The correct statement among the following regarding H3PO3 is -
Each hydrogen atom is attached to oxygen
Two hydrogen atoms are attached to oxygen atoms
One atom of H is attached to oxygen
None of the above
Strong oxidising agent and strong reducing agents are respectively
I2, HF
F2, HI
Cl2, HCl
Br2,HBr
Oxide of a non-metal possesses the following characterstics.
(i) It is both a proton donor and proton acceptor
(ii) It is poor conductor of electricity
(iii) It reacts readily with basic and acidic oxides
(iv) It oxidises Fe at boiling point.
The oxide is
H2O
CO2
H2O2
NO
A yellow metallic powder is burnt in a stream of fluorine to obtain a colourless gas X which is thermally stable and chemically inert. Its molecule has octahedral geometry. Another colourless gas Y with same constituent atoms as that of X is obtained when sulphur dichloride is heated with sodium fluoride. Its molecule has triangular pyramidal structure X and Y are
SF4 and S2F2
SF6 and SF4
NaF and NaCl
SF4 and SF6
Indicate for the CIF3 molecule, the shape and the type of hybridization (of the Cl-atom)
In the nitrogen family, the H-M-H bond angle in the hybrides MH3 gradually becomes closer to 90o on going from N to Sb. This shows that gradually
The basic strength of hybrides increases
Almost pure p-orbitals are used for M-H bonding
The bond energies of the M-H bond increases
The bond pairs of electrons become nearer to the central atom
Assertion : In trimethyalamine (N(CH3)3), the nitrogen has a pyramidal geometry, wheres in trisilylamine (N(SiH3)3), it has a planer geometry.
Reason : In trimethylamine, nitrogen shows sp3 hybridization while in trisilyamine it shows sp2 hybridization.
Assertion : Most of the known noble gas compounds are those of xenon.
Reason : The ionisation enthalpy of xenon is very close to that of oxygen.
Assertion : ClF3 exists but FCl3 does not.
Reason : FCl3 is not formed due to the inability of F to expand its coordination number due to the absence of a vacant d subshell.
Assertion: Among hydrides of the elements of group 16, water shows unusual physical properties.
Reason: Water shows unusual physical properties due to hydrogen bonding between the water molecules.
The halogen that gives O2 with hot conc. NaOH is -
F2
Cl2
Br2
l2
The anhydride of HClO4 among the following is -
Cl2O
ClO2
Cl2O7
Cl2O6
Assertion : Fluorine is a stronger oxidizing agent than chlorine.
Reason : Fluorine can displace chlorine from chlorides.
Which of the following pairs of the compound is isostructural?
TeF2 , XeF2
IBr2-, XeF2
IF3 , XeF2
BeCl2 , XeF2
In the structure of ClF3, the number of lone pairs of electrons on central atom 'Cl' is
1
2
3
4
Acidity of diprotic acids in aqueous solutions increases in the order:
H2S<H2Se<H2Te
H2Se<H2S<H2Te
H2Te<H2S<H2Se
H2Se<H2Te<H2S
The incorrect statement among the following regarding oxoacids of phosphorus is -
Orthophosphoric acid is used in the manufacture of triple superphosphate
Hypophoshphorous acid is a diprotic acid
All oxoacids contain tetrahedral four coordinated phosphorus
All oxoacids contain at least one P=O unit and one P-OH group
Sulphur trioxide can be obtained by which of the following reaction
CaSO4+C→∆
Fe2(SO4)3→∆
S+H2SO4→∆
H2SO4+PCl5→∆
Which of the following compounds has the lowest melting point?
CaBr2
Cal2
CaF2
CaCl2
Oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively
+3, +5, +4
+5, +3, +4
+5, +4, +3
+3, +4, +5
The electronegativity difference between N and F is greater than that between N and H yet the dipole moment of NH3 (1.5 D) is larger than that of NF3 (0.2 D). This is because :
in NH3 as well as in NF3 the atomic dipole and bond dipole are in the same direction
in NH3 the atomic dipole and bond dipole are in the same direction whereas in NF3 these are in opposite directions
in NH3 as well as in NF3 the atomic dipole and bond dipole are in opposite directions
in NH3 the atomic dipole and bond dipole is in the opposite directions whereas in NF3 these are in the same directions
The number of unpaired electrons in a paramagnetic diatomic molecule of an element with atomic number 16 is :
Which is the correct thermal stability order for H2EE=O, S, Se, Te and Po?
H2Se<H2Te<H2Po<H2O<H2S
H2S<H2O<H2Se<H2Te<H2Po
H2O<H2S<H2Se<H2Te<H2Po
H2Po<H2Te<H2Se<H2S<H2O
Match the following:
The incorrect statement among the following related to PCl5 is:
PCl5 molecules is non-reactive
Three equatorial P-Cl bonds make an angle of 120° with each other
Two axial P-Cl bonds make an angle of 180° with each other
Axial P-Cl bonds are longer than equatorial P-Cl bonds
The correct structure of tribromo octoxide is:
Aqua regia reacts with Pt to yield :
Pt(NO3)4
H2PtCl6
PtCl4
PtCl2
Radon is used in the treatment of:
Typhoid
Cancer
Cough and cold
Corona
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