Quartz is made of silicon and oxygen joined in a network arrangement that is similar to:

  • Diamond

  • Graphite

  •  O2

  • None of the above

The product obtained when silica reacts with hydrogen fluoride is:

  •  SiF4

  •  H2SiF6

  •  H2SiF4

  •  H2SiF3

Silica reacts with Mg to form a magnesium compound (A). (A) react with dil. HCl and forms (B). (B) is:

  • MgSiO

  • MgO

  •  MgCl2

  •  SiCl4

Silica is reacted with sodium carbonate. Which is the gas liberated?

  • CO

  •  O2

  •  O3

  •  CO2

Quartz is an example of:

  • chain silicate

  • sheet silicate

  • cyclic silicate

  • three dimensional network silicate

The products of the following reaction are;

SiO2+C

  • SiC and CO2

  •  SiO and CO

  • SiC and CO

  • Si and CO2

Which of the following shows bonding in silicone?

  •  Si-C-Si-O-Si

  •  Si-C-Si-C-Si

  •        l             l             l-Si-O-Si-O-Si-

  •  Si-Si-Si-Si

R3SiCl on polymerisation after hydrolysis forms:

  •  R3SiOH

  •  R3Si-O-SiR3

  •  R2Si=O

  • None of these

Among the following substituted silanes the one which will give rise to cross linked silicone polymer on hydrolysis is:

  •  R4Si

  •  RSiCl3

  •  R2SiCl2

  •  R3SiCl

The most commonly used reducing agent  is:

  •  SnCl4

  • HF

  •  SnCl2

  •  Cl2

Tin plague is the:

  • conversion of stannous to stannic

  • conversion of white tin to grey tin

  • emission of sound while bending a tin rod

  • atmospheric oxidation of tin

When chlorine is passed through molten tin, the product obtained is:

  •  SnCl2

  •  [SbCl4]2-

  •  [SnCl6]2-

  •  SnCl4

Iodine is decolourised by:

  •  ZnCl2

  •  HgCl2

  •  SnCl2

  •  AlCl3

Addition of excess of sodium hydroxide solution to stannous chloride solution, gives:

  •  Sn(OH)2

  •  SnO2.H2O

  •  Na2SnO3

  •  Na2SnO2

When SnCl2 reacts with HgCl2, the product formed is-

  •  Sn+HgCl4

  •  Sn+Cl2+Hg2Cl2

  •  SnCl4 and Hg2Cl2

  • None of the above

The soldiers of the Napolean army while at the Alps during freezing winter suffered a serious problem with regards to the tin buttons of their uniforms. White Metallic tin buttons get converted to grey powder. This transformation is related to-

  • An interaction with water vapour contained in humid air

  • A change in the crystalline structure of tin

  • A change in the partial pressure of O2 in the air

  • An interaction with N2 of air at low temperature

Most ionic chloride is:

  •  PbCl2

  •  CCl4

  •  PbCl4

  •  SiCl4

The amphoteric oxide among the following is -

  •  CO2

  •  PbO2

  •  SiO2

  •  SeO2

Which is not used as pigment in paints?

  • Lead dioxide

  • White lead

  • Lead chromate

  •  Pb3O4

Lead pipes are corroded by:

  •  H2SO4

  • HCl

  •  CH3COOH

  • Pure water

Compound of lead used in match industry is:

  • PbO

  •  PbO2

  •  PbCl2

  • None of these

Lead may be replaced from its salt solution by:

  • Zn

  • Au

  • Ag

  • Cu

Litharge is not commonly used in:

  • manufacture of special glasses

  • glazing pottery

  • preparing paints

  • lead storage battery

When PbO2 reacts with conc. HNO3, the gas evolved in

  •  NO2

  •  O2

  •  N2

  •  N2O

The product formed on heating Pb(NO3)are:

  •  PbO, N2, O2

  • Pb(NO2 )2, O2

  •  PbO, NO2, O2

  •  Pb, N2, O2

Aluminium chloride in acidified aqueous solution forms a complex 'A'. The formula of A and hybridisation state of Al in 'A' is respectively-

  • [Al(H2O)6]3+, sp3d2

  • [Al(H2O)4]3+, sp3

  • [Al(H2O)4]3+, dsp2

  • [Al(H2O)]3+, d2sp3

Which of the following compounds is used in cosmetic surgery?

  • Silica

  • Silicates

  • Silicones

  • Zeolites

Consider the following reaction

BF3 Al2Cl4 A dischargedH2 - gas B H2O C

Select the correct statement.

 

  •   The compound (A) is BCl3

  •   The compound (C) is B2H6

  •   The compound (C) is B2OH4-

  •   The compound (B) is B2Cl4

Tin dissolves in concentrated and dil. H2SO4 as well as HNO3. Which of the following is not the exact product of this process?

  •   SnSO4

  •   SnSO42

  •   SnNO33

  •   H2SnO3  

Mellitic acid is formed by the oxidation of graphite with -

  • Chromic acid

  • Alkaline KMnO4

  • Fuming HNO3

  • dil. HNO3

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