Which of the following reactions does not represent a redox change?

  • CaCO3 CaO + CO2

  • 2H2 + O2 2H2O

  • Na + H2 NaOH + 1/2 H2

  • MnCl3  MnCl2 + 1/2 Cl2

If H2S is passed through an acidified K2Cr2O7 solution, the colour of the solution:

  • . will remain unchanged

  • . will change to deep red

  • . will change to dark green

  • . will change to dark brown 

The oxidation number and covalency of sulphur in the sulphur molecule (S8) are respectively:

  • 0 and 2

  • +6 and 8

  • 0 and 8

  • +6 and 2

H2S is passed through an acidified solution of copper sulphate and a black precipitate is formed. This is due to:

  • oxidation of Cu2+

  • reduction of Cu2+

  • double decomposition

  • reduction and oxidation

The most common oxidation state of an element is -2. The number of electrons present in its outermost shell is:

  • 2

  • 4

  • 6

  • 8

4P + 3KOH + 3H2 3KH2PO2 + PH3:

Correct statement regarding the above reaction is -

  • P oxidised only

  • P is reduced only

  • P is oxidised as well as reduced

  • None of the above

In which SOacts as oxidant, while reacting with:

  • acidified KMnO4

  • acidified K2Cr2O7

  • H2S

  • H202

In the reaction;

3Br2 + 6CO32- + 3H25Br- + BrO3- + 6HCO3-

which statement is correct?

  • Br2 is oxidised

  • Br2 is reduced

  • Br2 is neither oxidised nor reduced

  • Br2 is oxidised and reduced as well 

When NaCl is dissolved in water, the sodium ion becomes:

  • oxidised

  • reduced

  • hydrolysed

  • hydrated

Hypochlorite disproportionate to give -

  • Cl- and ClO4-

  •  ClO4- and ClO3-

  •  ClO3- and Cl-

  • ClO2- and Cl-

Which has highest normality?

 

  • 1MH3PO2

  •  1MH3PO3

  •  1MH3PO4

  • All of these

Amongst the following species that have an atom in (+6) oxidation state is-

  • MnO4-

  • Cr(CN)63-

  • NiF62-

  • CrO2Cl2

Mg(OH)2 + HCl Mg(OH)Cl + H2O2, the equivalent weight of Mg(OH)2 will be (M= Mol. wt. of Mg(OH)2)

  • zero

  • M

  • M/2

  • M/4

A metallic oxide contains 20% oxygen. The equivalent weight of metal is

  • 12

  • 16

  • 32

  • 64

2 gm limestone (CaCO3 + Impurities ) is reacted with 100ml N/2 HCl. The excess acid requires 60ml N/2 NaOH. The % purity of limestone is

  • 25%

  • 50%

  • 75%

  • 100%

1.575 gm crystalline oxalic acid |      COOHCOOH·xH2O is dissolved in water and diluted upto 250 ml. 25ml of this solution is completely neutralised with 250ml N/10 NaOH. The value of 'x' is 

  • Zero

  • 1

  • 2

  • 5

A 2 gm mixture of K2CO3 and KCl is completely reacted with 100 ml N/10 HCl. The % of K2CO3 in the mixture is (K = 39, Cl =35.5, C=12, O=16)

  • 69%

  • 34.5%

  • 50%

  • 100%

400 ml M/10 H2SO4 is mixed with 600 ml N/10 NaOH then normality and nature of solution respectively will be

  • 0.02N, basic

  • 0.02N, acidic

  • 0.046N, acidic

  • 0.142N , acidic

The oxidation number of sulphur in S8, S2F2 and H2S respectively are :

  • 0, +1 and -2

  • +2, +1 and -2

  • 0, +1 and +2

  • -2. +1 and -2

When Cl2 is converted into Cl- & ClO3- then n-factor of Clwill be:

  • 3/5

  • 5/3

  • 7/2

  • 2

MnO2 + 4HCl MnCl2+2H2O+Cl2, the equivalent wt. of HCl will be (MMol wt of HCl)

  • M

  • M/2

  • 2M

  • M/4

In Na2S2O3, the oxidation number of S is

  • +2

  • +4 & zero

  • +6 & -2

  • +3

Which acts as a reducing agent only?

  • SO2

  • HNO3

  • MnO2

  • H2S

 

MnO4-(aq) + 8H+(aq) + 5e- Mn2+(aq) + 4H2O(l);E°=1051V

Cr2O72-(aq) +14H+(aq) + 6e 2Cr3+(aq) + 7H2O(l);E°=1.38V

Fe3+(aq) + e- Fe2+(aq);E°=0.77V

Cl2(g) + 2e- 2Cl-(aq); E°= 1.40V

The incorrect statement regarding the quantitative estimation of aqueous  Fe(NO3)is -

 

  • MnO4- can be used in aqueous HCl

  •  Cr2O72- can be used in aqueous HCl

  • MnO-24 can be used in aqueous H2SO4

  •   Cr2O72- can be used in aqueous H2SO4

The equivalent weight of H3PO2, when it disproportionates into PH3 and H3PO3 is 

  • 66

  • 49.5

  • 33

  • 20.5

In the reaction, 2Cu+ Cu + Cu2+, the equivalent weight of Cu+ is (M is the mol. wt. of Cu+)

  • M

  • M/2

  • M/4

  • 2M

Equal volumes of 1M each of KMnO4 and K2Cr2O7 are used to oxidize Fe(II) solution in acidic medium. The amount of Fe oxidized will be

  • More with  KMnO4 

  • More with K2Cr2O7 

  • Equal with both oxidising agent

  • Cannot be determined

Which of the following is Redox reaction?

  • 2CrO42- + 2H+ Cr2O72- + H2O

  • CuSO4 + 4NH3 [Cu (NH3)4] SO4

  • 2Na2S2O3 + I2 Na2S4O6 + 2NaI

  •  Cr2O72- + 2OH- 2CrO42- + H2O

In the reaction:

X HI + Y HNO3 NO + I2 + H2O

  • X=3, Y=2

  • X=2, Y=3

  • X=6, Y=2

  • X=6, Y=1

The equivalent weight of a metal is 4.5 and the molecular weight of its chloride is 80. The atomic weight of the metal is:-

  • 18

  • 9

  • 4.5

  • 36

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