Which one of the following is incorrect for ideal solution ?
∆Hmix=0
∆Umix=0
∆P=Pobs-Pcalculated by Raoul's law = 0
∆Gmix=0
Which gas when passed through dilute blood will impart a cherry red colour to the solution?
CO2
COCl2
NH3
CO
The vapour density of undecomposed N2O4 is 46. When heated, vapour density decreases to 24.5 due to its dissociation to NO2. The percent dissociation of N2O4 at the final temperature is:
87
60
40
70
At 298 K, 500cm3 H2O dissolved 15.30 cm3 CH4(STP) under a partial pressure of methane of one atm. If Henry's law holds, what pressure is required to cause 0.001 mole methane to dissolve in 300cm3 water ?
0.29 atm
2.33 atm
1.29 atm
3.11 atm
The molal depression constant for water=1.85 deg/molal and for benzene is 5.12 deg/molal. If the ratio of the latent heats of fusion of benzene to water is 3:8, calculate the freezing point of benzene.
6.75°C
5.12°C
8.97°C
6.1°C
Which of the following colligative properties is associated with the concentration term 'molarity'?
Lowering of vap.pressure
Osmotic pressure
Depression in freezing point
Elevation in boiling point
The vapour pressure of a dilute aqueous solution of glucose is 750 mm of mercury at 373 K. The mole fraction of solute in the solution is-
Which one of the folowing pairs of solution can we expect to be isotonic at the same temperature-
0.1 (M) urea and 0.1 (M) NaCl
0.1 (M) urea and 0.2 (M) MgCl2
0.1 (M) NaCl and 0.1 (M) Na2SO4
0.1 (M) Ca(NO3)2 and 0.1 (M) Na2SO4
The latent heat of vapourisation of water is 540 cal g-1 at 100°C. Kb for water is
1. 0.56 K.mole-1
2. 1.86 K.mole-1
3. 0.51 K.mole-1
4. 5.12 K.mole-1
Which of the following aqueous solution has osmotic pressure nearest to that an equimolar solution of K4[Fe(CN)6]?
Na2SO4
BaCl2
Al2(SO4)3
C12H22O11
The molar volume of liquid benzene (density= 0.877 g ml-1) increases by a factor of 2750 as it vapourises at 20°C. At 27°C when a non-volatile solute (that does not dissociate) is dissolved in 54.6cm3 of benzene, vapour pressure of this solution, is found to be 98.88 mm Hg. calculate the freezing point of the solution.
Given: Enthalpy of vapourisation of benzene(l)=394.57 Jg-1. Enthalpy of fusion of benzene (l) = 10.06 kJ mol-1 Molal depression constant for benzene=5.0 K kg mol-1.
177.65 K
277.65 K
517.65 K
237.15 K
The depression in the freezing point of water when 10 g of CH3CH2CHClCOOH is added to 250 g of water is -Ka=1.4 X 10-3, Kf=1.86K kg mol-1
0.15°C
2.15°C
1.15°C
0.65°C
The ratio of the vapour pressure of a solution to the vapour pressure of the solvent is
Equal to the mole fraction of the solvent
Proportional to the mole fraction of the solute
Equal to the mole fraction of the solute
None of the above
Mole fraction of the component A in vapour phase is X1 and mole fraction of component A in liquid mixture is X2 then
(PA0 = vapour pressure of pure A; PB0= vapour pressure of pure B),
then total vapour pressure of the liquid mixture is-
PA0X2X1
PA0X1X2
PB0X1X2
PB0X2X1
pH of a 0.1 (M) monobasic acid is 2. Osmotic pressure at a given temperature T is-
0.1 RT
0.11RT
1.1RT
0.01RT
The vapour pressure of pure water at 298K is 23.76mm. The vapour pressure of a solution of sucrose(C12H22O11) in 5.56 moles of water is 23.392mm Hg. The mass of sucrose in the solution is
15 g
45 g
30 g
37.5 g
Among the following options, 0.1 M aqueous solution will have the lowest freezing point is-
Potassium Sulphate
Sodium chloride
Urea
Glucose
The vapour pressure of toluene is 59.1 torr at 313.75 K and 298.7 torr at 353.15 K. Calculate, the molar heat of vaporisation.
37888 J mol-1
27188 J mol-1
12834 J mol-1
571328 J mol-1
The vapour pressure of pure liquid solvent A is 0.80 atm. When a non-volatile substance B is added to the solvent, its vapour pressure drops to 0.60 atm, mole fraction of the component B in the solution is-
0.50
0.75
0.40
0.25
Lowest boiling point among the following 0.1 (M) aqueous solution is -
a. K2SO4
b. NaCl
c. Urea
d. Glucose
a, b
b, c
c, d
d, a
The boiling point of acetic acid is 118.1°C and its latent heat of vaporisation is 121 cal/gm. A solution containing 0.4344 gm anthracene in 44.16 gm acetic acid boils at 118.24°C. What is the molecular wt. of anthracene ?
122
178
105
154
Which solution will have the highest boiling point ?
1 (M) C6H12O6 solution
1 (M) NaCl solution
1 (M) BaCl2 solution
1 (M) CO(NH2)2 solution
A 2.0% solution by weight of urea in water shows a boiling point elevation of 0.18 deg [Molecular weight of urea=60]. Calculate the latent heat of vaporization per gram of water.
495.3 cal/g
560.3 cal/g
525.8 cal/g
501.3 cal/g
A solution of 18 g of glucose in 1000 g of water is cooled to -0.2°C. The amount of ice separating out from this solution is -
(KfH2O=1.86 K molal-1)
70 g
140 g
90 g
210 g
The partial pressure of ethane over a saturated solution containing 6.56 X 10-2 g of ethane is 1 bar. If the solution contains 5.00 X 10-2 g of ethane, then what shall be the partial pressure of the gas.
0.76 bar
0.16 bar
1.16 bar
3.12 bar
In a dilute solution, any colligative property depends on
The total number of neutral species in the solution
The total number of ionic species in the solution
The total number of species irrespective of whether they are ionic or non-ionic.
The types of forces operating between the non-ionic species, ionic species and the solvent molecules
An aqueous solution of 2 percent non volatile solute exerts a pressure of 1.004 bar at the boiling point of the solvent. What is the molecular mass of the solute ?
9.19 g mol-1
41.3 g mol-1
71.2 g mol-1
50.4 g mol-1
An aqueous solution of hydrochloric acid is-
Obeys Raoult's law
Shows negative deviations from Raoult's law
Shows positive deviations from Raoult's law
Obeys Henry's law at all compositions
1000 gm of 1 m sucrose solution in water is cooled to -3.534°C. What weight of ice would be separated out at this temperature ? Kf'(H2O)=1.86 K mol-1kg.
352.98 gm.
252.98 gm.
302.98 gm.
152.12 gm
Osmotic pressure of equimolar solution of BaCl2, NaCl and glucose will be in the order -
BaCl2 > NaCl > glucose
glucose > NaCI > BaCl2
NaCl > BaCl2 >glucose
NaCl> glucose > BaCl2
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