Incorrect option about 2-D sheet silicates is
Two O-atoms of each tetrahedron are shared
General formula is Si2O5n2n-
Co-ordination number of Si is 4
Number of O-atoms per tetrahedra unit is 52
Colemanite mineral is
Ca2B6O115H2O
CaB4O7.NaBO28H2O
2Mg3B8O15MgCl2
Ca2B6O11.3H2O
Hydrolysis of SiF4 gives a compound, in which maximum coordination number of Si is
6
4
8
7
H2C2O4⟶ΔGas(A)+Gas(B)+liquid(C).
Gas (A) burns with blue flame and it oxidised to (B)Gas(A)+CI2⟶(D) →△NH3,(E)
A, B, C and E are respectively
CO, CO2, COCl2 and HCONH2
CO, CO2, H2O, COCl2
CO2, CO, H2O, HCONH2
CO, CO2, H2O, NH2CONH2
The most volatile compound among the following is -
CH4
SiH4
GeH4
SnH4
Borazine is called inorganic benzene. It has a ring structure with alternate BH and NH groups. Which of the following statements is not correct about borazine?
Each B and N atom is sp2 hybridized
Borazine satisfies the (4n + 2)π electrons Huckel's rule
Like organic benzene, borazine does not give addition product with HCI
Borazine contains dative pπ - pπ bond
The incorrect statement for orthoboric acid is
It can not be titrated satisfactorily with NaOH, as a sharp endpoint is not obtain
The acidity of its aqueous solution increases upon addition of ethylene glycol
It is a weak electrolyte in water
It has a three-dimensional structure due to hydrogen bonding
In aluminates, the co-ordination number of Al is-
3
1
A mixed oxide compound among the following is -
PbO2
SnO2
Pb2O3
Pb3O4
Select the correct statement(s) regarding the following reaction sequence
The compound (A) is CH32SiCl2
The compound D is SiC
The compound (B) is CH32SiOH2
All of the above
The number of double bonds at alternate position in C60 molecule are
20
25
30
36
Incorrect statement among the following is
BnHn+6 are known as arachnoboranes
Indium hydride is a polymeric solid
AlH3 is a monomeric planar molecule
Nido-boranes have the general formula BnHn+6
A species among the following that decomposes easily is -
Pbl2
Pbl4
PbCH3COO4
PbCl2
A strong oxidizing agent among the following is -
Tl3+
Ga3+
ln3+
Al3+
A compound(s) react with BF3 is -
Ethers
H2O
NH3
Which of the following statement is incorrect regarding B-F bond in BF3?
All the three B-F bond lengths are equal and each of them is shorter than the sum of the covalent radii of boron and fluorine
The bond energy of the B-F bond is very high, higher than for any other single bond
The unusual shortness and strength of the B-F bond may be explained by pπ-pπ interaction between boron and fluorine atoms
The unusual shortness and strength of the bonds may be explained by a pπ-dπ interaction between boron and fluorine atoms
Under hydrolytic conditions, the compounds used for the preparation of the linear polymer and for chain termination, respectively, are
CH3SiCl3 and SiCH34
CH32SiCl2 and CH33SiCl
CH32SiCl2 and CH3SiCl3
SiC4 and CH33SiCl
Na2B4O7⋅10H2O →∆740∘C 2NaBO2+(X)+10H2O(X)+CaF2+H2SO4⟶Y+CaSO4+H2O(Y)+NaBH4⟶(Z)+NaBF4
Select the incorrect statement regarding compounds (X), (Y) and (Z).
Compound (X) is B2O3 and compound (Z) contains two 3C - 2e bonds
Compound (X) is B2O3 and compound (Y) contains one 3C - 2e bonds
Compound (Y) is Lewis acid and stable due to pπ-pπ back bonding
Compound (Z) reacts with excess of NH3 at high temperature gives inorganic graphite
Which element does not form alum?
Fe
Li
K
Al
The major products obtained in the reaction of oxalic acid with conc. H2SO4 upon heating are
CO, CO2, H2O
CO, SO2, H2O
H2S, CO, H2O
HCOOH, H2S, CO
Al2O3 reacts with
Only water
Only acids
Only alkalis
Both acids and alkalis
The products formed by the oxidation of NaBH4 and l2 are:
B2H6 and Nal only
B2H6, H2 and Nal
Bl3 and NaH
NaBl4 and Hl
In the structure of borax, the numbers of boron atoms and B-O-B units, respectively, are
4 and 5
4 and 3
5 and 4
5 and 3
Hydrolysis of BCl3 gives X which on treatment with sodium carbonate produces Y. X and Y, respectively, are
H3BO3 and NaBO2
H3BO3 and Na2B4O7
B2O3 and NaBO2
B2O3 and Na2B4O7
The element that combines with oxygen to give an amphoteric oxide is
N
P
Na
The Lewis acid strength of BBr3, BCl3 and BF3 is the order
BBr3 < BCl3 < BF3
BCl3 < BF3 < BBr3
BF3 < BCl3 < BBr3
BBr3 < BF3 < BCl3
The bond energy of B-F bond in BF3 is 646 kJ mol-1, while that of N-F bond in NF3 is 280 kJ mol-1. This is because
N is more electronegative than B
The atomic mass of N is higher than that of B
The B-F bond gets a partial double bond character due to p-p overlap
N has a lone pair of electrons while B does not have
White fumes appear around the bottle of anhydrous AlCl3. This is due to -
Formation of Al(OH)3
Dimerisation of AlCl3
Hydrolysis of AlCl3 give HCl gas
Absorption of moisture
The most characteristic oxidation state for lead and tin is respectively:
+4, +2
+2, +4
+4, +4
+2, +2
B2H6 can't be prepared by -
NaBH4 + I2 →
BF3 + NaH →
B3N3H6 + H2O →
Mg3B2 + dil HCl→
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