incorrect statement regarding structure of H2O and H2O2 is:

  •  In gaseous phase, water molecule has a bent form.

  • Bond angle of water is 109.0°

  •  Hydrogen peroxide has a non-planar structure.

  •  The dihedral angle of H2Oin gas phase is 111.5° 

The reaction that is not an example of a hydrolysis reaction is-

  •  PbS(s) +H2O2(aq) PbSO4(s) + H2O(l)

  •  CaO(s) + H2O(g)  Ca(OH)2 (aq)

  •  AlCl3(g) + 3H2O(l) Al2O3(s) + 6HCl(aq)

  •  Ca3N2(s) + 6H2O(l) 3Ca(OH)2(aq) + 2NH3(g)

Structures of  and 

  • 2

The correct order of increasing electrical conductance is -

  • BeH2 > CaH2 > TiH2
  • BeH2 < CaH2 > TiH2
  • TiH2 < BeH2 < CaH2
  • BeH2 < CaH2 < TiH2

The correct order of increasing reducing nature is -

  • NaH > H2O < MgH2

  • H2O > MgH2> NaH

  • H2O< MgH2 < NaH

  • H2O  MgH2 < NaH

H+ ions always get associated with other atoms or molecules due to -

  •   Ionisation enthalpy of hydrogen resembles that of alkali metals

  •   Its reactivity is similar to halogens

  •   It resembles both alkali metals and halogens

  •   Loss of an electron from hydrogen atom results in a nucleus of very small size as compared to other atoms or ions. Due to small size it cannot exist free

Some statements about water are given below:

(a) Heavy water is used as a moderator in nuclear reactors.
(b) Heavy water is more associated than ordinary water.
(c) Heavy water is a more effective solvent than ordinary water.

Which of the above statements are correct?

  • (a), (b) and (c)

  • (b) and (c)

  • (a) and (c)

  • (a) and (b)

The pair that on reaction will not evolve H2 gas is : 

  •   Copper and HCl (aqueous)
  •   Iron and steam
  •   Iron and H2SO4 (aqueous)
  •   Sodium and ethyl alcohol

 H2Oon oxidation gives :

  •  O-2

  •  OH-

  •  O2-

  •  O2

Pure water can be obtain from sea water by :

  •   Centrifugation
  •   Plasmolysis
  •   Reverse osmosis
  •   Sedimentation

The isotopes of hydrogen and their mass ratio are -

  • Protium, Deuterium, Tritium ; 3:2:3

  • Protium, Deuterium, Tritium ; 1:2:3

  • Protium, Deuterium, Tritium ; 2:2:3

  • Protium, Deuterium, Tritium ; 3:2:1

Hydrogen exists in diatomic form rather than monoatomic form under normal conditions -

  • Due to high ionization enthalpy

  • Due to low ionization enthalpy

  • Due to high electron gain enthalpy

  • Due to low electron gain enthalpy

The role of an electrolyte in the  preparation of H2 by electrolytic method is-

  • It cools down the temperature.

  • None of the above

  • It lowers the availability of ions available in the process for the conduction of electricity.

  • It makes the ions available in the process for conduction of electricity.

The products obtained on the completion of the following reactions respectively are -

i. C3H8(g)+3H2O(g)catalystii. Zn(s) + NaOH(aq)heat

1. i=CO, and H2 ; ii =Na2ZnO22. i = CO2 ; ii = Na4ZnO43. i = CH3CH2CH2OH ; ii = ZnO4. None of the above

  • 1
  • 2
  • 3
  • 4

The consequences of high enthalpy of H–H bond in dihydrogen is /are -

  • Hydrogen has a low tendency to form H+ions.

  • It forms diatomic molecules (H2), and a large number of covalent hydrides.

  • Hydrogen does not possess metallic characteristics.

  • All of the above.

The correct statement about electron-deficient hydride is that it-

  • Does not have sufficient electrons to form a regular bond.
  • Cannot be represented by conventional Lewis structures.
  • Accept electrons.
  • All of the above.

The hydrides of carbon (CnH2n + 2) can act as -

  • Lewis acid.

  • Lewis base.

  • Both 1 and 2

  • None of the above

“Non-stoichiometric hydrides” are -

  • Hydrogen-deficient compounds formed by the reaction of a hydrogen atom with d-block and f-block elements.

  • Hydrogen-deficient compounds formed by the reaction of dihydrogen with d-block and f-block elements.

  • Electron-deficient compounds formed by the reaction of dihydrogen with d-block and f-block elements.

  • Hydrogen-deficient compounds formed by the reaction of dihydrogen with s-block and p-block elements.

Metallic hydrides are useful for hydrogen storage because : 

  • Metallic hydrides are oxygen-rich.

  • Metallic hydrides are oxygen-deficient.

  • Metallic hydrides are hydrogen-rich.

  • Metallic hydrides are hydrogen-deficient.

Atomic hydrogen or oxy-hydrogen torch is used for cutting and welding purposes because-

  • Atomic hydrogen converts into molecular hydrogen and generates a large amount of energy

  •  Atomic hydrogen converts into molecular hydrogen and generates a low amount of energy

  • Molecular hydrogen converts into atomic hydrogen and generates a large amount of energy

  • Molecular hydrogen converts into atomic hydrogen and generates a low amount of energy

 The correct order of hydrogen bonding among NH3, H2O and HF, is 

  • HF > H2O > NH3

  •  H2O > HF > NH3

  • HF > NH3 > H2O

  •  NH3 > HF > H2O

CO is used as a fire extinguisher because -

  •  CO2 has high lattice energy.

  •  CO2 will be effective in isolating the burning surface from dihydrogen and dioxygen.

  •  CO2 is lighter than dioxygen.

  •  CO2 is lighter than dihydrogen.

The term ’auto-protolysis’ of water means -

  • Physical reaction in which two water molecules react to produce a hydroxide ion (OH) and a hydronium ion (H3O+).

  • Chemical reaction in which five water molecules react to produce a hydroxide ion (OH) and a hydronium ion (H3O+).

  • Chemical reaction in which two water molecules react to produce a hydroxide ion (OH) and a hydronium ion (H3O+).

  • Chemical reaction in which two water molecules react to produce three hydroxide ions (OH)

The correct statement about the reaction of water with fluorine is

  • O is reduced from 0 to -1 oxidation state, whereas F is oxidized from –2 to 0

  • F is reduced from 0  to -1 oxidation state, whereas O is oxidized from –2 to 0

  • F is reduced from 0 to –2 oxidation state, whereas O is oxidized from – 2 to -1

  • O is reduced from 0 to –2 oxidation state, whereas F is oxidized from –3 to 0

The structure of the common form of ice is -

  • Each hydrogen atom is surrounded tetrahedrally by four other oxygen atoms at a distance of 540 pm.

  • Each hydrogen atom is surrounded tetrahedrally by four other oxygen atoms at a distance of 276 pm.

  • Each oxygen atom is surrounded tetrahedrally by four other oxygen atoms at a distance of 276 pm.

  • Each oxygen atom is surrounded tetrahedrally by four other oxygen atoms at a distance of 540 pm.

The temporary and permanent hardness of water is caused by -

  • Permanent hardness is caused by hydrogen carbonates and temporary hardness is caused by chlorides.
  • Temporary hardness is caused by dihydrogen and permanent hardness is caused by oxides.
  • Temporary hardness is caused by insoluble hydrogen carbonates and permanent hardness is caused by chlorides.
  • Temporary hardness is caused by hydrogen carbonates and permanent hardness is caused by chlorides.

The softening of hard water by synthetic ion-exchange resins is based on -

  • Increasing the lattice energy.

  • Physical separation.

  • Lowering the activation energy.

  • Exchange of cations and anions.

Water acts as a base in -

  • Reaction with H2S

  • Reaction with NH3

  • Reaction with NaOH

  • All of the above

‘Demineralised’ water can be obtained by -

  • Passing water successively through an anion exchange (in the K+ form) and cation exchange (in the Mn- form) resin

  • Passing water successively through a cation exchange (in the H+ form) and an anion exchange (in the OH- form) resin

  • Passing water successively through an anion exchange (in the O+ form) and cation exchange (in the OH- form) resin

  • Passing water successively through a cation exchange (in the OH- form) and an anion exchange (in the H+ form) resin

Demineralized or distilled water is not useful for drinking purposes because -

  • Demineralised water contains all insoluble minerals. 

  • Demineralised water is free of all soluble minerals. 

  • Demineralised water contains soluble minerals. 

  • Demineralised water contains soluble anion only.

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