Which of the following reactions does not represent a redox change?
CaCO3 →CaO + CO2
2H2 + O2 →2H2O
Na + H2O → NaOH + 1/2 H2
MnCl3 → MnCl2 + 1/2 Cl2
If H2S is passed through an acidified K2Cr2O7 solution, the colour of the solution:
. will remain unchanged
. will change to deep red
. will change to dark green
. will change to dark brown
The oxidation number and covalency of sulphur in the sulphur molecule (S8) are respectively:
0 and 2
+6 and 8
0 and 8
+6 and 2
H2S is passed through an acidified solution of copper sulphate and a black precipitate is formed. This is due to:
oxidation of Cu2+
reduction of Cu2+
double decomposition
reduction and oxidation
The most common oxidation state of an element is -2. The number of electrons present in its outermost shell is:
2
4
6
8
4P + 3KOH + 3H2O → 3KH2PO2 + PH3:
Correct statement regarding the above reaction is -
P oxidised only
P is reduced only
P is oxidised as well as reduced
None of the above
In which SO2 acts as oxidant, while reacting with:
acidified KMnO4
acidified K2Cr2O7
H2S
H202
In the reaction;
3Br2 + 6CO32- + 3H2O →5Br- + BrO3- + 6HCO3-
which statement is correct?
Br2 is oxidised
Br2 is reduced
Br2 is neither oxidised nor reduced
Br2 is oxidised and reduced as well
When NaCl is dissolved in water, the sodium ion becomes:
oxidised
reduced
hydrolysed
hydrated
Hypochlorite disproportionate to give -
Cl- and ClO4-
ClO4- and ClO3-
ClO3- and Cl-
ClO2- and Cl-
Which has highest normality?
1MH3PO2
1MH3PO3
1MH3PO4
All of these
Amongst the following species that have an atom in (+6) oxidation state is-
MnO4-
Cr(CN)63-
NiF62-
CrO2Cl2
Mg(OH)2 + HCl →Mg(OH)Cl + H2O2, the equivalent weight of Mg(OH)2 will be (M= Mol. wt. of Mg(OH)2)
zero
M
M/2
M/4
A metallic oxide contains 20% oxygen. The equivalent weight of metal is
12
16
32
64
2 gm limestone (CaCO3 + Impurities ) is reacted with 100ml N/2 HCl. The excess acid requires 60ml N/2 NaOH. The % purity of limestone is
25%
50%
75%
100%
1.575 gm crystalline oxalic acid | COOHCOOH·xH2O is dissolved in water and diluted upto 250 ml. 25ml of this solution is completely neutralised with 250ml N/10 NaOH. The value of 'x' is
Zero
1
5
A 2 gm mixture of K2CO3 and KCl is completely reacted with 100 ml N/10 HCl. The % of K2CO3 in the mixture is (K = 39, Cl =35.5, C=12, O=16)
69%
34.5%
400 ml M/10 H2SO4 is mixed with 600 ml N/10 NaOH then normality and nature of solution respectively will be
0.02N, basic
0.02N, acidic
0.046N, acidic
0.142N , acidic
The oxidation number of sulphur in S8, S2F2 and H2S respectively are :
0, +1 and -2
+2, +1 and -2
0, +1 and +2
-2. +1 and -2
When Cl2 is converted into Cl- & ClO3- then n-factor of Cl2 will be:
3/5
5/3
7/2
MnO2 + 4HCl →MnCl2+2H2O+Cl2, the equivalent wt. of HCl will be (M≡Mol wt of HCl)
2M
In Na2S2O3, the oxidation number of S is
+2
+4 & zero
+6 & -2
+3
Which acts as a reducing agent only?
SO2
HNO3
MnO2
MnO4-(aq) + 8H+(aq) + 5e- →Mn2+(aq) + 4H2O(l);E°=1051V
Cr2O72-(aq) +14H+(aq) + 6e →2Cr3+(aq) + 7H2O(l);E°=1.38V
Fe3+(aq) + e- →Fe2+(aq);E°=0.77V
Cl2(g) + 2e- →2Cl-(aq); E°= 1.40V
The incorrect statement regarding the quantitative estimation of aqueous Fe(NO3)2 is -
MnO4- can be used in aqueous HCl
Cr2O72- can be used in aqueous HCl
MnO-24 can be used in aqueous H2SO4
Cr2O72- can be used in aqueous H2SO4
The equivalent weight of H3PO2, when it disproportionates into PH3 and H3PO3 is
66
49.5
33
20.5
In the reaction, 2Cu+ →Cu + Cu2+, the equivalent weight of Cu+ is (M is the mol. wt. of Cu+)
Equal volumes of 1M each of KMnO4 and K2Cr2O7 are used to oxidize Fe(II) solution in acidic medium. The amount of Fe oxidized will be
More with KMnO4
More with K2Cr2O7
Equal with both oxidising agent
Cannot be determined
Which of the following is Redox reaction?
2CrO42- + 2H+ →Cr2O72- + H2O
CuSO4 + 4NH3 →[Cu (NH3)4] SO4
2Na2S2O3 + I2 →Na2S4O6 + 2NaI
Cr2O72- + 2OH- →2CrO42- + H2O
In the reaction:
X HI + Y HNO3 →NO + I2 + H2O
X=3, Y=2
X=2, Y=3
X=6, Y=2
X=6, Y=1
The equivalent weight of a metal is 4.5 and the molecular weight of its chloride is 80. The atomic weight of the metal is:-
18
9
4.5
36
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