The correct order of increasing lattice energy of the metallic compounds is –
NaCl < CaO < NaI < BaO
NaI < NaCl < BaO < CaO
NaCl < NaI < BaO < CaO
NaI < NaCl < CaO < BaO
Which alkali metal has the lowest melting point and exists as a liquid at 30 degree temp–
Na
K
Rb
Cs
The boiling point of calcium is abnormally high as compared to magnesium because-
In calcium d-orbital forms a weak metallic bond
In calcium p-orbital forms a weak metallic bond
In calcium d-orbital forms a strong metallic bond
In calcium s-orbital forms a strong metallic bond
The decreasing order of II ionisation energy of K, Ca, and Ba is –
K > Ca > Ba
(2) Ca > Ba > K
Ba > K > Ca
(4) K > Ba > Ca
Two metals X and Y form covalent halides. Both halides can act as Lewis acids and a catalyst in Friedel Crafts reaction. Halide of X is polymer in the solid state and a dimer in the vapour state which decomposes to monomer at 1200 K. However, halide of Y is a dimer in vapour state and becomes ionic in polar solvent. X and Y are respectively.
Be, Al
Al, Be
Be, Ca
Mg, Ca
Which of the following compounds decomposes on heating similar to LiNO3.
BaNO32
SrNO32
MgNO32
All
Solubility of sulphates in water decreases from MgSO4 to BaSO4. It is due to the fact that –
Ionic nature increases
Size of M2+ ion increases
Lattice energy decrease
Hydration enthalpy of M2+ ions decreases
In the Solvay process of manufacture of sodium carbonate, the raw materials used are :
Aqueous NaOH, NH3 and CO2
Molten NaOH, NH3 and CO
Brine NaCl, NH3 and CO
Brine NaCl, NH3 and CO2
A blue colored solution of an alkali metal in liq NH3 is due to the presence of -
M-atoms.
M+ ions .
Solvated anions .
Solvated electrons.
Alkali metal ions are-
Diamagnetic and coloured.
Diamagnetic and colourless.
Paramagnetic and coloured.
Paramagnetic and colourless.
A compound X on heating gives a colourless gas. The residue is dissolved in water to obtain Y. Excess CO2 is bubbled through an aqueous solution of Y, and Z is formed. Z on gentle heating gives back X. The compound X is-
CaCO3
Na2CO3
CaSO4.2H2O
K2CO3
Magnesia can be prepared by -
Burning Mg in air.
Heating hydroxide, nitrate, sulphate or carbonate of magnesium.
Heating Mg in steam.
All of the above.
A compound insoluble in acetic acid is -
Calcium oxide.
Calcium carbonate.
Calcium oxalate.
Calcium hydroxide.
Assertion : LiF is almost insoluble in water
Reason : LiCl is soluble not only in water but also in acetone.
Assertion : s-block elements do not occur free in nature
Reason: s-block elements are highly electropositive in nature.
Both A and R are true and R is the correct explanation of A.
Both A and R are true, but R is not the correct explanation of A.
A is true, but R is false.
Both A and R are false.
Assertion : Potassium and caesium are useful as electrodes in photoelectric cells.
Reason : Potassium and caesium, when irradiated with light, the light energy absorbed is sufficient to eject out the electron from an atom.
Assertion : The alkaline earth metals have much higher melting and boiling points than those of the alkali metals.
Reason : The melting and boiling points of alkaline earth metal do not vary in a regular fashion.
Assertion : The ionisation enthalpies of alkaline earth metals are fairly low.
Reason : In general, the low ionisation enthalpies of alkaline earth metals are due to large size of their atoms.
Both Be and Al become passive on reaction with concentrated nitric acid due to:
The non-reactive nature of the metal.
The non-reactive nature of the acid.
The formation of an inert oxide layer on the surface of the metals
None of these.
Yellow ppt←K2CrO4X→dil. HClYellow ppt +Z↑(pungent smelling gas)
If X gives a green flame test, then X is:
MgSO4
BaS2O3
CuSO4
PbS2O3
The pair of compounds, that cannot exist together in a solution is -
NaHCO3 and NaOH
Na2CO3 and NaOH
NaHCO3 and Na2CO3
NaHCO3 and H2O
A paramagnetic compound among the following is -
K2O
K2O2
Na2O2
RbO2
The commercial method of preparation of potassium by reduction of molten KCl with metallic sodium at 850°C is based on the fact that -
Potassium is solid and sodium distils off at 850 °C.
Potassium is more volatile and distils off thus shifting the reaction forward.
Sodium is more reactive than potassium at 850 °C.
Sodium has less affinity to chloride ions in the presence of potassium ions.
Solubility of alkaline earth metals' sulphates in water decreases in the sequence-
Which one of the alkali metals forms only, the normal oxide, M2O on heating in air?
Li
Which one of the following compounds is a peroxide?
KO2
BaO2
MnO2
NO2
Please disable the adBlock and continue. Thank you.