Identify the correct statements from the following:

a. CO2(g) is used as a refrigerant ice-cream and frozen food.

b. The structure of C60 customs twelve 6 carbon rings and twenty-five 5 carbon rings

c. ZSM-5, a type of zeolite, is used to convent alcohol into gasoline.

d. CO is a colorless and odorless gas

  • (a) and (c) only

  • (b) and (c) only

  •  (c) and (d) only

  •  (a), (c) and (c) only

An anion that cannot be formed by Boron is -

  •  BF63-

  •  BH4-

  •  B(OH)4-

  •  BO2-

When silicon is boiled with caustic soda solution, the gas is evolved is-

  •  O2

  •  SiH4

  •  H2

  • None of the above

The basic structural unit of silicates is-

 

  •  SiO44-

  •  (SiO3)2-

  •  SiO42-

  •  SiO-

Hydrogen will not reduce 

  • heated cupric oxide

  • heated ferric oxide

  • heated stannic oxide

  • heated aluminium oxide

Aluminium reacts with concentrated HCl and concentrated NaOH to liberate which of the

following gases-

  • H2, and H2

  • O2, and O2

  • O2, and H2

  • H2, and O2

Catenation i.e., linking of similar atoms depends on the size and electronic configuration of atoms. The

the tendency of catenation in group 14 elements follows the order-

  •   C>Si>Ge>Sn

  •   C>>Si>GeSn

  •   Si>C>Sn>Ge

  •   Ge>Sn>Si>C

Which of the following oxide is amphoteric in nature?

(2) SiO2

  • SnO2

  • (3) GeO2

  • 3
  • CO2

Which of the following statements is incorrect?

  • NaHCO3 on heating gives Na2CO3

  • Pure sodium metal dissolves in liquid ammonia to give a blue solution.
  • NaOH reacts with glass to give sodium silicate
  • Aluminium reacts with excess NaOH to give Al(OH)3

Incorrect  statement among the following  about the zeolites is:-

  • They have open structure which enables them to take up small molecules.

  • Zeolites are aluminosilicates having three dimensional network.

  • Some of the SiO44 units are replaced by AlO45 and AlO69 ions in zeolites.

  • They are used as cation exchangers.

In Borax bead test which compound is formed : 

  • Orthoborate

  • Metaborate

  • Double oxide

  • Tetraborate

PbO2  PbO                     G298 <0SnO2SnO                       G298 > 0

The most probable oxidation state of Pb & Sn will be-

  •  Pb+4, Sn+4

  •  Pb+4 , Sn+2

  •  Pb+2 , Sn+2

  •  Pb+2 , Sn+4

BCl has higher stability than TlCl3, because -

3. The +3 oxidation state of B is more stable than the +3 oxidation state of Tl

 

  • The +2 oxidation state of Tl is more stable than the +2 oxidation state of B

  • The +2 oxidation state of B is more stable than the +2 oxidation state of Tl

  • 4. The +3 oxidation state of Tl is more stable than the +3 oxidation state of B

  • 4

Boron trifluoride behaves as a Lewis acid because -

  • Boron trifluoride is electron-rich.

  • Boron trifluoride is electron-deficient.

  • Boron trifluoride is highly stable.

  • None of these.

The correct statement among the following regarding behavior of BCI3 and CCI4 in water is -

  •  BCI3 readily undergoes hydrolysis while CCI4 completely resists hydrolysis.

  •  CCI4  readily undergoes hydrolysis while BCI3 completely resists hydrolysis.

  • Both BCI3 and CCI4 readily undergo hydrolysis.

  • Neither BCI3 nor CCI4 undergo hydrolysis.

Boric acid is a-

  • Protic acid.

  • Weak monobasic acid.

  • Lewis acid.

  • Both '2' and '3'

The effect of heating Boric acid at 370 K or above is -

 

  • Orthoboric acid changes to metaboric acid

  • Metaboric acid changes to boric oxide

  • Both '1' and '2'

  • Neither '1' nor '2'

The shapes of BF3 and BH4- and the hybridization of boron in these species are respectively -

  •  BF3 - triangular geometry, sp2BH4-- tetrahedral, sp3

  •  BF3 - tetrahedral, sp2BH4- - triangular geometry, sp3

  •   BF3 - tetrahedral, sp3BH4- - triangular geometry, sp3

  •  BF3 - tetrahedral, sp2 ; BH4- - triangular geometry, sp2

Reaction(s) that justify the amphoteric nature of aluminum is-

  • 1. 2Al(s) + 6HCl(aq) 2Al+3(aq) + 6Cl-(aq) + 3H2(g)

  • 2. 2Al(s) + 2NaOH(aq) + 6H2O(l)  2Na[Al(OH)4]-(aq) +3H2(g)

  • Both '1' and '2'

  • Neither '1' nor '2'

The electron-deficient compound among the following is -

  •  SiCl4

  •  BCl3

  •  PCl3

  •  ICl

The hybridization of carbon in (a) CO32- (b) diamond (c) graphite is respectively-

  •  sp2sp3sp2

  •  sp2sp3sp3

  •  sp3sp3sp2

  •  sp3sp2sp3

The B–F bond lengths in BF3 (130 pm) and BF4-(143 pm) differ because of-

  • Presence of triple bond character in BF3

  • Resonance in BF4-

  • Presence of a double bond character in BF3

  • Presence of a double bond character in BF4-

B–Cl bond has a dipole moment. Still, the BCl3 molecule has zero dipole moment because-

  • The respective dipole-moments of the B–Cl bond add with each other

  • The respective dipole-moments of the B–Cl bond cancel each other

  • BCl3 is tetrahedral in shape

  •   None of the above

CO is a poisonous gas because -

  • It forms a complex with hemoglobin.

  • The CO–Hb complex is about 300 times more stable than the O2–Hb complex.

  • It can kill a person through suffocation on not receiving oxygen.

  • All of the above

An excessive content of CO2 is responsible for global warming as-

  • Higher the level of carbon dioxide, higher is the amount of heat trapped.

  • Higher the level of oxygen, higher is the amount of heat trapped.

  • Higher the level of carbon dioxide, lesser is the amount of heat trapped.

  • Higher the level of oxygen, lesser is the amount of heat trapped.

The sharp decrease in ionization enthalpy from carbon to silicon happens because of-

  •   Decrease in the charge of elements upon moving down the group.

  •   Decrease in the atomic sizes of elements upon moving down the group.

  •   Increase in the atomic sizes of elements upon moving down the group.

  •   Increase in the charge of elements upon moving down the group.

The correct explanation for the lower atomic radius of Ga as compared to Al is -

  • Poor shielding effect of the 2d-electrons

  • Poor shielding effect of the 3d-electrons

  • Poor shielding effect of the 3p-electrons

  • Poor shielding effect of the 2s-electrons

Amphoteric oxides are:

  •  Tl2O3SiO2

  •  CO2B2O3

  •  B2O3SiO2

  •  AI2O3PbO2

When a metal X is treated with sodium hydroxide, a white precipitate (A) is obtained, which is soluble in excess of NaOH to give soluble complex (B). Compound (A) is soluble in dilute HCl and forms compound (C). The compound (A) when heated strongly gives (D), which is used to extract the metal.

X, C & D are respectively - 

  • Aluminium, aluminium chloride, alumina

  • Aluminium, aluminium hydroxide, aluminium chloride

  • Aluminium hydroxide, aluminium chloride, aluminium

  • Aluminium hydroxide, aluminium chloride, sodium tetrahydroxoaluminate

An aqueous solution of Borax is-

  • Neutral

  • Amphoteric

  • Basic

  • Acidic

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