A 200 mL flask having oxygen at 220 mm and a 300 mL flask having nitrogen at 100 mm are connected in such a way that O2 and N2 may combine in their volumes if temperature is kept constant. The total pressure of the gaseous mixture is-

  • 158 mm

  • 138 mm

  • 148 mm

  • 168 mm

Given below is the graphical representation of volumes occupied by several gases at STP  at Y axis and mass at X axis. find out which gas/gases is/are not placed at the correct position?

  • He, NH3 

  • CH4, He

  • NH3, H2 

  • NH3, CH4 

If 1 g of each of the following gases are taken at STP, then the gas that will have the highest volume is -

CO, H2O, CH4, NO

  • CH4

  •   H2O

  • NO 

  • CO

The conditions at which real gas would behave ideally is-

  • At high temperature and low pressure.

  • At low temperature and high pressure.

  • At high temperature and high pressure.

  • At low temperature and low pressure .

If pressure is in atmosphere and volume in dm, then the unit of 'a' is-

  •  atm dm6 mol-2

  •  atm dm4 mol-2

  •  atm dm3 mol-3

  •  atm-1 dm4 mol-2

The pressure of 1 gm of an ideal gas A at 27 °C is found to be 2 bar. When 2 g of another ideal gas B is introduced in the same flask at the same temperature, the pressure becomes 3 bar.

The correct relationship between their molecular masses is -

  • MA=MB

  • 4MA=MB

  • MA= 2MB

  • 2MA=MB

 A = pV2T2n 

The SI unit for the quantity A is -

 

  •  N m2 K2 mol-1

  •  N m4 K mol-1

  •  N m2 K3 mol-1 

  •  N m4 K2mol-1

Assertion: Critical temperatures for carbon dioxide and methane are 31.1 °C and –81.9 °C  respectively.

Reason: The intermolecular forces of attraction are stronger in CO2 than CH4

 

  •   Both Assertion and Reason are true and Reason is the correct explanation of Assertion

  •   Both Assertion and Reason are true, but Reason is not the correct explanation of Assertion
  •   Assertion is true, but Reason is false
  •   Both Assertion and Reason are false

What will be the minimum pressure required to compress 500 dm3 of air at 1 bar to 200 dm3 at 30°C?

  • 5.0 bar

  • 2.5 bar

  • 2.7 bar

  • 3.0 bar

A vessel of 120 mL capacity contains a certain amount of gas at 35 °C and 1.2 bar pressure. The gas is transferred to another vessel of volume 180 mL at 35 °C. What would be its pressure?

  • 0.8 bar

  • 1.8 bar

  • 2.6 bar

  • 3.5 bar

At 0°C, the density of a certain oxide of a gas at 2 bar is the same as that of dinitrogen at 5 bar.

The molecular mass of the oxide would be -

  • 35 g/mol

  • 45 g/mol

  • 70 g/mol

  • 60 g/mol

The volume of H2 that would be released when 0.15 g of aluminium reacts at 20 °C and 1 bar pressure with caustic soda is-

  • 225 L

  • 301 mL

  • 156 L

  • 203 mL

The pressure exerted by a mixture of 3.2 g of methane and 4.4 g of carbon dioxide contained in a 9 dm3 flask at 27 °C would be -

1. 8.31 × 104 Pa2. 7.43 × 10-4 Pa3. 6.87 × 103 Pa4. 8.31 × 106 Pa

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0.5 L of H2 at 0.8 bar and 2.0 L of dioxygen at 0.7 bar are introduced in a 1L vessel at 27°C.

The pressure inside the vessel would be -

 

  • 3.6 bar

  • 1.8 bar

  • 4.1 bar

  • 0.7 bar

A student forgot to add the reaction mixture to the round-bottomed flask at 27 °C but instead, he placed the flask on the flame. After a lapse of time, he realized his mistake and using a pyrometer he found the temperature of the flask was 477 °C. The fraction of air that would  expel out would be

  • 1/3

  • 4/5

  • 3/5

  • 2/3

The total pressure of a mixture that contains 8 g of O2 and 4 g of H2 confined in a vessel of 1 dm3 at 27°would be -

(R = 0.083 bar dmK-1mol-1)

 

  • 45.67 bar

  • 3. 34.67 bar

  • 2. 56.02 bar

  • 67.13 bar  

Find the mass of payload of a balloon of radius 10 m, if a mass of 100 kg is filled with helium at 1.66 bar and 27°C temperature:

(Density of air = 1.2 kg m3 and R = 0.083 bar dm3 K1 mol1).

  • 2905 Kg

  • 3811 Kg 

  • 2721 Kg

  • 4201 Kg                                                                                                                

2.9 g of a gas at 95°C occupies the same volume as 0.184 g of dihydrogen at 17°C, at the same pressure. The molar mass of the gas is -

  • 20 g mol-1

  • 40 g mol-1

  • 34 g mol-1

  • 14 g mol-1

A mixture of dihydrogen and dioxygen at one bar pressure contains 20% by weight of dihydrogen. The partial pressure of dihydrogen is -

  • 0.2 bar

  • 0.7 bar

  • 0.8 bar

  • 0.6 bar

Van der Waals parameter 'a' signifies -

  • The magnitude of intermolecular attractive forces.

  • The magnitude of intermolecular repulsive forces.

  • The volume of a gas molecule.

  • All of the above.

A plot of volume versus temperature (T) for a gas at constant pressure is a straight line passing through the origin. The plots at different values of pressure are shown in the figure given below.

  
The correct order of pressure is -

         Temperature (K) 

  •  p1>p2>p3>p4

  •  p1=p2=p3=p4

  •  p1<p2<p3<p4

  •  p1<p2=p3<p4

The interaction energy of London force is inversely proportional to sixth power of the distance between two interacting particles. Their magnitude depends upon-

  • Charge of interacting particles

  • Mass of interacting particles

  • Polarisability of interacting particles

  • Strength of permanent dipoles in the particles

Dipole-dipole forces act between the molecules possessing permanent dipole. Ends of dipoles possess 'partial charges'. The partial charge will be-

  • More than unit electronic charge

  • Equal to unit electronic charge

  • Less than unit electronic charge

  • Double the unit electronic charge

As the temperature increases, average kinetic energy of molecules increases. With increase in temperature at constant volume, the pressure -  

  • Increases

  • Decreases

  • Remains same

  • Becomes half

Gases possess characteristic critical temperature which depends upon the magnitude of intermolecular forces between the particles. Following are the critical temperatures of some gases.

Gases

H2

He

O2

N2

The critical temperature in Kelvin

33.2

5.3

154.3

126

From the above data, the order of liquefaction of the given gases is-

(write the order from the gas liquefying first)

  •  H2, He, O2, N2

  •  He, O2, H2, N2

  •  N2, O2, He, H2

  •  O2, N2, H2, He

 In the given figure, the curve represents an ideal gas is-

  

  •   B only

  •   C and D only

  •   E and F only 

  •   A and B only

How does the surface tension of a liquid vary with increase in temperature?

  • Remains same

  • Decreases

  • Increases

  • No regular pattern is followed

The state of a gas can be described by quoting the relationship between-

  •   Pressure, volume, temperature

  •   Temperature, amount, pressure

  •   Amount, volume, temperature

  •   Pressure, volume, temperature, amount

The density of a gas is found to be 5.46 g/dm3 at 27°C at 2 bar pressure. The density of gas at STP would be -

1. 2.0 g dm-32. 3.0 g dm-33. 4.5 g dm-34. 1.5 g dm-3

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34.05 mL of phosphorus vapour weighs 0.0625 g at 546 °C and 0.1 bar pressure. The molar mass of phosphorus would be -

1. 1247.5 g mol-12. 2234.7 g mol-13. 3126.9 g mol-14. 1134.6 g mol-1

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