A solution of acetone in ethanol is-

  • Shows a negative deviation from Raoult's law

  • Shows a positive deviation from Raoult's law

  • Behaves like a near ideal solution

  • Obeys Raoult's law

Three solutions are prepared by adding 'w' gm of 'A' into 1kg of water, 'w' gm of 'B' into another 1 kg of water and 'w' gm of 'C' in another 1 kg of water (A, B, C are non electrolytic). Dry air is passed from these solutions in sequence (A → B → C). The loss in weight of solution A was found to be 2gm while solution B gained 0.5 gm and solution C lost 1 gm. Then the relation between molar masses of A, B and C is :

  • MA: MB : Mc = 4 : 3 : 5

  • MA : MB: Mc = 14:13:15

  • Mc > MA > MB

  • MB > MA> Mc

How many mili moles of sucrose should be dissolved in 500 gms of water so as to get a solution which has a difference of 103.57°C between boiling point and freezing point.

(K1 = 1.86 K Kg mol−1, Kb = 0.52 K Kg mo1−1)

  • 500 mmoles

  • 900 mmoles

  • 750 mmoles

  • 650 mmoles

The molar heat of vapourization of toluene is AHv. If its vapour pressure at 315 K is 60 torr & that at 356K is300 torr then AHv = ? (log 2 = 0.3)

  • 37.5 kJ/mole

  • 3.75 kJ/mole

  • 37.5 J/mol

  • 3.75 J/mole

Relative decrease in vapour pressure of an aqueous solution containing 2 moles [Cu(NH3)3Cl) Cl in 3 moles H2O is 0.50. On reaction with AgNO3, this solution will form (assuming no change in degree of ionisation of substance on adding AgNO3)

  • 1 mol AgCl

  • 0.25 mol AgCl

  • 0.5 mol AgCl

  • 0.40 mol AgCl

Which of the following has been arranged in order of decreasing freezing point?

  • 0.05 M KNO3 > 0.04 M CaCl2 > 0.140 M sugar > 0.075 M CuSO4

  • 0.04 M BaCl2 > 0.140 M sucrose > 0.075 M CuSO4 > 0.05 M KNO3

  • 0.075 MCuSO4 > 0.140 M sucrose > 0.04 M BaCl2 > 0.05 M KNO3

  • 0.075 M CuSO4 > 0.05 M NaNO3 > 0.140 M sucrose > 0.04 M BaCl2

A solution of x moles of sucrose in 100 grams of water freezes at −0.2°C. As ice separated the freezing point goes down to 0.25°C. How many grams of ice would have separated?

  • 10 grams

  • 20 grams

  • 25 grams

  • 23 grams

An ideal mixture of liquids A and B with 2 moles of A and 2 moles of B has a total vapour pressure of 1 atm at a certain temperature. Another mixture with 1 mole of A and 3 moles of B has a vapour pressure greater than 1 atm. But if 4 moles of C are added to the second mixture, the vapour pressure comes down to 1 atm. Vapour pressure of C, Pc° = 0.8 atm. Calculate the vapour pressures of pure A and pure B.

  • (1) PA° = 4 atm, PB° = 0.7 atm

  • (2) PA = 1.2 atm, PB° = 0.6 atm

  • (3) PA = 1.4 atm, PB° = 0.6 atm

  • (4) PA° = 0.6 atm, PB° = 1.4 atm

A sample of air is saturated with benzene (vapor pressure = 100 mm Hg at 298 K) at 298K, 750mm Hgpressure. If it is isothermally compressed to one third of its initial volume, the final pressure of the system is

  • 2250 torr

  • 2150 torr

  • 2050 torr

  • 1950 torr

Available solutions are 1L of 0.1 M NaCl and 2L of 0.2 M CaCl2. Using only these two solutions what maximum volume of a solution can be prepared having [Cl] = 0.34M exactly. Both electrolytes are strong

  • 2.5 L

  • 2.4 L

  • 2.3 L

  • None of these

Consider equimolal aqueous solutions of NaHSO4 and NaCl with Tb and T'b as their respective boiling point elevations. The value of limx0ΔTbΔTb' will be :

  • 1

  • 1.5

  • 3.5

  • 3

The vapor pressures of benzene, toluene and a xylene are 75 Torr, 22 Torr and 10 Torr at 20°C. Which of the following is not a possible value of the vapor pressure of an equimolar binary/ternary solution of these at 20°C ? Assume all form ideal solution with each other.

  • 4812

  • 16

  • 3523

  • 5312

Osmotic pressure is 0.0821 atm at a temperature of 300 K. Find concentration in mole/litre [Roorkee 1990]

  • 0.033

  • 0.066

  • 0.33 × 10–2

  • 3

The osmotic pressure of 5% (mass-volume) solution of cane sugar at 150°C (mol. mass of sugar = 342) is- 

  • 4 atm

  • 5.07 atm

  • 3.55 atm

  • 2.45 atm

3.24 g of Hg(NO3)2 (molar mass = 324) dissolved in 1000 g of water constitutes a solution having a freezing point of –0.0558°C while 21.68 g of HgCl2 (molar mass = 271) in 2000 g of water constitutes a solution with a freezing point of –0.0744°C. The Kf for water is 1.86 K – KgMol. About the state of ionization of these two solids in water it can be inferred that:

  • Hg(NO3)2 and HgCl2 both are completely ionized

  • Hg(NO3)2 is fully ionized but HgCl2 is fully unionized

  • Hg(NO3)2 and HgCl2 both are completely unionized

  • Hg(NO3)2 is fully unionized but HgCl2 is fully ionized  

15 g of methyl alcohol is dissolved in 35 g of water. The weight percentage of methyl alcohol in solution is

  • 70%

  • 30%

  • 50%

  • 75%

The seawater sample contains 5.8 × 10–3 g of dissolved oxygen per kilogram of the sample. The concentration of oxygen in parts per million is-

  • 5.8 ppm

  • 58.5 ppm

  • 0.58 ppm

  • 0.05 ppm

A 500 gm toothpaste sample has 0.2 g fluoride concentration. The concentration of fluoride ions in terms of ppm level is

  • 250 ppm

  • 200 ppm

  • 400 ppm

  • 1000 ppm

Normality of a solution containing 9.8 g of H2SO4 in 250 cm3 of the solution is

[MP PMT 1995, 2003; CMC Vellore 1991; JIPMER 1991]

  • 0.8 N

  • 1 N

  • 0.08 N

  • 1.8 N

Amount of NaOH present in 200 ml of 0.5 N solution is 

  • 40 g

  • 4 g

  • 0.4 g

  • 4.4 g

50 ml of 10NH2SO4,25ml of 12 N HCl and 40 ml of 5NHNO3 were mixed together and the volume of the mixture was made 1000 ml by adding water. The normality of the resulting solution will be 

  • 1 N

  • 2 N

  • 3 N

  • 4 N

100 ml of 0.3 N HCl is mixed with 200 ml of 0.6 N H2SO4. The final normality of the resulting solution will be

  • 0.1 N

  • 0.2 N

  • 0.3 N

  • 0.5 N

An aqueous solution of 6.3 g oxalic acid dihydrate is made up to 250 ml. The volume of 0.1 N NaOH required to completely neutralize 10 ml of this solution is [IIT 2001; CPMT 1986]

  • 40 ml

  • 20 ml

  • 10 ml

  • 4 ml

10.6 g of Na2CO3 was exactly neutralised by 100 ml of H2SO4 solution. Its normality is

  • 1 N

  • 2 N

  • 1.5 N

  • 0.5 N

The molarity of pure water (d = 1 g/l) is -

  • 555 M

  • 5.55 M

  • 55.5 M

  • None of the above

Equal volumes of 0.1MAgNO3 and 0.2 M NaCl are mixed. The concentration of NO3 ions in the mixture will be 

  • 0.1 M

  • 0.05 M

  • 0.2 M

  • 0.15 M

The molarity of H2SO4 solution that has a density of 1.84 g/cc at 35°C and contains 98% by weight is

  • 4.18 M

  • 8.14 M

  • 18.4 M

  • 18 M

Amount of oxalic acid (COOH)2.2H2O in grams that is required to obtain 250 ml of a semi-molar solution is 

  • 17.25 g

  • 17.00 g

  • 15.75 g

  • 15.00 g

Volume of 10 M HCl should be diluted with water to prepare 2.00 L of 5 M HCl is 

  • 2 L

  • 1.5 L

  • 1.00 L

  • 0.5 L

The volume of 95% H2SO4 (density = 1.85 g cm–3) needed to prepare 100 cm3 of 15% solution of H2SO4 (density = 1.10 g cm3) will be

  • 5 cc

  • 7.5 cc

  • 9.4 cc

  • 12.4 cc

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