In the given conformation C2 is rotated about C2-C3 bond anticlockwise by an angle of 120° then the conformation obtained is

  • Fully eclipsed conformation

  • Partially eclipsed conformation

  • Gauche conformation

  • Staggered conformation

What is the decreasing order of stability of the carbocation ions?

 

  • I>II>III          

  • II>III>I

  • III>I>II          

  •  II>I>III

Which is more acidic?

  • o-cresol       

  • p-nitrophenol
  • Phenol        
  • m-cresol

The correct order of basicities of the following compounds is:

(1)

(2) CH3-CH2-NH2

(3) (CH3)2NH

(4) CH3-C||O-NH2

  • 2>1>3>4         

  • 1>3>2>4

  • 3>1>2>4         

  • 1>2>3>4

Consider the acidity of the following carboxylic acids

(i) PhCOOH

(ii) o-NO2C6H4COOH

(iii) p-NO2C6H4COOH

(iv)m-NO2C6H4COOH

  • i>ii>iii>iv

  • ii>iv>iii>i

  • ii>iv>i>iii

  • ii>iii>iv>i

The IUPAC name of   

  • 3-methyl pentane

  • 2,3-diethyl butane

  • 3,4-dimethyl hexane

  • 2-ethyl 3-methyl pentane

Hybridisation of N in pyrrole  is

  • sp                               

  • sp2
  • sp3                             
  • sp3d

The most reactive of these compounds towards sulphonation is

  • Toluene               

  • Chlorobenzene

  • Nitrobenzene       

  • m-Xylene

In the above compound, arrange the nitrogen according to their decreasing basic strength.

  • 1>2>3>4

  • 4>3>1>2

  • 2>4>1>3

  • 3>4>1>2

 The correct stability order for the following species is:

  • II>IV>I>III

  • II>I>III>IV

  • II>I>IV>III

  • I>III>II>IV

The most stable carbanion among the following is-

  •  
  •   
  •   
  •   

The configuration of given tartaric acid is

  • 2R, 3R         

  • 2R, 3S

  • 2S, 3S         

  • 2S, 3R

   

The IUPAC name of the above mentioned compound is - 

  • (N-Bromo)-3-methyl-2-oxobutanamide

  • (N-Bromo)-2-oxo-4-methylbutanamide

  • (N-Bromo )- 1,2-dioxo-3-methylbutanamine carboxamide

  • (N-Bromo)-1-oxo-2-methylpropane

Which of the following σ-bonds participate in hyperconjugation?

  • I and II

  • I and V

  • II and IV

  • III and IV

Correct IUPAC name of the compound 

  • 4-(Ethyl methanolyonxy)phenylpropanoate

  • Ethyl 4-propanoyloxybenzenecarboxylate

  • 4-(1-Oxo-2-oxabutyl)phenylpropanoate

  • 1-(1-Oxo-2-oxbutyl)-4-(1-oxopropoxy)benzene

Correct IUPAC name of the compound  is

  • 2-Ethyl-3-methylbut-2-ene-1,4-dioic anhydride

  • 3-Ethyl_2-methylbut-2-enedioic anhydride

  • 2-Ethyl-3-Methyl-1,4-diketobut-2-enoic anhydride

  • 2-Ethyl-3-methylcyclopenatanoxy-1,4-dione

The IUPAC name of the following compound is

  • 2-(Ethoxycarbonyl)benzoylchloride

  • Ethyl 2-(chlorocarbonyl)benzoate

  • Ethyl 2-(chloromethanoyl)benzoate

  • Methyl 2-(Chlorocarbonyl)benzene carboxylate.

A hydrocarbon (R) has six membered ring in which there is no unsaturation. Two alkyl groups are atttached to the ring adjacent to each other. One group has 3 carbon atoms with branching at 1st carbon atom of chain and another has 4 carbon atoms. The larger alkyl group has main chain of three carbon atoms of which second carbon is substituted. Correct IUPAC name of compound (R) is

  • 1-(1-Methylethyl)-2-(1-methylpropyl)cyclohexane

  • 1-(2-Methylethyl)-2-(1-methylpropyl)cyclohexane

  • 1-(1-Methylethyl)-2-(2-methylpropyl)cyclohexane

  • 1-(1-Methylethyl)-2-butylcyclohexane

Identify the structure of x,

In which reaction a chiral reactant is giving a chiral product.

Choose the correct statement among the following

  • I effect transfers e from one carbon atom to another

  • I effect operates in both σ\p bond

  • I effect creates no charge in the molecule

  • I effect creates partial charges and it is distance-dependent

The correct stability order of following species is :

  • x > Y > w > z

  • y > x > w > z

  • x > w > z > y

  • z > x > y > w

Which of the following does not represent the resonating structure of

  •  

  •  
  •  
  •  

Ordinarily the barrier to rotation about a carbon-carbon double bond is quite high but in compound P double bond between two rings was observed by NMR to have a rotational energy barrier of only about 20 cal.\mol., showing that it has lot of single bond charcter. The reason for this is

  • Double bond having partial triple bond charcter because of resonance

  • Doule bond undergo flipping

  • Double bond having very high single bond charcter because of aromaticity gained in both three and five membered rings.

  • +I effect of nC3H7 groups makes double bond having partial single bond character.

The most contributing structure in nitroethene among the following is-

  •   

  •   
  •   
  •  

In which of the followig molecules all the effects namely inductive, mesomeric and hyperconjugation operate ?

The acid strength order is:

  • I > IV > II > III

  • III > I > II > IV

  • II > III > I > IV

  • I > III > II > IV

Acid strength of the conjugate acids of the following are-

  • I > II > III > IV

  • III > II > I > IV

  • IV > III > II > I

  • None of these

The acid dissociation constants of the following acids are given as under:

Compound Ka CICH2COOH 136 × 10–5 139 × 10–5 8.9 × 10–5 2.96 × 10–5 CH3CHCH2COOH 1.52 × 10–5 From this data, the following observations can be made. Mark the correct statements for above mentioned compounds.

(i) The above variation in acidities of the above acids are due to inductive effect only.

(ii) The above variation are both due to inductive and resonance effects.

(iii) Inductive effect varies sharply with distance.

(iv) –I effect of chlorine is not much.

  • i and ii

  • i and iii

  • ii and iii

  • iii and iv

If is mixed with NaOH solution. Acid base reaction occurs and HO- snatches H+ from organic molecule. Which carbon will loose H easily?

  • P

  • Q

  • R

  • S

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