Identify the correct statements from the following:
a. CO2(g) is used as a refrigerant ice-cream and frozen food.
b. The structure of C60 customs twelve 6 carbon rings and twenty-five 5 carbon rings
c. ZSM-5, a type of zeolite, is used to convent alcohol into gasoline.
d. CO is a colorless and odorless gas
(a) and (c) only
(b) and (c) only
(c) and (d) only
(a), (c) and (c) only
An anion that cannot be formed by Boron is -
BF63-
BH4-
B(OH)4-
BO2-
When silicon is boiled with caustic soda solution, the gas is evolved is-
O2
SiH4
H2
None of the above
The basic structural unit of silicates is-
SiO44-
(SiO3)2-
SiO42-
SiO-
Hydrogen will not reduce
heated cupric oxide
heated ferric oxide
heated stannic oxide
heated aluminium oxide
Aluminium reacts with concentrated HCl and concentrated NaOH to liberate which of the
following gases-
H2, and H2
O2, and O2
O2, and H2
H2, and O2
Catenation i.e., linking of similar atoms depends on the size and electronic configuration of atoms. The
the tendency of catenation in group 14 elements follows the order-
C>Si>Ge>Sn
C>>Si>Ge≈Sn
Si>C>Sn>Ge
Ge>Sn>Si>C
Which of the following oxide is amphoteric in nature?
(2) SiO2
SnO2
(3) GeO2
CO2
Which of the following statements is incorrect?
NaHCO3 on heating gives Na2CO3
Incorrect statement among the following about the zeolites is:-
They have open structure which enables them to take up small molecules.
Zeolites are aluminosilicates having three dimensional network.
Some of the SiO44− units are replaced by AlO45− and AlO69− ions in zeolites.
They are used as cation exchangers.
In Borax bead test which compound is formed :
Orthoborate
Metaborate
Double oxide
Tetraborate
PbO2 → PbO ∆G298 <0SnO2→SnO ∆G298 > 0
The most probable oxidation state of Pb & Sn will be-
Pb+4, Sn+4
Pb+4 , Sn+2
Pb+2 , Sn+2
Pb+2 , Sn+4
BCl3 has higher stability than TlCl3, because -
3. The +3 oxidation state of B is more stable than the +3 oxidation state of Tl
The +2 oxidation state of Tl is more stable than the +2 oxidation state of B
The +2 oxidation state of B is more stable than the +2 oxidation state of Tl
4. The +3 oxidation state of Tl is more stable than the +3 oxidation state of B
Boron trifluoride behaves as a Lewis acid because -
Boron trifluoride is electron-rich.
Boron trifluoride is electron-deficient.
Boron trifluoride is highly stable.
None of these.
The correct statement among the following regarding behavior of BCI3 and CCI4 in water is -
BCI3 readily undergoes hydrolysis while CCI4 completely resists hydrolysis.
CCI4 readily undergoes hydrolysis while BCI3 completely resists hydrolysis.
Both BCI3 and CCI4 readily undergo hydrolysis.
Neither BCI3 nor CCI4 undergo hydrolysis.
Boric acid is a-
Protic acid.
Weak monobasic acid.
Lewis acid.
Both '2' and '3'
The effect of heating Boric acid at 370 K or above is -
Orthoboric acid changes to metaboric acid
Metaboric acid changes to boric oxide
Both '1' and '2'
Neither '1' nor '2'
The shapes of BF3 and BH4- and the hybridization of boron in these species are respectively -
BF3 - triangular geometry, sp2; BH4-- tetrahedral, sp3
BF3 - tetrahedral, sp2; BH4- - triangular geometry, sp3
BF3 - tetrahedral, sp3 ; BH4- - triangular geometry, sp3
BF3 - tetrahedral, sp2 ; BH4- - triangular geometry, sp2
Reaction(s) that justify the amphoteric nature of aluminum is-
1. 2Al(s) + 6HCl(aq) →2Al+3(aq) + 6Cl-(aq) + 3H2(g)
2. 2Al(s) + 2NaOH(aq) + 6H2O(l) → 2Na[Al(OH)4]-(aq) +3H2(g)
The electron-deficient compound among the following is -
SiCl4
BCl3
PCl3
ICl
The hybridization of carbon in (a) CO32- (b) diamond (c) graphite is respectively-
sp2, sp3, sp2
sp2, sp3, sp3
sp3, sp3, sp2
sp3, sp2, sp3
The B–F bond lengths in BF3 (130 pm) and BF4-(143 pm) differ because of-
Presence of triple bond character in BF3
Resonance in BF4-
Presence of a double bond character in BF3
Presence of a double bond character in BF4-
B–Cl bond has a dipole moment. Still, the BCl3 molecule has zero dipole moment because-
The respective dipole-moments of the B–Cl bond add with each other
The respective dipole-moments of the B–Cl bond cancel each other
BCl3 is tetrahedral in shape
CO is a poisonous gas because -
It forms a complex with hemoglobin.
The CO–Hb complex is about 300 times more stable than the O2–Hb complex.
It can kill a person through suffocation on not receiving oxygen.
All of the above
An excessive content of CO2 is responsible for global warming as-
Higher the level of carbon dioxide, higher is the amount of heat trapped.
Higher the level of oxygen, higher is the amount of heat trapped.
Higher the level of carbon dioxide, lesser is the amount of heat trapped.
Higher the level of oxygen, lesser is the amount of heat trapped.
The sharp decrease in ionization enthalpy from carbon to silicon happens because of-
Decrease in the charge of elements upon moving down the group.
Decrease in the atomic sizes of elements upon moving down the group.
Increase in the atomic sizes of elements upon moving down the group.
Increase in the charge of elements upon moving down the group.
The correct explanation for the lower atomic radius of Ga as compared to Al is -
Poor shielding effect of the 2d-electrons
Poor shielding effect of the 3d-electrons
Poor shielding effect of the 3p-electrons
Poor shielding effect of the 2s-electrons
Amphoteric oxides are:
Tl2O3, SiO2
CO2, B2O3
B2O3, SiO2
AI2O3, PbO2
When a metal X is treated with sodium hydroxide, a white precipitate (A) is obtained, which is soluble in excess of NaOH to give soluble complex (B). Compound (A) is soluble in dilute HCl and forms compound (C). The compound (A) when heated strongly gives (D), which is used to extract the metal.
X, C & D are respectively -
Aluminium, aluminium chloride, alumina
Aluminium, aluminium hydroxide, aluminium chloride
Aluminium hydroxide, aluminium chloride, aluminium
Aluminium hydroxide, aluminium chloride, sodium tetrahydroxoaluminate
An aqueous solution of Borax is-
Neutral
Amphoteric
Basic
Acidic
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