One gm. of a metal carbonate gave 0.56 gm. of its oxide on heating. The equivalent mass of the metal is

  • 40

  • 30

  • 20

  • 10

The pair of compounds that can exist together is

  • FeCl3, SnCl2             

  • HgCl2, SnCl2

  • FeCl2, SnCl2             

  • FeCl3, KI

In which of the following compounds, nitrogen exhibits highest oxidation state?

  • N2H                

  • NH3

  • N3H                   

  • NH2OH

A mixture of potassium chlorate, oxalic acid and sulphuric acid is heated. During the

reaction which element undergoes a maximum change in the oxidation number?

  • S

  • H

  • Cl

  • C

The oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively -

  • +3, +5, +4

  • +5, +3, +4

  • +5, +4, +3

  • +3, +4, +5

Oxidation numbers of P in PO43-, of S in SO42- and that of Cr in Cr2O72- are respectively,

  • +5, +6 and +6                     

  • +3, +6 and +5

  • +5, +3 and +6                     

  • -3, +6 and +6

The number of moles of MnO-4 required to oxidise one mole of ferrous oxalate completely in an acidic medium is-

  • 0.6 mole

  • 0.4 mole

  • 7.5 moles

  • 0.2 mole

Which of the following oxidation states are the most characteristics for lead and tin respectively?

  • +4, +2                     

  • +2, +4

  • +4, +4                     

  • +2, +2

Which one of the following orders correctly represents the increasing acid strengths of the given acids?

  • HOCl <HOClO <HOClO< HOClO3

  • HOClO <HOCl <HOClO<HOClO2

  • HOClO<HOClO<HOClO <HOCl

  • HOClO3> HOClO<HOClO <HOCl

HNO2 acts both as reductant and oxidant, while HNO3 acts only as oxidant. It is due to their .

  • Solubility ability

  • Maximum oxidation number

  • Minimum oxidation number

  • Minimum number of valence electrons

The valency of Cr in the complex [Cr(H2O)4Cl2]+ [MP PMT 2000]

  • 1

  • 3

  • 5

  • 6

In the conversion Br2BrO3, the oxidation state of bromine changes from -

  • – 1 to – 1

  • 0 to – 1

  • 0 to + 5

  • 0 to – 5

Oxidation number of cobalt in K[Co(CO)4] is

  • + 1

  • + 3

  • – 1

  • – 3

The oxidation number of nickel in Ni(CO)4

  • 0

  • + 4

  • – 4

  • + 2

Sn++ loses two electrons in a reaction. The final oxidation number of tin will be-

  • + 2

  • Zero

  • + 4

  • – 2

The oxidation number of S in H2S2O8 is -

  • + 2

  • + 4

  • + 6

  • + 7

The oxidation state of nitrogen in N3H is-

  •  +13

  • + 3

  • –1

  •  13

The oxidation state of Cr in [Cr(NH3)4Cl2]+ is [AIEEE 2005]

  • +3

  • +2

  • +1

  • 0

A brown ring complex compound is formulated as [Fe(H2O)5NO]SO4. The oxidation state of iron is 

  • 1

  • 2

  • 3

  • 0

The oxidation number of P in Mg2P2O7 is - 

  • + 3

  • + 2

  • + 5

  • – 3

What is the oxidation number of sulphur in Na2S4O6 - 

  • 23

  • 32

  • 35

  • 52

What is the oxidation number of Co in [Co(NH3)4ClNO2]

  • + 2

  • + 3

  • + 4

  • + 5

When KMnO4 acts as an oxidising agent and ultimately forms [MnO4]2,  MnO2,   Mn2O3,  Mn+2 then the number of electrons transferred in each case respectively is -

  • 4, 3, 1, 5

  • 1, 5, 3, 7

  • 1, 3, 4, 5

  • 3, 5, 7, 1

For the redox reaction MnO4+C2O42+H+Mn2++CO2+H2O the correct coefficients of the reactants for the balanced reaction are 

 

 

MnO4  

C2O42  

H+

(1)  

 2

5

16

(2)

16

5

2

(3)

5

16

2

(4)

2

16

5

  • 1
  • 2
  • 3
  • 4

 The strongest oxidising agent among the following is -

  •  BrO3/Br2+,Eo=+1.50

  •  Fe3+/Fe2+,Eo=+0.76

  •  MnO4/Mn2+,Eo=+1.52

  •  Cr2O72/Cr3+,Eo=+1.33

In the balanced chemical reaction,

IO3+aI+bH+cH2O+dI2

a, b, c and d respectively correspond to -

  • 5, 6, 3, 3 

  • 5, 3, 6, 3

  • 3, 5, 3, 6

  • 5, 6, 5, 5

The number of moles of KMnO4 reduced by one mole of KI in alkaline medium is:

  • One fifth

  • five

  • One

  • Two

In the equation

H2S+2HNO32H2O+2NO2+S

The equivalent weight of hydrogen sulphide is [BVP 2003]

  • 16

  • 68

  • 34

  • 17

If 1.2 g of metal displace 1.12 litre hydrogen at normal temperature and pressure, equivalent weight of metal would be 

  • 24

  • 12

  • 1.2 ÷ 11.2

  • 1.2 × 11.2

The equivalent weight of phosphoric acid (H3PO4) in the reaction NaOH+H3PO4NaH2PO4+H2O is

  • 25

  • 49

  • 59

  • 98

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