Which of the following acts as an oxidizing as well as a reducing agent?
Na2O
NaO3
NaNO
NaNO2
Alkaline earth metal nitrates on heating decompose to give:
MNO22 and O2 only
MO, N2 and O2
MO, NO2 and O2
MO and NO2 only
Consider the following statements and pick out the correct one.
(1) The solubility, thermal stability, and the basic character of the hydroxides of alkaline earth
metals increases from MgOH2 to BaOH2.
(2) The dehydration of hydrated chlorides, bromides, bromides and iodides of Ca, Sr and Ba can be
achieved on heating.
Lewis acids.
(3) The chlorides of both beryllium and aluminium are soluble in organic solvents and are strong
(1) and (2) only
(1) and (3) only
(1), (2) and (3)
none
A metal [X] heating on nitrogen gas gives [Y]. [Y] on treatment with H2O gives a colourless gas which when passed through CuSO4 solution gives a blue colour. [Y] is-
MgO
MgNO32
Mg3N2
NaN3
Assertion : Beryllium resembles aluminium.
Reason : : Charge / radius of Be2+ ion is nearly the same as that of the Al3+ ion.
Assertion : As the electropositive character increases down the group, the stability of carbonates and hydrogen carbonates of alkali metals increases.
Reason : Lithium carbonates is not so stable to heat ; lithium being very small in size polarizes a large CO32-ion leading to the formation of more stable Li2O and CO2.
The following is the correct order of chemical reactivity with water according to electrochemical series-
K>Mg>Cu>Zn
K>Mg>Zn>Cu
Cu>Zn>K>Mg
Mg>K>Cu>Zn
In the reaction M+O2→MO2 (superoxide) the metal is -
Li
Na
K
Ba
The reaction of sodium with water is highly exothermic. The rate of reaction can be lowered by-
Decreasing the temperature
Mixing with alcohol
Mixing with acetic acid
Making an amalgam
Sodium reacts with water less vigorously than potassium because-
It has a higher atomic weight.
It is less electropositive .
It is more electronegative.
It is a metal .
The correct relation about the density of Na and K is
Na > K
Na = K
K > Na
Li > K
Which of the following does not give an oxide on heating-
MgCO3
Li2CO3
ZnCO3
K2CO3
The reason for a lower basicity of hydroxides of alkaline earth metals than alkali metals is :
Alkali metals form ionic compounds.
The bond strength of oxygen is more for alkali metals.
The electropositivity of alkali metals is more than alkaline earth metals.
The electropositivity of alkali metals is less than alkaline earth metals.
In K+F- ionic radius of F- is more while atomic radius of K+ is –
Less than F-
More than F-
Equal to F-
None of these
Lattice energy is lowest for –
LiF
NaCl
KBr
CsI
MgO is a-
Acidic oxide
Basic oxide
Neutral oxide
Amphoteric oxide
Which of the following statements is wrong ?
Lithium nitrate on heating gives lithium nitrite and O2.
Sodium oxide, Na2O is obtained on heating sodium azide with sodium nitrite.
Potassium cyanide dissolves silver in presence of air or O2.
Potassium formate is formed when moist CO2 reacts with potassium hydride.
Ionic conductances of hydrated M+ ions are in the order-
Li+aq>Na+aq>K+aq>Rb+aq>Cs+aq
Li+aq>Na+aq<K+aq<Rb+aq<Cs+aq
Li+aq>Na+aq>K+aq>Rb+aq<Cs+aq
Li+aq<Na+aq<K+aq<Rb+aq<Cs+aq
Among the following groups of oxides, the group containing oxides that cannot be reduced by carbon to give the respective metals is –
PbO, Fe3O4
CaO, K2O
Cu2O, SnO2
Fe2O3, ZnO
The number of crystal water in Gypsum, Plaster of Paris and Epsom salt respectively are-
2, 0.5, 7
7, 2, 1
7, 0.5, 2
3, 4, 2
Which of the following statement is false regarding saline hydrides –
They conduct electricity in molten state
They dissolve in water and liberate H2
They are used as reducing agents
They are covalent in nature
An amphoteric oxide among the following is-
CaO
SrO
BeO
The incorrect statement among the following regarding Lithium is that-
The hydroxide, carbonate and nitrate decompose to give the oxide on heating.
It is the most electronegative element of group IA.
The hydrogen carbonate cannot be isolated as a stable solid.
It forms superoxide.
Which one of the following is most stable in ether-
BeCl2
CaCl2
SrCl2
The strongest reducing agent is-
Be
Mg
Sr
The largest value of Ksp among the following is -
BeSO4
MgSO4
CaSO4
BaSO4
What are α, β and γ in the following equation
αK4FeCN6+β K2CO3+γS→heat Products ?
the products are Fe, CO2, KCNO and KSCN.
() 1, 2, 3
() 2, 1, 5
() 1, 1, 5
() 2, 2, 3
The correct order of increasing ionic character is –
BeCl2<BaCl2<MgCl<CaCl2
BeCl2<MgCl2<CaCl2< BaCl2
BeCl2<MgCl2<BaCl2<CaCl2
BaCl2<CaCl2<MgCl2<BeCl2
The polarising power of Mg is close to that of –
Cs
Sodium metal cannot be stored under-
Benzene
Kerosene
Alcohol
Toluene
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