The number of primary carbon atoms in the following compound are-
6
2
4
3
4-methylpent-2-ene is achiral because it has:
a centre of symmetry
a plane of symmetry
symmetry at C 4 carbon
both centre and a plane of symmetry
The (R)- and (S)-enantiomers of an optically active compound differ in
their solubility in a chiral solvent
their reactivity with a chiral reagent
their optical rotation of plane polarised light
their melting points
The cylindrical shape of an alkyne is due to the presence of-
Three sigma C-C bonds
Three π C-C bonds
Two sigma C-C and one π C-C bonds
One sigma C-C and two π C-C bonds
What is decreasing order of basicity of 1°, 2° and 3° ethyl amines and ammonia?
NH3>C2H5NH2>(C2H5)2NH>(C2H5)3N
(C2H5)3N>(C2H5)2NH>C2H5NH2> NH3
(C2H5)3NH>C2H5NH2>(C2H5)3N>NH3
(C2H5)2NH>(C2H5)3N>C2H5NH2>NH3
The shortest C-C bond distance is found in
Diamond
Ethane
Benzene
Acetylene
Which of the following is more basic than aniline?
Diphenylamine
Triphenylamine
p-nitroaniline
Benzylamine
Which one of the following has the shortest carbon-carbon bond length?
Ethene
Ethyne
Which one of the following compounds is most acidic?
Which of the following represents the correct order of acidity in the given compounds?
FCH2COOH > CH3COOH > BrCH2COOH > ClCH2COOH
BrCH2COOH > ClCH2COOH > FCH2COOH > CH3COOH
FCH2COOH > ClCH2COOH > BrCH2COOH > CH3COOH
CH3COOH > BrCH2COOH > ClCH2COOH > FCH2COOH
Among the following the strongest acid is
CH3COOH
CH2ClCH2COOH
CH2ClCOOH
CH3CH2COOH
The distance between two adjacent carbon atoms is largest in
Butane
Increasing order of acidic strength among p-methoxyphenol (I), p-methylphenol (II) and p-nitrophenol (III) is-
III, I, II
II, I, III
III, II, I
I, II, III
Which of the following represent the correct decreasing order of acidic strength of following?
(i) Methanoic acid
(ii) Ethanoic acid
(iii) Propanoic acid
(iv) Butanoic acid
(i)>(ii)>(iii)>(iv)
(ii)>(iii)>(iv)>(i)
(i)>(iv)>(iii)>(ii)
(iv)>(i)>(iii)>(ii)
The IUPAC name of the compound,
is-
1, 3-Dibromo-3-methylbutane
3-Methyl-1,2-bromobutane
3-Methyl-1,3-bromopropane
None of the above
Polar solvent favours keto form while non-polar solvent faours enol form. Which has maximum enolic content in CCl4?
O O || ||CH3-C - CH2 - C- CH3
O O || ||CH3-C-CH2 -C-H
O ||CH3-C-CH2 -COOC2H5
O ||CH3-C-CH2CH3
Maximum enol content is in
The relative stability order of carbanions CH≡C-, CH3 - and CH2=CH- is ____________
CH≡C->CH2=CH->CH3-
CH3->CH2=CH->CH≡C-
CH≡C-<CH2=CH->CH3-
CH2=CH-<CH≡C-<CH3-
A solution of (+)-1 chloro-1-phenylethane in toluene racemizes slowly in the presence of small amount of SbCl5 due to formation of
carbanion
free radical
Among the following compounds, the strongest acid is
HC≡CH
Which of the following is the strongest nucleophile?
Br-
Which of the following is the most stable carbocation
CH2=CH-C⊕H2
CH2=C⊕H
In the following compounds
The order of acidity is-
III>IV>I>II
The carbon-carbon bond length in the compounds
follows the order
III<II<I<IV
IV<I<II<III
I<II<III<IV
I<IV<III<II
In the following compounds,
The order of basicity is
IV>I>III>II
III>I>IV>II
II>I>III>IV
I>III>II>IV
Which of the following happens to be the carbanion with highest stability?
The IUPAC name of the following compounds
is
1-Bromocyclohexane carboxylic acid
3-Bromocyclohexanoic acid
3-Bromoheptanoic acid
3-Bromocyclohexanecarboxylic acid
Trans-2-butene on bromination using CS2 gives which dibromoderivative
(R), (R)-2,3-dibromobutane
(S),(S)-2,3-dibromobutane
Racemic-2,3-dibromobutane
Meso-2,3-dibromobutane
Which of the following carbocations is expected to be most stable?
A group that deactivates the benzene ring towards electrophilic substitution but which directs the incoming group principally to the o- and p-position is.
-NH2
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