Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose to nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 X 10−3 m aqueous solution required for the above dose is?
3.2 g
0.2 g
5.1 g
7.3 g
One molal solution of a carboxylic acid in benzene shows the elevation of boiling point of 1.518 K. The degree of association for dimerisation of the acid in benzene is
(Kb for benzene = 2.53 K kgmol-1)
60%
70%
75%
80 %
The relationship between osmotic pressure at 273K, when 10gm glucose(P1), 10 gm urea (P2) and 10 gm sucrose (P3) dissolved in 250 ml of water is-
P1 > P2 > P3
P3 > P1 > P2
P2 > P1 > P3
P2 > P3 > P1
If 'A' contains 2% NaCl and is separated by a semi permeable membrane from 'B', which contains 10% NaCl, then the event will occur is-
NaCl will flow from 'A' to 'B'
NaCl will flow from 'B' to 'A'
Water will flow from 'A' to 'B'
Water will flow from 'B' to 'A'
The vapour pressure of water depends upon:
surface area of container
volume of container
Temperature
All of these
The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows
No deviation from Raoult's law
Positive deviation from Raoult's law
Negative deviation from Raoult's law
That the solution is unsaturated
A 5.85% solution of NaCl has osmotic pressure close to-
5.85% solution of urea
2M solution of glucose
1M solution of urea
5.8% solution of glucose
The mole(s) of K2SO4 to be dissolved in 12 moles water to lower its vapor pressure by 10 mm of Hg at a temperature at which vapor pressure of pure water is 50 mm of Hg is-
3 mol
0.5 mol
1 mol
2 mol
The salt that possesses the highest freezing point is-
0.01 M MgCl2
0.02 M NaCl
Aluminium phosphate is 100% ionized in 0.01m aqueous solution. Hence, ∆Tb/kb is-
0.01
0.015
0.0175
0.02
Which solution has highest freezing point?
1% glucose solution
1% urea solution
1% sucrose solution
All have same freezing
Osmotic pressure of 40% (w/V) urea solution is 1.64 atm. and that of 3.42% (w/V) cane sugar solution is 2.46 atm. When equal volumes of the above two solutions are mixed, the osmotic pressure of the resulting solution will be?
(1) 64 atm
(2) 46 atm
(3) 4.10 atm
(4) 2.05 atm
20g of naphthoic acid (C11H8O2) dissolved in 50g of benzene (Kf=1.72 K Kg mol-1) shows a depression in freezing point of 2K. The Vant Hoff factor is?
0.1
2
3
A 0.002 molar solution of NaCl having degree of dissociation of 90% at 270C, has osmotic pressure equal to:-
0.94 bar
9.4 bar
0.094 bar
9.4 x 10-4 bar
The density of NH4OH solution is found to be 0.6 g/ml. It contains 35% by mass of NH4OH. The normality of the solution is
4.8 N
10 N
0.5 N
6 N
The relative lowering of vapour caused by dissolving 71.3g of a substance in 1000g of water is 7.13x10-3. The molecular mass of substance is-
180
18
1.8
360
Total vapour pressure of a mixture of 1 mol A (pA° = 150 torr) and 2 mol B (pB° = 240 torr) is 200 torr. In this case:-
There is positive deviation from Raoult's law
There is negative deviation from Raoult's law
There is no deviation from Raoult's law
None of these
Which of the following aqueous solution should have the highest osmotic pressure?
50 g of antifreeze (ethylene glycol) is added to 200g water. What amount of ice will separate out at -9.3°C. (Kf = 1.86 K Kg mol-1) :-
40 g NaOH (i=2) is dissolved in 1L volatile solvent vapour pressure of this solution becomes equal to its solid phase at 300K. What is the freezing point of pure solvent.
(Density = 1g/mL) (Kf=1.8 k kgmol-1)
296.4 K
303.6 K
297.5 K
302.4 K
At 100°C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be
100°C
102°C
103°C
101°C
P1 and P2 are vapour pressure of solvent and solution at temperature T. The solution is prepared by dissolving non-volatile solute in the same solvent. P1 =760 torr, P2 =684 mm Hg, Mole fraction of solvent in the solution will be:-
0.2
0.9
Can't be predicted
100 g solute is dissolved in 1400 g of solvent. Density of resultant solution is 1.5 g/mL. The ratio of its molarity and molality will be :-
As scuba divers come towards water surface from underwater, solubility of gases in their blood :-
Solution A & B are formed by dissolving a certain amount of glucose and sucrose in water. The Vapour pressure of these solutions is 660 and 560 mm Hg respectively at 100oC. The ratio of molality of solutions A & B will be:-
1. 1433 2. 33143. 15354. 3515
Saturated solution of Ag2SO4 shows 0.003K rise in boiling point, Ksp will be :(Kb = 5 K kg mol-1)(1m=1M)
3.2 x 10-11
3.2 x 10-10
3.2 x 10-9
3.2 x 10-12
When 36 g of a solute having the empirical formula CH2O is dissolved in 1.2 kg of water, the solution freezes at -0.93°C. What is the molecular formula of solute (Kf = 1.86 kg K mol-1)
6g urea is dissolved in 1kg solvent. Value of (T1-T2) will be : (Kf=2 kg K mol-1)
A solution containing 0.03659 g/ml of HCl and a solution containing 0.04509 g/ml of acetic acid Then:
NHCl is more
NCH3COOH is more
Both have same normality
The lubricating action of an oil is more if it possess:-
High vapour pressure
low vapour pressure
High surface tension
High density
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