Nalorphene (C19H21NO3), similar to morphine, is used to combat withdrawal symptoms in narcotic users. Dose to nalorphene generally given is 1.5 mg. Calculate the mass of 1.5 X m aqueous solution required for the above dose is?

  • 3.2 g

  • 0.2 g

  • 5.1 g

  • 7.3 g

One molal solution of a carboxylic acid in benzene shows the elevation of boiling point of 1.518 K. The degree of association for dimerisation of the acid in benzene is 

(Kb for benzene = 2.53 K kgmol-1)

  • 60%

  • 70%

  • 75%

  • 80 %

The relationship between osmotic pressure at 273K, when 10gm glucose(P1), 10 gm urea (P2) and 10 gm sucrose (P3) dissolved in 250 ml of water is-

  • P1 > P2 > P3

  • P3 > P1 > P2

  • P2 > P1 > P3

  • P2 > P3 > P1

If 'A' contains 2% NaCl and is separated by a semi permeable membrane from 'B', which contains 10% NaCl, then the event will occur is-

  • NaCl will flow from 'A' to 'B'

  • NaCl will flow from 'B' to 'A'

  • Water will flow from 'A' to 'B'

  • Water will flow from 'B' to 'A'

The vapour pressure of water depends upon:

  • surface area of container

  • volume of container

  • Temperature

  • All of these

The boiling point of an azeotropic mixture of water and ethanol is less than that of water and ethanol. The mixture shows

  • No deviation from Raoult's law

  • Positive deviation from Raoult's law

  • Negative deviation from Raoult's law

  • That the solution is unsaturated

A 5.85% solution of NaCl has osmotic pressure close to-

  • 5.85% solution of urea

  • 2M solution of glucose

  • 1M solution of urea

  • 5.8% solution of glucose

The mole(s) of K2SO4 to be dissolved in 12 moles water to lower its vapor pressure by 10 mm of Hg at a temperature at which vapor pressure of pure water is 50 mm of Hg is-

  • 3 mol

  • 0.5 mol

  • 1 mol

  • 2 mol

The salt that possesses the highest freezing point is-

  • 0.01M NaCl
  • 0.05M Urea

  • 0.01 M MgCl2

  • 0.02 M NaCl

Aluminium phosphate is 100% ionized in 0.01m aqueous solution. Hence, Tb/kb is-

  • 0.01

  • 0.015

  • 0.0175

  • 0.02

Which solution has highest freezing point?

  • 1% glucose solution

  • 1% urea solution

  • 1% sucrose solution

  • All have same freezing

Osmotic pressure of 40% (w/V) urea solution is 1.64 atm. and that of 3.42% (w/V) cane sugar solution is 2.46 atm. When equal volumes of the above two solutions are mixed, the osmotic pressure of the resulting solution will be?  


  • (1) 64 atm

  • (2) 46 atm

  • (3) 4.10 atm

  • (4) 2.05 atm 

20g of naphthoic acid (C11H8O2) dissolved in 50g of benzene (Kf=1.72 K Kg mol-1) shows a depression in freezing point of 2K. The Vant Hoff factor is?

  • 0.5

  • 0.1

  • 2

  • 3

A 0.002 molar solution of NaCl having degree of dissociation of 90% at 270C, has osmotic pressure equal to:-

  • 0.94 bar

  • 9.4 bar

  • 0.094 bar

  • 9.4 x 10-4 bar

The density of NH4OH solution is found to be 0.6 g/ml. It contains 35% by mass of NH4OH. The normality of the solution is

  • 4.8 N

  • 10 N

  • 0.5 N

  • 6 N

The relative lowering of vapour caused by dissolving 71.3g of a substance in 1000g of water is 7.13x10-3. The molecular mass of substance is-

  • 180

  • 18

  • 1.8

  • 360

Total vapour pressure of a mixture of 1 mol A (pA° = 150 torr) and 2 mol B (pB° = 240 torr) is 200 torr. In this case:-

  • There is positive deviation from Raoult's law

  • There is negative deviation from Raoult's law

  • There is no deviation from Raoult's law

  • None of these 

Which of the following aqueous solution should have the highest osmotic pressure?

  • 0.011 M AICIat 50°C
  • 0.03 M NaCI at 25°C
  • 0.012 M (NH4)2SOat 25°C
  • 0.03 M NaCI at 50°C

50 g of antifreeze (ethylene glycol) is added to 200g water. What amount of ice will separate out at -9.3°C. (Kf = 1.86 K Kg mol-1) :-

  • 42 mg
  • 42 g
  • 38.71 g
  • 38.71 mg

40 g NaOH (i=2) is dissolved in 1L volatile solvent vapour pressure  of this solution becomes equal to its solid phase at 300K. What is the freezing point of pure solvent.

(Density = 1g/mL) (Kf=1.8 k kgmol-1)

  • 296.4 K

  • 303.6 K 

  • 297.5 K

  • 302.4 K

At 100°C the vapour pressure of a solution of 6.5 g of a solute in 100 g water is 732 mm. If Kb = 0.52, the boiling point of this solution will be

  • 100°C

  • 102°C

  • 103°C

  •  101°C

P1 and P2 are vapour pressure of solvent and solution at temperature T. The solution is prepared by dissolving non-volatile solute in the same solvent. P1 =760 torr, P2 =684 mm Hg, Mole fraction of solvent in the solution will be:-

  • 0.1

  • 0.2

  • 0.9

  • Can't be predicted

100 g solute is dissolved in 1400 g of solvent. Density of resultant solution is 1.5 g/mL. The ratio of its molarity and molality will be :-

  • (1) 5
  • (2) 1.3
  • (3) 1.4
  • (4) 1.2

As scuba divers come towards water surface from underwater, solubility of gases in their blood :-

  • Increases
  • Decreases
  • Firstly Increases then decrease
  • Firstly Decreases then Increase

Solution A & B are formed by dissolving a certain amount of glucose and sucrose in water. The Vapour pressure of these solutions is 660 and 560 mm Hg respectively at 100oC. The ratio of molality of solutions A & B will be:-

1. 1433     2. 33143. 15354. 3515

  • 1
  • 2
  • 3
  • 4

Saturated solution of Ag2SO4 shows 0.003K rise in boiling point, Ksp will be :(Kb = 5 K kg mol-1)(1m=1M)

  • 3.2 x 10-11

  •   3.2 x 10-10

  •   3.2 x 10-9

  •   3.2 x 10-12

When 36 g of a solute having the empirical formula CH2O is dissolved in 1.2 kg of water, the solution freezes at -0.93°C. What is the molecular formula of solute (K= 1.86 kg K mol-1)

  •  C2H4O
  • C2H2O2
  • C2H4O3
  • C2H4O2

6g urea is dissolved in 1kg solvent. Value of (T1-T2) will be : (Kf=2 kg K mol-1)

  • 0.2°C
  • -0.2°C
  • 0.1°C
  • -0.1 K

A solution containing 0.03659 g/ml of HCl and a solution containing 0.04509 g/ml of acetic acid Then:

  • NHCl is more

  • NCH3COOH is more

  • Both have same normality

  • None of these

The lubricating action of an oil is more if it possess:-

  • High vapour pressure

  • low vapour pressure

  • High surface tension

  • High density

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