One gm. of a metal carbonate gave 0.56 gm. of its oxide on heating. The equivalent mass of the metal is
40
30
20
10
The pair of compounds that can exist together is
FeCl3, SnCl2
HgCl2, SnCl2
FeCl2, SnCl2
FeCl3, KI
In which of the following compounds, nitrogen exhibits highest oxidation state?
N2H4
NH3
N3H
NH2OH
A mixture of potassium chlorate, oxalic acid and sulphuric acid is heated. During the
reaction which element undergoes a maximum change in the oxidation number?
S
H
Cl
C
The oxidation states of P in H4P2O5, H4P2O6, H4P2O7, are respectively -
+3, +5, +4
+5, +3, +4
+5, +4, +3
+3, +4, +5
Oxidation numbers of P in PO43-, of S in SO42- and that of Cr in Cr2O72- are respectively,
+5, +6 and +6
+3, +6 and +5
+5, +3 and +6
-3, +6 and +6
The number of moles of MnO-4 required to oxidise one mole of ferrous oxalate completely in an acidic medium is-
0.6 mole
0.4 mole
7.5 moles
0.2 mole
Which of the following oxidation states are the most characteristics for lead and tin respectively?
+4, +2
+2, +4
+4, +4
+2, +2
Which one of the following orders correctly represents the increasing acid strengths of the given acids?
HOCl <HOClO <HOClO2 < HOClO3
HOClO <HOCl <HOClO3 <HOClO2
HOClO2 <HOClO3 <HOClO <HOCl
HOClO3> HOClO2 <HOClO <HOCl
HNO2 acts both as reductant and oxidant, while HNO3 acts only as oxidant. It is due to their .
Solubility ability
Maximum oxidation number
Minimum oxidation number
Minimum number of valence electrons
The valency of Cr in the complex [Cr(H2O)4Cl2]+ [MP PMT 2000]
1
3
5
6
In the conversion Br2 → BrO3−, the oxidation state of bromine changes from -
– 1 to – 1
0 to – 1
0 to + 5
0 to – 5
Oxidation number of cobalt in K[Co(CO)4] is
+ 1
+ 3
– 1
– 3
The oxidation number of nickel in Ni(CO)4
0
+ 4
– 4
+ 2
Sn++ loses two electrons in a reaction. The final oxidation number of tin will be-
Zero
– 2
The oxidation number of S in H2S2O8 is -
+ 6
+ 7
The oxidation state of nitrogen in N3H is-
+13
–1
−13
The oxidation state of Cr in [Cr(NH3)4Cl2]+ is [AIEEE 2005]
+3
+2
+1
A brown ring complex compound is formulated as [Fe(H2O)5NO] SO4. The oxidation state of iron is
2
The oxidation number of P in Mg2P2O7 is -
+ 5
What is the oxidation number of sulphur in Na2S4O6 -
23
32
35
52
What is the oxidation number of Co in [Co(NH3)4ClNO2]
When KMnO4 acts as an oxidising agent and ultimately forms [ MnO4]−2, MnO2, Mn2O3, Mn+2 then the number of electrons transferred in each case respectively is -
4, 3, 1, 5
1, 5, 3, 7
1, 3, 4, 5
3, 5, 7, 1
For the redox reaction MnO4−+C2O4−2+H+→ Mn2++CO2+H2O the correct coefficients of the reactants for the balanced reaction are
MnO4−
C2O42−
H+
(1)
16
(2)
(3)
(4)
The strongest oxidising agent among the following is -
BrO3−/Br2+, Eo=+1.50
Fe3+/Fe2+, Eo=+0.76
MnO4−/Mn2+, Eo=+1.52
Cr2O72−/Cr3+, Eo=+1.33
In the balanced chemical reaction,
IO3−+a I−+b H+→c H2O+d I2
a, b, c and d respectively correspond to -
5, 6, 3, 3
5, 3, 6, 3
3, 5, 3, 6
5, 6, 5, 5
The number of moles of KMnO4 reduced by one mole of KI in alkaline medium is:
One fifth
five
One
Two
In the equation
H2S+2HNO3→2H2O+2NO2+S
The equivalent weight of hydrogen sulphide is [BVP 2003]
68
34
17
If 1.2 g of metal displace 1.12 litre hydrogen at normal temperature and pressure, equivalent weight of metal would be
24
12
1.2 ÷ 11.2
1.2 × 11.2
The equivalent weight of phosphoric acid (H3PO4) in the reaction NaOH+H3PO4→NaH2PO4+H2O is
25
49
59
98
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