Assertion: HNO3 makes iron passive.

Reason: HNO3 forms a protective layer of ferric nitrate on the surface of the iron.

  • Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.

  • Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.

  • Assertion is correct, but Reason is the wrong statement.

  • Assertion is wrong but Reason is the correct statement.

Assertion: HI cannot be prepared by the reaction of KI with concentrated H2SO4.

Reason: HI has the lowest H—X bond strength among halogen acids.

 

  • Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.

  • Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.

  • Assertion is correct, but Reason is the wrong statement.

  • Assertion is wrong but Reason is the correct statement.

Assertion: Both rhombic and monoclinic sulphur exist as S8 but oxygen exists as O2.

Reason: Oxygen forms  -  multiple bonds due to its small size and small bond length but  -  bonding is not possible in sulphur.

  • Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.

  • Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.

  • Assertion is correct, but Reason is wrong statement.

  • Both Assertion and Reason are wrong statements.

Assertion (A) SF6 cannot be hydrolysed but SF4 can be.

Reason (R) Six F-atoms in SF6 prevent the attack of H2O on sulphur atom of SF6

  • Both Assertion and Reason are correct statements, and Reason is the correct explanation of the Assertion.

  • Both Assertion and Reason are correct statements, and Reason is not the correct explanation of the Assertion.

  • Assertion is correct, but Reason is the wrong statement.

  • Assertion is wrong but Reason is a correct statement.

Match the compounds of Xe in column I with the molecular structure in column II.


     Column-I                 Column-II

(a) XeF2                    (i) Square planar

(b) XeF4                    (ii) Linear

(c) XeO3                    (iii) Square pyramidal

(d) XeOF4                  (iv) Pyramidal

  • (a)-(ii) , (b)-(i) , (c)-(iii) , (d)-(iv)

  • (a)-(ii) , (b)-(iv) , (c)-(iii) , (d)-(i)

  • (a)-(ii) , (b)-(iii) , (c)-(i) , (d)-(iv)

  • (a)-(ii) , (b)-(i) , (c)-(iv) , (d)-(iii)

Which one of the following reactions does not come under hydrolysis type reaction?

  •  SiCl4(l)+2H2O(l)SiO2(s)+4HCl(aq)

  •  Li3N(s)+2H2O(l)NH3(g)+3LiOH(aq)

  •  2F2(g)+2H2O(l)4HF(aq)+O2(g)

  •  P4O10(s)+6H2O(l)4H3PO4(aq)

Assertion: H2O is the only hydride of the chalcogen family which is liquid.

Reason: Acidic nature of hydrides of the chalcogen family increases down the group.

  • Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

  • Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

  • Assertion is a true statement but Reason is false.

  • Both Assertion and Reason are false statements.

Assertion: PF5 and IF3 have similar shapes.

Reason: All the bond lengths are equal in PF5.

  • Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

  • Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

  • Assertion is a true statement but Reason is false.

  • Both Assertion and Reason are false statements.

Assertion: Atomic size of F is smaller than that of Cl.

Reason: F-F bond is stronger than the Cl-Cl bond.

  • Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

  • Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

  • Assertion is a true statement but Reason is false.

  • Both Assertion and Reason are false statements.

Assertion: Noble gases have the highest ionization energies in their respective periods.

Reason: The outermost sub-shell of noble gases in which the electron enters is completely filled.

  • Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

  • Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

  • Assertion is a true statement but Reason is false.

  • Both Assertion and Reason are false statements.

Assertion: The valency and oxidation number of sulphur in S8 respectively are 2 and 0.

Reason: S8 Rhombic is the most stable allotropic form of sulphur.

  • Both Assertion & Reason are true and the reason is the correct explanation of the assertion.

  • Both Assertion & Reason are true but the reason is not the correct explanation of the assertion.

  • Assertion is a true statement but Reason is false.

  • Both Assertion and Reason are false statements.

In which of the following arrangements the given sequence is not strictly according to the property indicated against it ?

  (1) H2O<H2S <H2Se <H2Te: increasing pKa values

 (2) NH3<PH3<AsH3<SbH3:       increasing  acidic character 

 (3) CO2<SiO2<SnO2 <PbO2:       increasing oxidising power 

  (4) HF<HCl <HBr<HI :       increasing acidic strength

  • 1
  • 2
  • 3
  • 4

Total number of  bridging oxygen atoms present in P4O10 are :

  • 6

  • 4

  • 2

  • 5

Match List-I (substances) with List-II (processes) employed in the manufacture of the substances and select the correct option.

     List –I                                         List – II
     Substances                                 Processes
(a) Sulphuric acid                         (i) Haber's Process
(b) Steel                                      (ii) Bessemer's Process
(c) Sodium carbonate                  (iii) Leblanc Process
(d) Ammonia                                 (iv) Contact Process

Options :
      (a)  (b)  (c)  (d)

  •   (i)   (ii)  (iii) (iv)
  •   (iv) (iii)  (ii)  (i)
  •   (iv)  (ii)  (iii)  (i)
  •    (i)  (iv)  (ii)  (iii)

Which statement is wrong:

  • Bond energy of F2 > Cl2

  • Electronegativity of F > Cl

  • F is more oxidizing than Cl

  • Electron affinity of Cl > F

Compound that has planar structure :
2. XeOF2

  • XeF4
  • 3. XeO2F2
  • 3
  • XeO4

Oxidation number of P in pyrophosphoric acid is :

  •   + 5
  •   + 2
  •   + 3
  •   + 4

A compound having two direct bonds between P and H atom is :

  •  H3PO2

  •  H3PO3

  •  H3PO4

  •  H4P2O7

General behavior of O3 is : 

  • Gives electrons.

  • Gives O2
  • Reaction with H2
  • Accept electrons.

The correct statement among the following is: -

  • Silicon exhibits 8 coordination numbers in its compound.

  • Bond energy of F2 is less than Cl2

  • Mn(III) oxidation state is more stable than Mn (II) in an aqueous state.

  • Elements of 15th gp show only + 3, and + 5 oxidation states.

Incorrect statement among the following  is :

  • Among halide ions, iodide is the most powerful reducing agent.

  • Fluorine is the only halogen that does not show a variable oxidation state.

  • HOCl is a stronger acid than HOBr

  • HF is a stronger acid than HCl

In X- H ----- Y, X and Y both are electronegative elements : 

  •   Electron density on X will increase and on H will decrease.
  •   In both electron density will increase.
  •   In both electron density will decrease.
  •   On X electron density will decrease and on  H increases.

Nitrogen form N2, but phosphorous form P2, it's at a time convert in P4, reason is : -

  •   Triple bond present between phosphorous atom. 

  •   pπ -  pπ bonding is weak in phosphorous.
  •   pπ -  pπ bonding is strong in phosphorous.
  •   Multiple bond form easilly phosphorous.

NH3 forms a hydrogen bond but PH3 does not because -

  • Phosphorus is more electronegative as compared to nitrogen.

  •  Nitrogen is more electronegative as compared to phosphorus.

  •  Nitrogen and phosphorous have equal electronegativity.

  •  Nitrogen is more stable as compared to phosphorus.

Nitrogen exists as a diatomic molecule and phosphorus as P4 because -

  • On moving up a group, the tendency to form pπ−pπ bonds decreases.
  • On moving down a group, the tendency to form pπ−pπ bonds decreases.
  • On moving down a group, the tendency to form dπ−dπ bonds decreases.
  • On moving up a group, the tendency to form dπ−dπ bonds decreases.

A chemical that depletes the ozone layer is -

  • Sulphur

  • Chlorofluorocarbons (CFCs)

  • Nitrogen

  • Hydrogen

Fluorine forms only one oxoacid, HOF because of -

  • Low electronegativity and small size

  • High electronegativity and small size

  • High electronegativity and big size

  • Low electronegativity and big size

 Oxygen forms hydrogen bonding while chlorine does not, because-

  • Chlorine has a bigger size and as a result, a higher electron density per unit volume.

  • Oxygen has a smaller size and as a result, a lower electron density per unit volume.

  • Oxygen has a smaller size and as a result, a higher electron density per unit volume.

  • Oxygen has a bigger size and as a result, a higher electron density per unit volume.

The uses of ClO2 is /are-

  • It is used for purifying water

  • It is used as a bleaching agent

  • Both '1'and '2'

  • None of the above

Halogens are colored because -

  • They absorb radiations in the U.V region

  • They absorb radiations in the visible region

  • They absorb radiations in the infrared region

  • They absorb radiations in the radiowaves region

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