When a non-volatile solute is dissolved in a solvent. The relative lowering of vapor pressure is equal to 

 

  • Molar fraction of solute 

  • Molar fraction of solvent 

  • Concentration of the solute in grams per liter 

  • Concentration of the solute in gram per 100 mL.

Van't Hoff factor is 

  • More than one in case of association 

  • Less than one in case of dissociation 

  • Equal to normal molecular massobserved molecular mass

  • Equal to observed molecular massnormal molecular mass

The solubility of a gas in a liquid increase with 

  • Increase of temperature

  • Amount of liquid taken

  • Decrease in temperature

  • Reduction of gas pressure

Which of the following solution would exhibit abnormal colligative properties?

  • 1 M glucose

  • 0.1 M NaCl

  • 0.1 M sucrose 

  • 10 gram glass powder in water 

The number of moles of sodium hydroxide present in 2.5 L and 0.5 M aqueous solution will be

  • (1) 25

  • (2) 0.5

  • (3) 12.5

  • (4) 5

Maximum freezing point will be for 1 molal solution of assuming equal ionization in each case:

  • [Fe(H2O)6]Cl3

  • [Fe(H2O)5Cl] Cl2.H2O

  • [Fe(H2O)4Cl2]Cl.2H2O

  • [Fe(H2O)3Cl3].3H2O

The solution which has the lowest freezing point is 

  • 0.1 M potassium nitrate

  • 0.1 M aluminium sulphate

  • 0.1 M potassium chloride

  • 0.1 M potassium sulphate

The vant Hoff factor 'i' accounts for

  • the extent of dissociation of solute

  • the extent of dissolution of solute

  • the degree of decomposition of solution

  • degree of solubilization of solute

The azeotropic mixture of water and ethanol boils at 78.15°C. When this mixture is distilled, it is possible to obtain-

  • Pure H2O

  • Pure C2H5OH

  • Pure H2O as well as pure C2HOH

  • Neither H2O nor C2H5OH in their pure state 

Which of the following changes with a change in temperature?

  • Mole fraction

  • Formality

  • %(W/W)

  • Molality

When the solute is present in trace quantities the following expression is used

  • Gram per million

  • Nanogram percent

  • Microgram percent

  • parts per million

Increasing the temperature of an aqueous solution will cause

  • Decrease in molality

  • Decrease in molarity

  • Decrease in mole fraction

  • Decrease in % (w/w)

During depression in freezing point in a solution, the following are in equilibrium.

  • liquid solvent, solid solvent

  • liquid solvent, solid solute

  • liquid solute, solid solute

  • liquid solute, solid solvent

When the attraction between A — B is more than that of A-A and B— B, the solution will show deviation from Raoult’s law

  • Positive

  • Negative

  • No

  • Cannot be Predicted 

Can an egg be inserted into a bottle with a narrow neck without distorting its shape?

1) Yes

2) No

3) Maybe

4) Insufficient data is there

 

  • 1
  • 2
  • 3
  • 4

An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. Molar mass of the solute would be -

  • 23.69 g mol-1

  • 41.35 g mol-1

  • 56.23 g mol-1

  • 22.76 g mol-1

Heptane and octane form an ideal solution. At 373 K, the vapour pressures of the two liquid components are 105.2 kPa and 46.8 kPa respectively. The vapour pressure of a mixture of 26.0 g of heptane and 35 g of octane would be -

  • 43.45 kPa

  • 78.96 Pa

  • 73.43 kPa 

  • 65.72 Pa

A 5% solution (by mass) of cane sugar in water has freezing point of 271K. Freezing point of 5% glucose in water would be -

(freezing point of pure water is 273.15 K)

  • 279.24 K

  • - 269.06 K

  • 275. 42o C

  • 269.06 K

If the density of lake water is 1.25g mL–1 and contains 92 g of Na+ ions per kg of water, then the molality of Na+ ions will be-

  • 4 molal

  • 5 molal

  • 3.5 molal

  • 3.24 molal

The Vapour pressure of water at 293 K is 17.535 mm Hg. The vapour pressure of water at 293 K when 25 g of glucose is dissolved in 450 g of water is-

  • 18.54 mm of Hg

  • 17.44 mm of Hg

  • 12.35 mm of Hg

  • 18.67 mm of Hg

Benzene and toluene form ideal solution over the entire range of composition. The vapour pressure of pure benzene and toluene at 300 K are 50.71 mm Hg and 32.06 mm Hg respectively. The mole fraction of benzene in vapour phase, if 80 g of benzene is mixed with 100 g of toluene would be -

  • 0.41

  • 0.68

  • 0.72

  • 0.59

 1. 2.76 × 10-3 atm2. 5.39 × 10-4 atm3. 5.27 × 10-3 atm4. 3.19 × 10-3 atm

  • 1
  • The osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litres of water at 25° C, assuming that it is completely dissociated is-

  • 3
  • 4

Mole fraction of benzene in solution containing 30% by mass in carbon tetrachloride is

  • 0.46

  • 0.54

  • 0.27

  • 0.35

What is the mass of urea (NH2CONH2) required in making 2.5 kg of 0.25 molal aqueous solution?

  • 74 g

  • 69 g

  • 33 g

  • 37 g

What is the molarity of KI if density of 20% (mass/mass) aqueous KI is 1.202 g mL-1?

 

  • 1.23 mol L-1

  • 1.45 mol L-1

  • 1.62 mol L-1

  • 1.45 mol mL-1

H2S, a toxic gas with rotten egg like smell, is used for the qualitative analysis. If the solubility of H2S in water at STP is 0.195 molal, what is the Henry’s law constant?

 

  • 255 bar

  • 293 bar

  • 342 atm

  • 282 bar

Henry’s law constant for CO2 in water is 1.67 × 108 Pa at 298 K. What is the quantity of CO2 in 500 mL of soda water when packed under 2.5 atm CO2 pressure at 298 K?

  • 1.57 g

  • 1.85 g

  • 0.15 g

  • 1.96 g

Boiling point of water at 750 mm Hg is 99.63°C. How much sucrose is to be added to 500 g of water such that it boils at 100°C?

 ( Kb H2O = 0.52 K kg mol−1)

 

  • 134.76g

  • 121.67g

  • 145.14g

  • 124.79g

What is the mass of ascorbic acid (Vitamin C, C6H8O6) to be dissolved in 75 g of acetic acid to lower its melting point by 1.5°C? Kf = 3.9 K kg mol−1.

  • 6.83 g

  • 6.03 g

  • 4.12 g

  • 5.08 g

What is the osmotic pressure exerted by a solution prepared by dissolving 1.0 g of polymer of molar mass 185,000 in 450 mL of water at 37°C?

  • 42.56 Pa

  • 30.98 Pa

  • 23.67 Pa

  • 67.55 Pa

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