Al2O3 can be converted to anhydrous AlCl3 by heating-

  •  Al2O3 with HCl gas

  •  Al2O3 with NaCl in solid-state

  • a mixture of Al2O3  and carbon in dry Cl2 gas

  •  Al2O3  with Cl2 gas

Which of the following species is not stable?

  •   SiCl62-

  •   SiF62-

  •   GeCl62-

  •   SnOH62-

An acid among the following is-

  •  B(OH)3

  •  Al(OH)3

  •  Fe(OH)3 

  • None of the above

Boric acid is polymeric because of:

  • Its acidic nature

  • Presence of hydrogen bonds

  • Its monobasic nature

  • Its geometry

Boric acid on heating at 150°C gives:

  •  B2O3

  •  H2B4O7

  •  HBO2

  •  H2BO3

The product formed in the reaction,

BCl3+H2OProduct is:

  •  H3BO3+HCl

  •  B2O3+HOCl

  •  B2H6+HCl

  • no reaction

H3BO3 is:

  • monobasic and weak Lewis acid

  • monobasic and weak Bronsted acid

  • monobasic and strong Lewis acid

  • tribasic and weak Bronsted acid

On the addition of mineral acid to an aqueous solution of borax, the compound formed is:

  • borodihydride

  • orthoboric acid

  •   metaboric acid

  • pyroboric acid

Borax is prepared by treating boric acid with:

  •  NaNO3

  • NaCl

  •  Na2CO3

  •  NaHCO3

The main factor responsible for weak acidic nature of  B-F bonds in BF3 is:

  • large electronegativity of F

  • three centred two electrons bonds in BF3

  • px-dπ back bonding

  •  pπ- back bonding 

 Which among the following is a gas?

  •  BF3

  •  BCl3

  •  BBr3

  •  BI3

B-F bond order in BF3 is:

  • 1

  • 2

  • 3

  • 4/3

Aluminium reacts with nitrogen to form:

  • AlN

  •  Al2N3

  •  Al2N

  •  Al4N6

Which metal is powdered, suspended in oil and used as paint?

  • Fe

  • Sn

  • Ag

  • Al

Aluminium metal is corroded in coastal  places near to the sea, because protective oxide film:

  • is removed by sea water

  • reacts with sea water

  • is attacked by salts present in sea water

  • reacts with sand particles

Aluminium deposited as vapours on glass forms a good mirror, essentially because:

  • it has better shine than Ag

  • it does not scratch

  • coating is much smoother

  • it does not tarnish in air

Conc. HNO3 can be stored in a container of:

  • Cu

  • Al

  • Zn

  • Sn

Duralumin is an alloy of:

  • Al and Mg

  • Mg and Cu

  • Al, Mg, Mn and Cu

  • Al and Cu

Aluminium is not used:

  • In thermite welding

  • As oxidiser in metallurgy

  • For making utensils

  • In silvery paints

When Al is added to the potassium hydroxide solution:

  • No reaction takes place 

  • Oxygen gas is evolved

  • Water is produced 

  • Hydrogen gas is evolved

A metal powder if spread in air, becomes hazardous is-

  • Al 

  • B

  • Ca

  • K

CO2 and N2 are non-supporters of combustion. However, for putting out fires CO2 is preferred over N2 because CO2:

  • Does not burn.

  • Forms non-combustible products with burning substances.

  • Is denser than nitrogen.

  • Is a more reactive gas.

When sodium or potassium oxide is heated in a current of CO2 at 360°C, we get:

  • sodium formate

  • sodium oxalate

  • sodium acetate

  • sodium carbonate

Which can be directly brought into gaseous state from solid state?

  • CO

  • Solid CO2

  •  PH3

  •  CO+H2

Which is amphoteric oxide?

  • ZnO

  • MnO-4

  • CO2

  • SiO

Which is a true acid anhydride?

  •  Al2O3

  • CO

  • CaO

  •  CO2

CCl4 does not show hydrolysis but SiCl4 is readily hydrolysed because:

  • carbon cannot expand its octet but silicon can expand.

  • electronegativity of carbon is higher than of silicon

  • IP of carbon is higher than of silicon

  • carbon forms double and triple bonds but not silicon

Which is formed when SiCl4 vapours are passed over hot Mg?

  •  SiCl2+MgCl2

  •  Si+MgCl2

  •  Mg2Si+Cl2

  •  MgSiCl6

Asbestors is chemically:

  • silicate of calcium and magnesium

  • calcium alumino silicate

  • magnesium alumino silicates

  • calcium silicate + calcium aluminates

Aqueous solution of sodium silicate is:

  • neutral

  • insoluble

  • acidic

  • alkaline

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