When a non-volatile solute is dissolved in a solvent. The relative lowering of vapor pressure is equal to
Molar fraction of solute
Molar fraction of solvent
Concentration of the solute in grams per liter
Concentration of the solute in gram per 100 mL.
Van't Hoff factor is
More than one in case of association
Less than one in case of dissociation
Equal to normal molecular massobserved molecular mass
Equal to observed molecular massnormal molecular mass
The solubility of a gas in a liquid increase with
Increase of temperature
Amount of liquid taken
Decrease in temperature
Reduction of gas pressure
Which of the following solution would exhibit abnormal colligative properties?
1 M glucose
0.1 M NaCl
0.1 M sucrose
10 gram glass powder in water
The number of moles of sodium hydroxide present in 2.5 L and 0.5 M aqueous solution will be
(1) 25
(2) 0.5
(3) 12.5
(4) 5
Maximum freezing point will be for 1 molal solution of assuming equal ionization in each case:
[Fe(H2O)6]Cl3
[Fe(H2O)5Cl] Cl2.H2O
[Fe(H2O)4Cl2]Cl.2H2O
[Fe(H2O)3Cl3].3H2O
The solution which has the lowest freezing point is
0.1 M potassium nitrate
0.1 M aluminium sulphate
0.1 M potassium chloride
0.1 M potassium sulphate
The vant Hoff factor 'i' accounts for
the extent of dissociation of solute
the extent of dissolution of solute
the degree of decomposition of solution
degree of solubilization of solute
The azeotropic mixture of water and ethanol boils at 78.15°C. When this mixture is distilled, it is possible to obtain-
Pure H2O
Pure C2H5OH
Pure H2O as well as pure C2HOH
Neither H2O nor C2H5OH in their pure state
Which of the following changes with a change in temperature?
Mole fraction
Formality
%(W/W)
Molality
When the solute is present in trace quantities the following expression is used
Gram per million
Nanogram percent
Microgram percent
parts per million
Increasing the temperature of an aqueous solution will cause
Decrease in molality
Decrease in molarity
Decrease in mole fraction
Decrease in % (w/w)
During depression in freezing point in a solution, the following are in equilibrium.
liquid solvent, solid solvent
liquid solvent, solid solute
liquid solute, solid solute
liquid solute, solid solvent
When the attraction between A — B is more than that of A-A and B— B, the solution will show deviation from Raoult’s law
Positive
Negative
No
Cannot be Predicted
Can an egg be inserted into a bottle with a narrow neck without distorting its shape?
1) Yes
2) No
3) Maybe
4) Insufficient data is there
An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. Molar mass of the solute would be -
23.69 g mol-1
41.35 g mol-1
56.23 g mol-1
22.76 g mol-1
Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. The vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane would be -
43.45 kPa
78.96 Pa
73.43 kPa
65.72 Pa
A 5% solution (by mass) of cane sugar in water has freezing point of 271K. Freezing point of 5% glucose in water would be -
(freezing point of pure water is 273.15 K)
279.24 K
- 269.06 K
275. 42o C
269.06 K
If the density of lake water is 1.25g mL–1 and contains 92 g of Na+ ions per kg of water, then the molality of Na+ ions will be-
4 molal
5 molal
3.5 molal
3.24 molal
The Vapour pressure of water at 293 K is 17.535 mm Hg. The vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water is-
18.54 mm of Hg
17.44 mm of Hg
12.35 mm of Hg
18.67 mm of Hg
Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. The mole fraction of benzene in vapour phase, if 80 g of benzene is mixed with 100 g of toluene would be -
0.41
0.68
0.72
0.59
1. 2.76 × 10-3 atm2. 5.39 × 10-4 atm3. 5.27 × 10-3 atm4. 3.19 × 10-3 atm
The osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litres of water at 25° C, assuming that it is completely dissociated is-
Mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride is
0.46
0.54
0.27
0.35
What is the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution?
74 g
69 g
33 g
37 g
What is the molarity of KI if density of 20% (mass/mass) aqueous KI is 1.202 g mL-1?
1.23 mol L-1
1.45 mol L-1
1.62 mol L-1
1.45 mol mL-1
H2S, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of H2S in water at STP is 0.195 molal, what is the Henry’s law constant?
255 bar
293 bar
342 atm
282 bar
Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. What is the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K?
1.57 g
1.85 g
0.15 g
1.96 g
Boiling point of water at 750 mm Hg is 99.63°C. How much sucrose is to be added to 500 g of water such that it boils at 100°C?
( Kb H2O = 0.52 K kg mol−1)
134.76g
121.67g
145.14g
124.79g
What is the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1.5°C? Kf = 3.9 K kg mol−1.
6.83 g
6.03 g
4.12 g
5.08 g
What is the osmotic pressure exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C?
42.56 Pa
30.98 Pa
23.67 Pa
67.55 Pa
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