Incorrect option about 2-D sheet silicates is

  •   Two O-atoms of each tetrahedron are shared

  •   General formula is Si2O5n2n-

  •   Co-ordination number of Si is 4

  •   Number of O-atoms per tetrahedra unit is 52

Colemanite mineral is

  •   Ca2B6O115H2O

  •   CaB4O7.NaBO28H2O

  •   2Mg3B8O15MgCl2

  •   Ca2B6O11.3H2O

Hydrolysis of SiF4 gives a compound, in which maximum coordination number of Si is

  •   6

  •   4

  •   8

  •   7

H2C2O4ΔGas(A)+Gas(B)+liquid(C).

Gas (A) burns with blue flame and it oxidised to (B)
Gas(A)+CI2(D) NH3,(E)

A, B, C and E are respectively

  •   CO, CO2, COCl2 and HCONH2

  •   CO, CO2, H2O, COCl2

  •   CO2, CO, H2O, HCONH2

  •   CO, CO2, H2O, NH2CONH2

The most volatile compound among the following is -

  •   CH4

  •   SiH4

  •   GeH4

  •   SnH4

Borazine is called inorganic benzene. It has a ring structure with alternate BH and NH groups. Which of the following statements is not correct about borazine?

  •   Each B and N atom is sp2 hybridized

  •   Borazine satisfies the (4n + 2)π electrons Huckel's rule

  •   Like organic benzene, borazine does not give addition product with HCI

  •   Borazine contains dative pπ - pπ bond

The incorrect statement for orthoboric acid is

  •   It can not be titrated satisfactorily with NaOH, as a sharp endpoint is not obtain

  •   The acidity of its aqueous solution increases upon addition of ethylene glycol

  •   It is a weak electrolyte in water

  •   It has a three-dimensional structure due to hydrogen bonding

In aluminates, the co-ordination number of Al is-

  • 3

  • 6

  • 1

  • 4

A mixed oxide compound among the following is -

  •   PbO2

  •   SnO2

  •   Pb2O3

  •   Pb3O4

Select the correct statement(s) regarding the following reaction sequence
 
   

  •   The compound (A) is CH32SiCl2

  •   The compound D is SiC

  •   The compound (B) is CH32SiOH2

  •   All of the above

The number of double bonds at alternate position in C60 molecule are

  •   20

  •   25

  •   30

  •   36

Incorrect statement among the following is

  •   BnHn+6 are known as arachnoboranes

  •   Indium hydride is a polymeric solid

  •   AlH3 is a monomeric planar molecule

  •   Nido-boranes have the general formula BnHn+6

A species among the following that decomposes easily is -

  •   Pbl2

  •   Pbl4

  •   PbCH3COO4

  •   PbCl2

A strong oxidizing agent among the following is -

  •   Tl3+

  •   Ga3+

  •   ln3+

  •   Al3+

A compound(s) react with BF3 is -

  •   Ethers

  •   H2O

  •   NH3

  •   All of the above

Which of the following statement is incorrect regarding B-F bond in BF3?

  •   All the three B-F bond lengths are equal and each of them is shorter than the sum of the covalent radii of boron and fluorine

  •   The bond energy of the B-F bond is very high, higher than for any other single bond

  •   The unusual shortness and strength of the B-F bond may be explained by pπ-pπ interaction between boron and fluorine atoms

  •   The unusual shortness and strength of the bonds may be explained by a pπ-dπ interaction between boron and fluorine atoms

Under hydrolytic conditions, the compounds used for the preparation of the linear polymer and for chain termination, respectively, are

  •   CH3SiCl3 and SiCH34

  •   CH32SiCl2 and CH33SiCl

  •   CH32SiCl2 and CH3SiCl3

  •   SiC4 and CH33SiCl

Na2B4O710H2O 740C 2NaBO2+(X)+10H2O(X)+CaF2+H2SO4Y+CaSO4+H2O(Y)+NaBH4(Z)+NaBF4

Select the incorrect statement regarding compounds (X), (Y) and (Z).

  •   Compound (X) is B2O3 and compound (Z) contains two 3C - 2e bonds

  •   Compound (X) is B2O3 and compound (Y) contains one 3C - 2e bonds 

  •   Compound (Y) is Lewis acid and stable due to pπ-pπ back bonding

  •   Compound (Z) reacts with excess of NH3 at high temperature gives inorganic graphite 

Which element does not form alum?

  •   Fe

  •   Li

  •   K

  •   Al

The major products obtained in the reaction of oxalic acid with conc. H2SO4 upon heating are

  •   CO, CO2, H2O

  •   CO, SO2, H2O

  •   H2S, CO, H2O

  •   HCOOH, H2S, CO

Al2O3 reacts with 

  •   Only water

  •   Only acids

  •   Only alkalis

  •   Both acids and alkalis

The products formed by the oxidation of NaBH4 and l2 are:

  •   B2H6 and Nal only

  •   B2H6, H2 and Nal 

  •   Bl3 and NaH

  •   NaBl4 and Hl 

In the structure of borax, the numbers of boron atoms and B-O-B units, respectively, are

  •   4 and 5

  •   4 and 3

  •   5 and 4

  •   5 and 3

Hydrolysis of BCl3 gives X which on treatment with sodium carbonate produces Y. X and Y, respectively, are 

  •   H3BO3 and NaBO2

  •   H3BO3 and Na2B4O7

  •   B2O3 and NaBO2

  •   B2O3 and Na2B4O7

The element that combines with oxygen to give an amphoteric oxide is

  •   N

  •   P

  •   Al

  •   Na

The Lewis acid strength of BBr3BCl3 and BF3 is the order 

  •   BBr3 < BCl3 < BF3

  •   BCl3 < BF3 < BBr3

  •   BF3 < BCl3 < BBr3

  •   BBr3 < BF3 < BCl3

The bond energy of B-F bond in BF3 is 646 kJ mol-1, while that of N-F bond in NF3 is 280 kJ mol-1. This is because

 

 

  •   N is more electronegative than B

  •   The atomic mass of N is higher than that of B

  •   The B-F bond gets a partial double bond character due to p-p overlap

  •   N has a lone pair of electrons while B does not have

White fumes appear around the bottle of anhydrous AlCl3. This is due to -

  • Formation of Al(OH)3

  • Dimerisation of AlCl3

  • Hydrolysis of AlCl3 give HCl gas

  • Absorption of moisture 

The most characteristic oxidation state for lead and tin is respectively:

  • +4, +2

  • +2, +4

  • +4, +4

  • +2, +2

B2H6 can't be prepared by -

  •  NaBH4  + I2 

  •  BF3  + NaH 

  •  B3N3H6  + H2O 

  •  Mg3B2 + dil HCl

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Practice Chemistry Quiz Questions and Answers