The incorrect statement among the following is -


  •  GeOH2 is amphoteric

  •  GeCl2 is more stable than GeCl4

  •  GeO2 is weakly acidic

  • GeCl4 + 2HCl ⇄ H2[GeCl6]

Silicon carbide is used as:

  •   Dehydrating agent

  •   Abrasive

  •   Solvent

  •   Catalyst

An incorrect statement among the following regarding Al2Cl6 is-

  •   Four AlCl bonds are of same length and two of different length

  •   Six AlCl bonds are of same length and two of different length

  •   The angle ClAlCl is 110° and 93°

  •   The angle AlClAl is 87°

Heating an aqueous solution of aluminium chloride to dryness will give:

  •   AlCl3

  •   Al2Cl6

  •   Al2O3

  •   AlOHCl2

Carbon dioxide is a gas but silica is a solid because:

     tetrahedral structure

  •   carbon dioxide is composed of discrete covalent CO2 molecules whereas silica has continuous

  •   CO2 molecules are lighter than SiO2 molecules

  •   CO2 is more acidic than SiO2

  •   melting point of silica is very high

When a mixture of diborane and ammonia is heated, the final product is

  •   BH3

  •   NH4BH4

  •   NH2NH2

  •   B3N3H6

The greatest percentage of CO is in:

  •   coal gas

  •   producer gas

  •   water gas

  •   oil gas

Which of the following shows bond in silicone?

  •   SiCSiOSi

  •   SiCSiCSi

  •   Si|OSi|OSi|

  •   SiSiSiSi

Mica is chemically:

  •   potassium alumino silicate having sheet structure

  •   calcium alumino silicate having fibrous structure

  •   calcium magnesium silicate having three dimensional network

  •   hydrated sodium alumino silicate having three dimensional network

Borazine is obtained by reaction of:

  •   NH3+B2H6 in 2 : 1 ratio

  •   NH3+B2H6 in 1 : 2 ratio

  •   NH3+B2H6 in 1 : 4 ratio

  •   NH3+B2H6 in 4 : 1 ratio

Boric acid is not used:

  •  As an antiseptic

  •  As a flux in soldering

  •  In making optical glasses

  • In making enamels and pottery glazes

Which loses weight on exposure to the atmosphere ?

  • Concentrated H2SO4

  • Solid NaOH

  • A saturated solution of CO2

  • Anhydrous sodium carbonate

Which of the following compound is weakest Lewis acid ?

  • BF3

  • BCl3

  • BBr3

  • BI3

The element among the following that does not show inert pair effect is-

  •   Al

  • Sn

  • Pb

  • Thallium

Pick the correct statement :

  • Borax is white crystalline solid containing [B4O5(OH)4]2- units

  • Aqueous solution of borax is acidic in nature.

  • Cobalt gives green colour in borax bead test.

  • All are incorrect.

An amphoteric  oxide among the following is-

  • CO2

  • CO

  • SnO2

  • CaO

In B2H6 

  • there is direct boron-boron bond

  • the structure is similar to that of C2H6

  • the boron atoms are linked through hydrogen bridges

  • all the atoms are in one plane

From the B2H6 all the following can be prepared except:

  • H3BO3

  • [BH2(NH3)2]+ [BH4]-

  • B2(CH3)6

  • NaBH4

Which of the following shows correct Lewis acidic strength order of trihalides of boron ?

  • BCl3 > BBr3 > BF3 > BI3

  • BF3 < BBr3 < BCl3 < BI3

  • BF3 < BCl3 < BBr3 < BI3

  • BF3 >BCl3 > BBr3 > BI3

It is because inability of ns2 electrons of the valence shell to participate in bonding that

  • Sn2+ is reducing while Pb4+ is oxidising agent

  • Sn2+ is oxidising while Pb4+ is reducing agent

  • Sn2+ and Pb2+ are both oxidising and reducing agent

  • Sn4+ is reducing while Pb4+ is oxidising agent

The number of carbon atoms per unit cell of diamond unit cell is:-


  • 4

  • 8

  • 6

  • 1

Which one of the following anions is present in chain structure silicates?

(a) Si2O76-                 (b) (Si2O52-)n

(c) (Si2O64-)n               (d) SiO44-

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  • 4

BX3+NH3R.T.BX3 .NH3+ Heat of adduct formation H

The numerical value of H is found to be maximum for :

  •  BF3                               

  •  BCl3

  •  BBr3                             

  •  BI3

Borax is converted into crystalline boron by the following steps:

          BoraxXH3BO3B2O3YB

X and Y are respectively :

  • HCl, Mg                                 

  • HCl, C
  • C, Al 
  • HCl, Al

The dissolution of Al(OH)3 in a solution of NaOH results in the formation of -

  •  AlH2O4OH2+       

  •  AlH2O3OH3

  •  AlH2O2OH4-     

  •  AlH2O6OH3

The incorrect statement among the following regarding borax is-

  • It is a useful primary standard for titrating against acids 

  • One molecule of borax contains 4 BOB bonds 

  • Aqueous solution of borax can be used as a buffer

  • It is made up of two triangular BO3 units and two tetrahedral BO4 units

B(OH)3+NaOHNaBO2+NaBOH4+H2O

How can this reaction is made to proceed in forward direction?

  • () addition of cis1, 2 diol                   

  • () addition of borax

  • () addition of trans1, 2 diol               

  • () addition of Na2HPO4

The species among the following that does not exist is-

  •  SnF62-

  •  GeCl62-

  •  CCl62-

  •  SiF62-

The incorrect statement regarding above reactions is :

(a) Al shows amphoteric character

(b) Gas 'P' and 'Q' are different

(d) Both X and Y are water soluble

(d) Gas Q is inflammable

 

 

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  • 3
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The incorrect statement regarding above reactions is :

BF3+LiAlH4Ether(X)+LiF+AlF3

  • Twelve electrons are involed in bonding 

  • Four, two centre-two electron bonds

  • Two, three centre-two electron bonds 

  •  X does not react with NH3

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