A 200 mL flask having oxygen at 220 mm and a 300 mL flask having nitrogen at 100 mm are connected in such a way that O2 and N2 may combine in their volumes if temperature is kept constant. The total pressure of the gaseous mixture is-
158 mm
138 mm
148 mm
168 mm
Given below is the graphical representation of volumes occupied by several gases at STP at Y axis and mass at X axis. find out which gas/gases is/are not placed at the correct position?
He, NH3
CH4, He
NH3, H2
NH3, CH4
If 1 g of each of the following gases are taken at STP, then the gas that will have the highest volume is -
CO, H2O, CH4, NO
CH4
H2O
NO
CO
The conditions at which real gas would behave ideally is-
At high temperature and low pressure.
At low temperature and high pressure.
At high temperature and high pressure.
At low temperature and low pressure .
If pressure is in atmosphere and volume in dm3 , then the unit of 'a' is-
atm dm6 mol-2
atm dm4 mol-2
atm dm3 mol-3
atm-1 dm4 mol-2
The pressure of 1 gm of an ideal gas A at 27 °C is found to be 2 bar. When 2 g of another ideal gas B is introduced in the same flask at the same temperature, the pressure becomes 3 bar.
The correct relationship between their molecular masses is -
MA=MB
4MA=MB
MA= 2MB
2MA=MB
A = pV2T2n
The SI unit for the quantity A is -
N m2 K2 mol-1
N m4 K mol-1
N m2 K3 mol-1
N m4 K2mol-1
Assertion: Critical temperatures for carbon dioxide and methane are 31.1 °C and –81.9 °C respectively.
Reason: The intermolecular forces of attraction are stronger in CO2 than CH4
Both Assertion and Reason are true and Reason is the correct explanation of Assertion
What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?
5.0 bar
2.5 bar
2.7 bar
3.0 bar
A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?
0.8 bar
1.8 bar
2.6 bar
3.5 bar
At 0°C, the density of a certain oxide of a gas at 2 bar is the same as that of dinitrogen at 5 bar.
The molecular mass of the oxide would be -
35 g/mol
45 g/mol
70 g/mol
60 g/mol
The volume of H2 that would be released when 0.15 g of aluminium reacts at 20 °C and 1 bar pressure with caustic soda is-
225 L
301 mL
156 L
203 mL
The pressure exerted by a mixture of 3.2 g of methane and 4.4 g of carbon dioxide contained in a 9 dm3 flask at 27 °C would be -
1. 8.31 × 104 Pa2. 7.43 × 10-4 Pa3. 6.87 × 103 Pa4. 8.31 × 106 Pa
0.5 L of H2 at 0.8 bar and 2.0 L of dioxygen at 0.7 bar are introduced in a 1L vessel at 27°C.
The pressure inside the vessel would be -
3.6 bar
4.1 bar
0.7 bar
A student forgot to add the reaction mixture to the round-bottomed flask at 27 °C but instead, he placed the flask on the flame. After a lapse of time, he realized his mistake and using a pyrometer he found the temperature of the flask was 477 °C. The fraction of air that would expel out would be
1/3
4/5
3/5
2/3
The total pressure of a mixture that contains 8 g of O2 and 4 g of H2 confined in a vessel of 1 dm3 at 27°C would be -
(R = 0.083 bar dm3 K-1mol-1)
45.67 bar
3. 34.67 bar
2. 56.02 bar
67.13 bar
Find the mass of payload of a balloon of radius 10 m, if a mass of 100 kg is filled with helium at 1.66 bar and 27°C temperature:
(Density of air = 1.2 kg m–3 and R = 0.083 bar dm3 K–1 mol–1).
2905 Kg
3811 Kg
2721 Kg
4201 Kg
2.9 g of a gas at 95°C occupies the same volume as 0.184 g of dihydrogen at 17°C, at the same pressure. The molar mass of the gas is -
20 g mol-1
40 g mol-1
34 g mol-1
14 g mol-1
A mixture of dihydrogen and dioxygen at one bar pressure contains 20% by weight of dihydrogen. The partial pressure of dihydrogen is -
0.2 bar
0.6 bar
Van der Waals parameter 'a' signifies -
The magnitude of intermolecular attractive forces.
The magnitude of intermolecular repulsive forces.
The volume of a gas molecule.
All of the above.
A plot of volume versus temperature (T) for a gas at constant pressure is a straight line passing through the origin. The plots at different values of pressure are shown in the figure given below.
The correct order of pressure is -
Temperature (K)
p1>p2>p3>p4
p1=p2=p3=p4
p1<p2<p3<p4
p1<p2=p3<p4
The interaction energy of London force is inversely proportional to sixth power of the distance between two interacting particles. Their magnitude depends upon-
Charge of interacting particles
Mass of interacting particles
Polarisability of interacting particles
Strength of permanent dipoles in the particles
Dipole-dipole forces act between the molecules possessing permanent dipole. Ends of dipoles possess 'partial charges'. The partial charge will be-
More than unit electronic charge
Equal to unit electronic charge
Less than unit electronic charge
Double the unit electronic charge
As the temperature increases, average kinetic energy of molecules increases. With increase in temperature at constant volume, the pressure -
Increases
Decreases
Remains same
Becomes half
Gases possess characteristic critical temperature which depends upon the magnitude of intermolecular forces between the particles. Following are the critical temperatures of some gases.
Gases
H2
He
O2
N2
The critical temperature in Kelvin
33.2
5.3
154.3
126
From the above data, the order of liquefaction of the given gases is-
(write the order from the gas liquefying first)
H2, He, O2, N2
He, O2, H2, N2
N2, O2, He, H2
O2, N2, H2, He
In the given figure, the curve represents an ideal gas is-
B only
C and D only
E and F only
A and B only
How does the surface tension of a liquid vary with increase in temperature?
No regular pattern is followed
The state of a gas can be described by quoting the relationship between-
Pressure, volume, temperature
Temperature, amount, pressure
Amount, volume, temperature
Pressure, volume, temperature, amount
The density of a gas is found to be 5.46 g/dm3 at 27°C at 2 bar pressure. The density of gas at STP would be -
1. 2.0 g dm-32. 3.0 g dm-33. 4.5 g dm-34. 1.5 g dm-3
34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. The molar mass of phosphorus would be -
1. 1247.5 g mol-12. 2234.7 g mol-13. 3126.9 g mol-14. 1134.6 g mol-1
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