Among the following  application/s of osmosis is/are : 


  • In animals, water moves into different parts of the body.

  • Stretching of leaves, flower.

  • Opening and closing of flowers.
  • All of the above.

The unit that relates concentration of solution with its vapour pressure is: 

 

  •   Mole fraction.

  •   Parts per million.

  •   Mass percentage.

  •   Molality.

A beaker contains a solution of substance 'A' . Precipitation of substance ‘A’ takes place when small amount of 'A' is added to the solution. The solution is -

 

  •   Saturated.

  •   Supersaturated.

  •   Unsaturated.

  •   Concentrated.

Colligative properties depend on -

 

  •   The nature of the solute particles dissolved in solution.

  •   The number of solute particles in solution.

  •   The physical properties of the solute particles dissolved in solution.

  •   The nature of solvent particles.

A solution that has the highest boiling point among the following is -

 

  • 1.0 M NaOH

  • 1.0 M Na2SO4 

  • 1.0 M NH4NO3

  • 1.0 M KNO3

An unripe mango placed in a concentrated salt solution to prepare pickle shrivels because -

 

  •   It gains water due to osmosis.

  •   It loses water due to reverse osmosis.

  •   It gains water due to reverse osmosis.

  •   It loses water due to osmosis.

At a given temperature, osmotic pressure of a concentrated solution of a substance is-

 

  •   Is higher than that of a dilute solution.

  •   Is lower than that of a dilute solution.

  •   Is same as that of a dilute solution.

  •   Cannot be compared with osmotic pressure of dilute solution.

Value of Henry's constant Kis-

 

  •   Increases with increase in temperature.

  •   Decreases with increase in temperature.

  •   Remains constant.

  •   First increases then decreases.

The value of Henry's constant, KH is ......... .

 

  •   Greater for gases with higher solubility.

  •   Greater for gases with lower solubility.

  •   Constant for all gases.

  •   Not related to the solubility of gases.

Intermolecular forces between two benzene molecules are nearly the same strength as those between two toluene molecules.

Incorrect statement among the following for a mixture of benzene and toluene is -

a. mixH= zero

b. ΔmixV = Zero

c. These will form a minimum boiling azeotrope

d. These will not form an ideal solution

  • (a, b)

  • (b, c)

  • (c, d)

  • (a, d)

For a binary ideal liquid solution, the curve that represents the variation in total vapor pressure versus composition of the solution is -

a.  

b.   

c.  

d.   

The correct option is-

  • (a, b)

  • (b, c)

  • (c, d)

  • (a, d)

3. 22.6 kg mol-1

  • 53.50 g mol-1

  • 43.5 kg mol-1

  • 4. 41.35 g mol-1

  • An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. The molar mass of the solute is -

If 8g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapour pressure to 80%, the molar mass (in g mol–1) of the solute is -

[Molar mass of n-octane is 114 g mol–1 ]

  • 40

  • 60

  • 80

  • 20

Isotonic solutions have same-

  • Vapour pressure

  • Freezing temperature

  • Osmotic pressure

  • Boiling temperature

The molarity of H2SO4 solution that has a density 1.84 g/cc at 35°C and contains 98% H2SO4 by weight is-

  • 1.84 M

  • 81.4 M

  • 18.4 M

  • 184 M

Vapour pressure of chloroform (CHCl3) and dichloromethane (CH2Cl2) at 25°C are 200 mmHg and 41.5 mmHg respectively. Vapour pressure of the solution obtained by mixing 25.5 g of (CHCl3) and 40 g of (CH2Cl2) at the same temperature will be: (Molecular mass of (CHCl3) = 119.5 u and molecular mass of (CH2Cl2) = 85 u)

  •   90.40 mm Hg

  •   119.5 mm Hg 

  •   75 mm Hg 

  •   173.9 mm Hg 

A 0.1 molal aqueous solution of a weak acid (HA) is 30% ionized. If Kf for water is 1.86°C/m, the freezing point of the solution will be -

  • –0.24°C 

  • –0.18°C

  • –0.54°C 

  • –0.36°C

200 mL of an aqueous solution of a protein contains it's 1.26 g. The Osmotic pressure of this solution at 300 K is found to be 2.57 × 10–3 bar.The molar mass of protein will be

(R = 0.083 L bar mol–1 K–1):

  • 61038 g mol–1 

  • 51022 g mol–1

  • 122044 g mol–1 

  • 31011 g mol–1

Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. The solubility of methane in benzene at 298 K under 760 mm Hg is -

 

  • 1.78 x 10-3

  •  1.78 x 10-5

  • 2.98 x 10-4

  • 3.78 x 10-3

The addition of water vapours does not change the density of -

  •   CCl4

  •   CS2

  •   Ether

  •   Coke

1% (w/w)solution of a compound is isotonic with 5% (w/w)sucrose (sugar) solution. Then molecular wt. of compound will be :

  •   32.4
  •   68.4
  •   129.6
  •   34.2

Mole fraction of solute is 0.2 in solution then lowering in V.P (∆P) = 10. If lowering in V.P.( ∆P) = 20 then mole fraction of solvent will be in solution :

  •   0.2
  •   0.4
  •   0.6
  • 4  0.8

Camphor is often used in molecular mass determination because :-

  • It has a very high cryoscopic constant

  • It is volatile

  • It is solvent for organic substances

  • It is readily available 

From the colligative properties of solution which one is the best method for the determination of molecular weight of proteins & polymers :

  • Osmotic pressure

  • Lowering in vapour pressure 

  • Lowering is freezing point

  • Elevation in boiling point

A solution contains non volatile solute of molecular mass M2. The molecular mass of solute in terms of osmotic pressure is  : -
 

Note:

m2 → mass of solute

V → Volume of solution

\(\Pi\) → Osmotic pressure

  •  M2=(m2π)VRT

  •  M2=(m2V)RTπ

  •  M2=(m2V)πRT

  •  M2=(m2V)πRT

The ideal solution indicates -

  • A – B attraction force is greater than A – A and B – B

  • A – B attraction force is less than A – A and B – B

  • Attraction force remains same in A – A and B – B

  • Volume of the solution is different from the sum of the volume of solute and solvent

Beans get cooked earlier in a pressure cooker, because: -





  •   Boiling point increase with increasing pressure

  •   Boiling point decrease with increasing pressure

  •   Extra pressure of pressure cooker, softens the beans

  •   Internal energy is not lost while cooking in a pressure cooker

If 22 g of benzene is dissolved in 122 g of carbon tetrachloride then the mass percentage of carbon tetrachloride (CCl4) is-

  • 82.72%

  • 83.72%

  • 84.72%

  • 85.72%

The partial pressure of ethane over a solution containing 6.56 × 10–2 g of ethane is 1 bar. If the solution contains 5.00 × 10–2 g of ethane, the partial pressure of the gas will be -

  •  0.66 bar

  •  0.96 bar

  •  0.76 bar

  •  0.19 bar

The positive deviations from Raoult’s law mean the vapour pressure is -

  • Higher than the expected one.

  • Lower than the expected one.

  • Equal to the expected.

  • None of the above

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