Among the following application/s of osmosis is/are :
In animals, water moves into different parts of the body.
Stretching of leaves, flower.
The unit that relates concentration of solution with its vapour pressure is:
Mole fraction.
Parts per million.
Mass percentage.
Molality.
A beaker contains a solution of substance 'A' . Precipitation of substance ‘A’ takes place when small amount of 'A' is added to the solution. The solution is -
Saturated.
Supersaturated.
Unsaturated.
Concentrated.
Colligative properties depend on -
The nature of the solute particles dissolved in solution.
The number of solute particles in solution.
The physical properties of the solute particles dissolved in solution.
The nature of solvent particles.
A solution that has the highest boiling point among the following is -
1.0 M NaOH
1.0 M Na2SO4
1.0 M NH4NO3
1.0 M KNO3
An unripe mango placed in a concentrated salt solution to prepare pickle shrivels because -
It gains water due to osmosis.
It loses water due to reverse osmosis.
It gains water due to reverse osmosis.
It loses water due to osmosis.
At a given temperature, osmotic pressure of a concentrated solution of a substance is-
Is higher than that of a dilute solution.
Is lower than that of a dilute solution.
Is same as that of a dilute solution.
Cannot be compared with osmotic pressure of dilute solution.
Value of Henry's constant KH is-
Increases with increase in temperature.
Decreases with increase in temperature.
Remains constant.
First increases then decreases.
The value of Henry's constant, KH is ......... .
Greater for gases with higher solubility.
Greater for gases with lower solubility.
Constant for all gases.
Not related to the solubility of gases.
Intermolecular forces between two benzene molecules are nearly the same strength as those between two toluene molecules.
Incorrect statement among the following for a mixture of benzene and toluene is -
a. ∆mixH= zero
b. ΔmixV = Zero
c. These will form a minimum boiling azeotrope
d. These will not form an ideal solution
(a, b)
(b, c)
(c, d)
(a, d)
For a binary ideal liquid solution, the curve that represents the variation in total vapor pressure versus composition of the solution is -
a.
b.
c.
d.
The correct option is-
3. 22.6 kg mol-1
53.50 g mol-1
43.5 kg mol-1
4. 41.35 g mol-1
An aqueous solution of 2% non-volatile solute exerts a pressure of 1.004 bar at the normal boiling point of the solvent. The molar mass of the solute is -
If 8g of a non-electrolyte solute is dissolved in 114 g of n-octane to reduce its vapour pressure to 80%, the molar mass (in g mol–1) of the solute is -
[Molar mass of n-octane is 114 g mol–1 ]
40
60
80
20
Isotonic solutions have same-
Vapour pressure
Freezing temperature
Osmotic pressure
Boiling temperature
The molarity of H2SO4 solution that has a density 1.84 g/cc at 35°C and contains 98% H2SO4 by weight is-
1.84 M
81.4 M
18.4 M
184 M
Vapour pressure of chloroform (CHCl3) and dichloromethane (CH2Cl2) at 25°C are 200 mmHg and 41.5 mmHg respectively. Vapour pressure of the solution obtained by mixing 25.5 g of (CHCl3) and 40 g of (CH2Cl2) at the same temperature will be: (Molecular mass of (CHCl3) = 119.5 u and molecular mass of (CH2Cl2) = 85 u)
90.40 mm Hg
119.5 mm Hg
75 mm Hg
173.9 mm Hg
A 0.1 molal aqueous solution of a weak acid (HA) is 30% ionized. If Kf for water is 1.86°C/m, the freezing point of the solution will be -
–0.24°C
–0.18°C
–0.54°C
–0.36°C
200 mL of an aqueous solution of a protein contains it's 1.26 g. The Osmotic pressure of this solution at 300 K is found to be 2.57 × 10–3 bar.The molar mass of protein will be
(R = 0.083 L bar mol–1 K–1):
61038 g mol–1
51022 g mol–1
122044 g mol–1
31011 g mol–1
Henry’s law constant for the molality of methane in benzene at 298 K is 4.27 × 105 mm Hg. The solubility of methane in benzene at 298 K under 760 mm Hg is -
1.78 x 10-3
1.78 x 10-5
2.98 x 10-4
3.78 x 10-3
The addition of water vapours does not change the density of -
CCl4
CS2
Ether
Coke
1% (w/w)solution of a compound is isotonic with 5% (w/w)sucrose (sugar) solution. Then molecular wt. of compound will be :
Mole fraction of solute is 0.2 in solution then lowering in V.P (∆P) = 10. If lowering in V.P.( ∆P) = 20 then mole fraction of solvent will be in solution :
Camphor is often used in molecular mass determination because :-
It has a very high cryoscopic constant
It is volatile
It is solvent for organic substances
It is readily available
From the colligative properties of solution which one is the best method for the determination of molecular weight of proteins & polymers :
Lowering in vapour pressure
Lowering is freezing point
Elevation in boiling point
A solution contains non volatile solute of molecular mass M2. The molecular mass of solute in terms of osmotic pressure is : -
Note:
m2 → mass of solute
V → Volume of solution
\(\Pi\) → Osmotic pressure
M2=(m2π)VRT
M2=(m2V)RTπ
M2=(m2V)πRT
The ideal solution indicates -
A – B attraction force is greater than A – A and B – B
A – B attraction force is less than A – A and B – B
Attraction force remains same in A – A and B – B
Volume of the solution is different from the sum of the volume of solute and solvent
Beans get cooked earlier in a pressure cooker, because: -
If 22 g of benzene is dissolved in 122 g of carbon tetrachloride then the mass percentage of carbon tetrachloride (CCl4) is-
82.72%
83.72%
84.72%
85.72%
The partial pressure of ethane over a solution containing 6.56 × 10–2 g of ethane is 1 bar. If the solution contains 5.00 × 10–2 g of ethane, the partial pressure of the gas will be -
0.66 bar
0.96 bar
0.76 bar
0.19 bar
The positive deviations from Raoult’s law mean the vapour pressure is -
Higher than the expected one.
Lower than the expected one.
Equal to the expected.
None of the above
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