Geometrical isomerism is not shown by:
CH2 = CClCH3
CH3 - CH = CH - CH = CH2
The maximum number of stereoisomers possible for 3-hydroxy-2-methyl butanoic acid is:
1
3
The enol form of acetone after treatment with D2O gives:
OD |CH3—C=CH2
O ||CH3—C—CD3
OH |CH2=C—CH2D
OD |CD2=C—CD3
Maleic and fumaric acids are:
tautomers
geometrical isomers
chain isomers
functional isomers
Isomers which can be interconverted through rotation around a single bond are:
Conformers
Diastereomers
Enantiomers
Positional isomers
How many structures of F are possible?
2
5
6
The optically active alkane with lowest molar mass is:
CH3CH2C≡CH
CH3CH2-CH|CH3-CH3
CH3CH2.CH2CH3
a-D-(+)-glucose and β-D-(+)-glucose are :
enantiomers
conformers
epimers
anomers
The absolute configuration of
is:
S, R
S, S
R, R
R, S
The correct statement regarding electrophile is
Electrophile is a negatively charge species and can form a bond by accepting a pair of electrons from a nucleophile
Electrophile is a negatively charged species and can form a bond by accepting a pair of electrons from another electrophile
Electrophiles are generally neutral species and can form a bond by accepting a pair of electrons from a nucleophile
Electrophile can be either neutral or positively charged species and can form a bond by accepting a pair of electrons from a nucleophile
With respect to the conformers of ethane, which of the following statements is true?
Bond angle remains same but bond length changes
Bond angle changes but bond length remains same
Both bond angle and bond length change
Both bond angles and bond length remain same
The IUPAC name of the compound
is-
3-Keto-2-methylhex-4-enal
5-Formylhex-2-en-3-one
5-Methyl-4-oxohex-2-en-5-al
3-Keto-2-methylhex-5-enal
The correct order of acidity among the following is-
CH2=CH2 > CH3-CH=CH2 > CH3C≡CH > CH≡CH
CH≡CH > CH3-C≡CH > CH2=CH2 > CH3 CH3
CH≡CH > CH2=CH2 > CH3-C≡CH > CH3-CH3
CH3-CH3 > CH2=CH2 > CH3-C≡CH > CH≡CH
The most suitable method of separation of 1:1 mixture of ortho and para-nitrophenols is
sublimation
chromatography
crystallisation
steam distillation
In pyrrole,
The electron density is maximum on
1. 2 and 3 2. 3 and 4
3. 2 and 4 4. 2 and 5
Which among the given molecules can exhibit tautomerisrn?
The correct order of strengths of the carboxylic acids :-
(a) I>II>III (b) II>III>I(c) III>II>I (d) lI>I>IlI
The correct statement regarding the comparison of staggered and eclipsed conformations of ethane is
The eclipsed conformation of ethane is more stable than staggered conformation because eclipsed conformation has no torsional strain
The eclipsed conformation of ethane is more stable than staggered conformation even though the eclipsed conformation has a torsional strain
The staggered conformation of ethane is more stable than eclipsed conformation because staggered conformation has no torsional strain
The staggered conformation of ethane is less stable than eclipsed conformation because staggered conformation has the torsional strain
In Duma’s method for estimation of nitrogen, 0.25g of an organic compound gave 40 mL
of nitrogen collected at 300 K temperature and 725 mm pressure. If the aqueous tension
at 300 K is 25 mm, the percentage of nitrogen in the compound is
17.36
18.20..
16.76
15.76
The compound that gives the most stable carbonium ion after C- Cl bond ionisation among the following is-
consider the following compounds
hyperconjugation occurs in
I only
II only
III only
I and III
Which of the following is the most correct electron displacement for a nucleophilic reaction to take place?
The enolic form of ethyl acetoacetate is given below. The number of sigma and pi bonds in the enolic form of ethyl acetoacetate are -
18 sigma bonds and 2 pi-bonds
16 sigma bonds and 1 pi-bond
9 sigma bonds and 2 pi-bonds
9 sigma bonds and 1 pi-bond
Given,
Which of the given compounds can exhibit tautomerism?
I and II
II and III
I, II and III
The incorrect statement among the following for a nucleophile is-
Nucleophile is a Lewis acid
Ammonia is a nucleophile
Nucleophiles attack low electron density sites
Nucleophiles are not electron seeking
In the Kjeldahl's method for estimation of nitrogen present in a soil sample, ammonia evolved from 0.75 g of sample neutralised 10 mL of 1 M H2SO4. The percentage of nitrogen in the soil is
37.33  
35.33
Which one is most reactive towards nucleophilic addition reaction?
Structure of the compound whose IUPAC name is 3-ethyl-2-hydroxy-4-methylhex-3-en- 5-ynoic acid is ?
The structure of isobutyl group in an organic compound is
Some meta-directing substituents in aromatic substitution are given. Which one is most
deactivating?
-C≡N
-SO3 H
-COOH
-NO2
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